简介:Loadedonthecordierite,therareearthdopedcompositecatalystwaspreparedbysol-gelmethodcombinedwithdippingtechnique.TakingOrthodichlorobenzeneasmodel,thecatalystwasusedtoremovethedioxinsofthewastegas.Theresultsshowedthatat280℃andgasspacevelocitybeing8000h-1,theorthodichlorobenzenecouldberemovedeffectivilybythepreparedCeO2-TiO2-V2O5compositecatalystwhoseactivitywasremarkablyenhancedbythedopingofCe,whiletheindustrialside-streamtestofdioxinsfromrefuseincinerationsmokeindicatedthatthedecompositionratecouldreachabove93%underthesameconditions.
简介:TheeffectsofSO2,SO3ondenovosynthesisofpolychlorinateddibenzo-p-dioxins(PCDDs)anddibenzofurans(PCDFs)werestudiedusingmodelflyashesincorporatingcopperoxideandactivatedcarbon.ItwasfoundthattheinhibitiveeffectofSO2onPCDD/FsformationissimilartothatofSO3.Toinvestigatetheinhibitionmechanism,CuSO4formationsfrombothCuOandCuCl2wereexamined.TheabilityofSO3toconvertCuCl2andCuOonasilicasupportintosulfateismuchstrongerthanthatofSO2.However,replacingsilicabyactivatedcarbonleadstoamuchhighconversionofCuCl2toCuSO4inthepresenceofSO2.ThepromotionbyactivatedcarbonisexplainedbythereductionofCuCl2toCu2Cl2andtheeventualconversionofCu2Cl2intoCuSO4isthemaininhibitionmechanismofSO2ondenovosynthesisofPCDD/Fs.