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500 个结果
  • 简介:针对GKD2内燃机车电空接触器存在的烧损故障问题,结合电空接触器结构特点和电路原理从理论上进行了分析,提出了相应的改进措施和建议,保证了电空接触器无电状态下闭合和分断。对电空接触器触头的技术状态进行测试,开距、超程、压力和研距控制在规定的范围内,为确保机车正常运用发挥了重要作用。

  • 标签: 电力机车 电空接触器 烧损故障原因分析 措施 改进预防
  • 简介:Loadedonthecordierite,therareearthdopedcompositecatalystwaspreparedbysol-gelmethodcombinedwithdippingtechnique.TakingOrthodichlorobenzeneasmodel,thecatalystwasusedtoremovethedioxinsofthewastegas.Theresultsshowedthatat280℃andgasspacevelocitybeing8000h-1,theorthodichlorobenzenecouldberemovedeffectivilybythepreparedCeO2-TiO2-V2O5compositecatalystwhoseactivitywasremarkablyenhancedbythedopingofCe,whiletheindustrialside-streamtestofdioxinsfromrefuseincinerationsmokeindicatedthatthedecompositionratecouldreachabove93%underthesameconditions.

  • 标签: orthodichlorobenzene DIOXINS CATALYTIC oxidation REFUSE INCINERATION
  • 简介:本文针对2250热轧生产线生产冷轧基料过程中出现的窄问题,通过分析窄卷的工艺过程参数,分析导致窄的具体原因。从优化中间坯宽度控制及卷取控制参数两方面采取措施,窄问题得到有效解决。

  • 标签: 拉窄 卷取张力 卷取超前率 宽度控制
  • 简介:针对故障频发的矫机缺陷,提出了改进措施并付诸实施,提高了矫机作业率,减少了故障,降低了维护费用,延长了设备寿命。

  • 标签: 拉矫机 连铸机 小方坯 水冷电动机
  • 简介:本文从质量异议的角度,指出了控制热轧带钢厂带钢产品窄问题的重要性。通过对带钢窄问题进行分析,查找要因,提出了控制窄的解决方法,实施后取得了一定的效果。

  • 标签: 拉窄 要因 控制 调整
  • 简介:Inthiswork,boththethermalexpansionandelectricalconductivityofnanocrystallineLa2Mo2O9werestudied.ThenanocrystallinepowderofLa2Mo2O9wasobtainedbysol-gelmethod,andwiththehelpofSHP(superhighpressure)upto4.5×104atmat700℃forashorttime,andthenanocrystallinepowderwasdensifiedwithoutobviousparticlesizegrowth.TheelectricalconductivityofnanocrystallineLa2Mo2O9wasoneorderofmagnitudelowerthanthatofthemicrocrystallinesampleatthesametemperature.Owingtothephasetransition,themicrocrystallineLa2Mo2O9hasanabruptincreaseofthermalexpansionwithapeakvalueof48×10-6K-1at556℃.Forthenanocrystallinematerial,thepeakvalueincreasesto112×10-6K-1at520℃.Ontheotherhand,above600℃thesignificantgrowthofparticlesizeofthenanocrystallineLa2Mo2O9wasobserved,accompanyingbyatremendousincreaseofthermalexpansionwithapeakvalueofthirdhigherthanthatofLa2Mo2O9.

  • 标签: NANOCRYSTALLINE electrical CONDUCTIVITY LANTHANUM MOLYBDATE superhigh
  • 简介:Basedonthethermodynamicallyself-consistentanalysisandoptimizationofthreesub-binarysystemsoftheternarysystemPrCl3-CaCl2-MgCl2,thethermodynamicsofthisternarysystemhasbeenstudied.UsingHillertmodelandtakingMgCl2asanasymmetriccomponent,thePrCl3-CaCl2-MgCl2phasediagramhasbeencalculated.Theagreementbetweencalculatedandmeasuredcompositionsandtemperaturesatdeflectingpointsonliquidusisgood.Thesystemisasimpleeutecticonewithaeutecticpointat26.0mol%PrCl3,41.5mol%CaCl2,32.5mol%MgCl2;560℃(calculated)and26.0mol%PrCl3,39.4mol%CaCl2,34.6mol%MgCl2;546℃(measured),respectively.

  • 标签: TERNARY system Phase DIAGRAM Rare earth
  • 简介:TheZrO2-Al2O3ceramiccompositeswerepreparedbyappropriatetechniqueswithcommercialZrO2andAl2O3powdersasrawmaterialsandY2O3asstabilizer.TheresultsindicatethatwiththeintroductionofAl2O3intotheZrO2matrixwherethequantityofadditiveY2O3is3.5%(molefraction),thegrowthofZrO2grainsisefficientlyinhibited,whichhelpstheZrO2grainsexistinametastabletetragonalmanner;thushigherstrengthandtoughnessareacquired.Whenthecontentofaluminais20%(massfraction),thebendingstrengthandfracturetoughnessofthecompositesare676.7MPaand10MPa·m1/2respectively,themechanicalbehaviorsareclosetothosepreparedwithZrO2andAl2O3powderssynthesizedthroughwetchemicalapproach.Themechanicalbehaviorsofthecompositesarewellimprovedowingtothedispersiontougheningofaluminagrainsandphasetransformationtougheningofzirconiagrains.

