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218 个结果
  • 简介:Duetotheremarkablemagnetoresistance(MR)effectonperovskite-typemanganite,magnetoelectronicsandspintronicshavebecomeattractivesubjectsofexperimentalandtheoreticalinvestigationsfortheapplicationpurpose.(La0.9Nd0.1)2/3Ca1/3Mn1-xFexO3(x=0,x=0.05)werepreparedsuccessfullybysol-gelmethod.Thestructure,magneticproperties,andtransportpropertiesofthecompoundswereinvestigated.Themagnetoresistanceeffectdependsonthecompositionandthetemperature.XRDpatternsshowthatthecompoundisasinglephasepolycrystalwithpseudocubicstructure.Alargenegativeisotropicmagnetoresistanceeffectinthesampleswereobservedatlowtemperatureregion.ThemaximumMRofthesampleswas77%and97%,respectively.Itwasmostlikelyduetothescatteringorthetunnelingtransportofspin-polarizedcarriersinlatticeunderstrongmagneticfield.

  • 标签: SOL-GEL method MAGNETORESISTANCE effect PEROVSKITE pseudocubic
  • 简介:15%Ag-addedcubicperovskitesSr0.9La0.1TiO3andRuddlesden-Popper(RP)phasesSr2.7La0.3Ti2O7werefabricatedviahydrothermalsynthesis,coldpressingandhigh-temperaturesintering.Thestructureandthermoelectricpropertieswerealsoinvestigatedforallsamples.TheresultsindicatedthatAgprecipitatedasasecondphase.AgadditionmadeelectricalconductivityandabsoluteSeebeckcoefficientenhanced,asaresult,theZTvalueswereenhancedbothfortwoseries.Comparedwithcubicperovskite,RPphasewassubjectedtosmallerimpactbyAgaddition.ThereasonsforenhancingZTvalueandthedifferentimpactfortwoseriesbyAgadditionwerealsodiscussed.

  • 标签: 热电性能 SEEBECK系数 Ag 钙钛矿相 水热合成法 高温烧结
  • 简介:(Cu60Zr30Ti10)98Y2bulkmetallicglass(Φ4mm×70mm)wasobtainedsuccessfullybycoppermouldcoolingandspraying-casting,andsomesampleswereisothermallyannealedattemperaturesof473and623K,whichwaslowerthantheglasstransitiontemperature(Tg)for1h.Microstructureandpropertiesofas-castandannealedsampleswerestudied.Crystallizationphases(Cu10Zr7andCuZr)wereobservedinannealedsamples,andthespeciesandfractionofthesephasesincreasedwithincreasingannealingtemperature.Mic...

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  • 简介:Selectivecatalyticoxidation(SCO)ofammoniawascarriedoutoverCu-MncompoundscatalystsmodifiedwithtrivalentrareearthoxideCe2O3andLa2O3respectively.TiO2wasusedassupportanddifferentratioofO2weretestedinordertofindanappropriateO2concentration(vol.%),andtheresultsshowedthat1%O2(vol.%)waspropitioustoSCOofammonia.TheeffectsofthetworareearthoxidesmodifiedcatalystsCe2O3-Cu-Mn/TiO2andLa2O3-Cu-Mn/TiO2onthecatalyticactivityandselectivityofammoniaoxidationwereinvestigatedunderthereactionconditionof500ppmammonia,1%O2(vol.%),atthetemperaturefrom125to250oC.TheresultsrevealedthebeneficialroleofCe2O3andLa2O3incatalyticactivityatlowtemperatureandleanoxygenconcentration,whilethemodificationwithCe2O3andLa2O3ledtothenegativeinfluenceonN2selectivity.ForthecatalystsmodifiedwithCeshowedlowerNOandN2OselectivitythanthecatalystsmodifiedwithLa,thentheeffectsofdifferentCeloadingsoncatalyticactivityandselectivitywerealsoconsidered,incombinationwithcatalystspreparationmethods,whichincludeincipientwetimpregnation,sol-gelmethodandco-precipitation.Resultsrevealedthatthecatalystspreparedbysol-gelmethodobtainedpreferablecatalyticactivitycomparedwiththeothers,reaching99%ammoniaat200oC,whereas96%NOwasdetected.Italsoindicatedthatdifferentcatalystpreparationmethodsignificantlydeterminedproductiondistribution.