  • 标签: 无机非金属材料 陶瓷 稳定设备 稀土
  • 简介:Differentrareearth(RE)ionsdopantswereaddedintotheSrAl2SiO7:Eu2+phosphorsinordertoenhancethephosphorescenceproperties,andtheeffectoftheREionsincludingYb3+,Ce3+,Nd3+,Dy3+andTm3+,wascomparativelyinvestigated.ItwasfoundthatNd3+additionimprovedthephosphorescencepropertiesobviouslyamongallthestudiedREions.Therefore,Sr1.96–xAl2SiO7:xEu2+,yNd3+phosphorswerestudiedindetail,andtheoptimumEu2+andNd3+concentrationsweredeterminedwiththeafterglowtimeofabout20min.Thephasestructures,photoluminescence(PL)properties,long-lastingphosphorescence(LLP)properties,afterglowdecaycurvesandthermo-luminescence(TL)fortheselectedphosphorsduringthecorrespondingstudywereinvestigated.AllthephosphorsexhibitedgreenPLemissionandLLPemission.ThereweretwoTLbandslocatedatabout325and380Kforthestudiedsamples,andtherelationshipbetweenREadditionandphosphorescencepropertieswasdiscussed.

  • 标签: 稀土掺杂 光性质 荧光粉 磷光 欧盟 稀土离子
  • 简介:FluorescencespectraofSm2+andEu2+→Sm2+energytransferwerestudiedinSrB4O7.Thereappearsonlyfluorescencefrom5D0transitionofSm2+at77K.Thevibroniclinesassociatedwith5D0→7F0transitionwereobserved.Thethermalpopulationtoupperstatesof5D1and4f5dlevelsfrom5D0givesriseto5D1→7FJand5d→4fradiativetransitionsofSin2+athighertemperature.

  • 标签: Strontium-samarium BORATE Energy transfer ELECTRON-PHONON interaction
  • 简介:Reactionof(MeC5H4)3LnwithHOCH2CH2NMe2intetrahydrofuran(THF)givesthenewcomplexes[(MeC5H4)2Ln(μ-OCH2CH2NMe2)]2(Ln=Sm,Y,Nd)withnitrogenfunctionalizedμ-alkoxideligand.ThecomplexeswerecharacterizedbyelementalanalysisandIR,and[(MeC5H4)2Sm(μ-OCH2CH2NMe2)]2wasstructurallycharacterizedbytheX-raydiffractiontobeadimerformedbytwounsymmetricoxygenbridges.ThecomplexhasatricyclicskeletonwiththeadditionaltwoSm-NbondsviaintramolecularcoordinationofOCH2CH2NMe2.ThecoordinationnumberofthecentralmetalSmisnine.Thetitlecomplexesshowgoodcatalyticactivityforring-openingpolymerizationofε-caprolactone.

  • 标签: 2 晶体结构 合成 镧系元素 ε-已内酯 聚合
  • 简介:采用碱熔处理样品,酸化后,移取部分溶液稀释后引入ICP测定ZrO2、TiO2、Fe2O3含量,剩余溶液用强碱分离钛、铁、锰等干扰元素后,EDTA—CuSO4法返滴定Al2O3,终点明显,检测重现性好;

  • 标签: FE2O3 AL2O3 ZRO2 TIO2 测定方法 质砖
  • 简介:增加的CeO2(ZrO2)/TiO2催化剂独立由大音阶的第五音胶化和受精的方法准备了的一系列镨为选择催化减小被测试没有,并且由X光检查衍射(XRD)描绘了,N2-brumauer-emmett-teller(N2-BET),NH3-temperature规划了解吸附作用(NH3-TPD),H2-temperature规划了减小(H2-TPR),PL系列,曼系列,电子顺磁的回声(EPR)一催化性能上的准备方法的影响被学习。结果证明CeO2(ZrO2)/TiO2催化剂的催化性能上的Pr增加的影响在大音阶的第五音胶化方法和受精方法之间是不同的。Pr增加趋于与TiO2交往并且当它是更可能的与在受精方法形成Ce-O-Pr的结构的CeO2交往时,在大音阶的第五音胶化方法形成了Ti-O-Pr的结构。大音阶的第五音胶化方法准备的催化剂的全部的酸数量和氧化还原作用性质与Pr元素的增加减少了,它导致了催化活动的减少。相反,受精方法准备的增加Pr的催化剂被发现拥有更容易的reducibility,更多的全部的酸数量和Ce3+种类的更高的比例,它为更高催化的活动是赞成的。

  • 标签: 增加镨 CeO 2(ZrO2)/TiO2 准备方法 选择催化减小 催化性能 稀土元素
  • 简介:在甲烷(POM)的部分氧化的催化活动和稳定性混合方法的CeO2-ZrO2和-Al2O3的影响在Ni/Ce0.7Zr0.3O2-Al2O3催化剂上被调查。催化剂被XRD,TPR,H2-chemsorption,和TG-DTA描绘。为新鲜催化剂,结果证明混合催化剂(原子)的盐先锋比混合方法(摩尔)和机械地混合方法(MECH)的粉末的催促的人准备的催化剂介绍了更好的性能。XRD的结果建议在在原子样品的CeO2-ZrO2和Al2O3之间的相互作用比其它强壮,它导致了更多的格子缺点和从而更好的起始的活动。而且,MECH样品在24h稳定性测试有最好的稳定性和最少的焦炭免职。TPR和H2-chemsorption的结果显示在MECH样品的Ni-Al的亲密接触提高了抵抗焦炭免职和金属sintering的能力。

  • 标签: CEO2-ZRO2 Γ-AL2O3 催化剂 稀土
  • 简介:以Nb2O5、In(NO3)3和Sm(NO3)3为原料,采用溶胶-凝胶法制备新型光催化材料Sm2InNbO7。采用X射线衍射(XRD)、扫描电镜(SEM)、比表面积分析(BET)以及紫外-可见漫反射光谱(UV-Visdiffusereflectancespectroscopy)技术对该材料的结构、形貌和光吸收性能进行表征。以可见光下亚甲基蓝(MB)的脱色降解为模型反应,考察煅烧温度、催化剂用量、H2O2用量和pH值对Sm2InNbO7光催化性能的影响。结果表明,煅烧温度为700℃时即可获得具有烧绿石结构的Sm2InNbO7。随焙烧温度升高,催化剂结晶度增加,粒径增大,比表面积下降,吸收边界出现一定的蓝移;在850℃下煅烧3h获得的Sm2InNbO7样品具有最高的催化活性,当50mL质量浓度的10mg/L的MB溶液中催化剂用量为0.1g、30%H2O2溶液用量为0.5mL、pH=6时,亚甲基蓝的降解率高达93.8%,明显优于固相法制备的Sm2InNbO7以及P-25TiO2。较高的pH值有利于光催化反应的进行。

  • 标签: 溶胶?凝胶法 光催化 烧绿石结构 合成
  • 简介:Inthispaper,varioustechniquesincludingBET,XRD,SEMandXPSwereusedtostudythesinteringofpureandLa2O3-dopedtitania.Theexperimentalresultsshowthatsinteringoftitaniaproceedsviavolumediffu-sion.Addingoflanthanumoxidedecreasestherateofsinteringandhindersthephasetransitionfromanatasetorutilecrystalbystrongsurfaceinteractionbetweenthemixedcrystals(La4Ti9O24,La0.66TiO2.99)andTiO2.

  • 标签: La2O3 TiO2 SINTERING kinetics Thermal stability
  • 简介:综述了粉末注射成形技术的工艺特点、技术现状以及在硬质合金异型产品制备中的应用,分析了钨钴硬质合金注射成形过程中存在的缺陷控制、碳含量控制、尺寸精度控制和提高制品力学性能等难点问题并给出了相应的的解决方法.并对硬质合金注射成形技术的发展方向和前景进行了展望.

  • 标签: 硬质合金 注射成形 缺陷控制
  • 简介:本文通过对卧式压滤机自动板装置的分析和研究,提出了一种新型的恒力矩板传动装置。

  • 标签: 压滤机 拉板装置 研究
  • 简介:Ni-W-P-CeO2-SiO2nano-compositecoatingswerepreparedonthecarbonsteelsurfacebypulseco-depositionofnickel,tungsten,phosphorus,nano-CeO2andnano-SiO2particles.Theinfluenceofnano-SiO2particlesconcentrationsinelectrolyteonmicrostructuresandpropertiesofthenano-compositecoatingswereresearched,andthecharacteristicswereassessedbychemicalcompositions,elementdistribution,depositionrate,microhardnessandmicrostructures.Theresultsindicatethatwhennano-SiO2particlesconcentrationsinelectrolytearecontrolledat20g·L-1,thedepositionratewith27.07μm·h-1andthemicrohardnesswith666Hvofthenano-compositecoatingsarehighest,elementlinescanningandareascanninganalysesshowthattheaveragecontentsofelementsW,P,SiandCeinthenano-compositecoatingsareclose,displayingthatthedistributionofeveryelementwithinthenano-compositecoatingsiseven.Anincreaseinnano-SiO2particlesconcentrationsinelectrolyte(whenlowerthan20g·L-1)leadstorefinementingrainstructureofnano-compositecoatings,butwhenitimprovedto30g·L-1,thecrystallitesizesincreaseagainandinthemeantimetherearealotofsmallbosswithnodulationshapeappearingonthesurfaceofnano-compositecoatings.

  • 标签: pulse electrodepositon NANO-COMPOSITE coatings deposition rate