  • 标签: AMMONIA selective CATALYTIC oxidation (SCO) rare
  • 简介:分析了ZJK3×1.5A矿井提升机卷筒的结构简述,对卷筒上木衬的作用进行了分析,并结合实际情况对木衬中绳槽加工工艺进行了改进。

  • 标签: 矿井提升机 卷筒 木衬 绳槽 改进
  • 简介:记者从中国地质大学获悉,该校地质调查学院郑有业教授和他负责的项目团队,经过近4年的研究、勘探,证实了西藏冈底斯铜矿带是我国超千万吨级的铜多金属巨型成矿带,目前己控制的铜资源量达800万t,确证远景铜资源量可达1500万t以上,相当于我国保有铜总储量四分之

  • 标签: 铜矿带 资源量 西藏 中国地质大学 项目团队 地质调查
  • 简介:本文通过对压滤机各部件的结构和工作原理的介绍,以及使用有限元软件对压滤机主要受力构件的有限元分析,论述了XAZG50/1000×1500-UA全自动卧式压滤机的设计思路和重点。

  • 标签: 卧式 压滤机 全自动
  • 简介:1969年以来,我国于世界上首先发现、命名了“离子相”矿物、“离子相”稀土矿物、“风化壳离子吸附稀土矿”,并发明了“离子相”稀土矿物的两代提取工艺。从而,为世界提供了一种新型、特殊、富含中、重稀土、高科技所需的战略性矿产资源。本文回顾了“离子吸附”稀土发现、命名和两代提取工艺发明的有关情况,介绍了离子稀土矿的勘查与地质简况,以及在其开发应用历程中发生的一些重大事项。重点介绍了事件的主人公——赣州有色冶金研究所为此作出的贡献。旨在增加人们对它的认知和了解,进一步为“振兴中华”添砖加瓦。本文涉及的许多事项,尚属首次公布。

  • 标签: 离子吸附型 稀土矿物 勘查 开发 利用史 离子型稀土矿
  • 简介:介绍了方大特钢科技股份有限公司焦化厂焦炉工艺技术参数和配煤比的调,重点阐述了整捣固焦炉与顶装焦炉共用一套干熄焦系统时出现的问题,包括焦炉出焦计划编排、三大车联锁控制、焦炭运输过程等方面,并针对存在的问题提出了具体的解决措施。通过探索改进,焦炭整体干熄率达97%以上,大部分在99%以上。

  • 标签: 两种炉型 焦炉 干熄焦 生产组织
  • 简介:研究了非离子有机添加剂P强化铝酸钠溶液晶种分解过程的影响因素,同时引用XRD分析了不同晶种的活性。结果表明:添加剂P可有效提高分解率,显著改变产品的形貌,并具有一定增大产品粒度的作用;晶种性质极大影响添加剂的效用,特别是(002)晶面所对应的峰越强,晶种活性越好;研究了最佳工艺条件为在种分过程开始10h后加入100mg/L添加剂,保持晶种系数为3.39,最后于34h以后取出产品;晶种是分解过程的主要因素,添加剂仅能进行改善。

  • 标签: 晶种分解 添加剂 粒度 分解率 晶种活性
  • 简介:一系列立方的稀土元素sesquioxidesRE2O3的拉曼系列(RE=Eu,Gd,Dy,惊讶,嗯,Tm,Yb,陆,Sc和Y)被拉曼光谱学与532和785根nm激光线调查。丰富的另外的乐队由于激光激动的光被观察。为Eu2O3,Dy2O3,Ho2O3,Er2O3,Tm2O3和Yb2O3,,光主要为Gd2O3,Lu2O3,Sc2O3和Y2O3来自内在的三价的lanthanide离子,他们的光被归因于象Eu3+,Nd3+和Er3+那样的另外的光lanthanide离子的踪迹杂质。这调查为检测踪迹作为一个有用工具证实了拉曼光谱学光lanthanide杂质。

  • 标签: 激光激发荧光 RE2O3 拉曼光谱仪 杂质分析 氧化铕 氧化铒
  • 简介:ThephaseandmorphologytransformationduringthehydrothermaltreatingprocessofY2O3wasevaluatedwithX-raydiffcrcnce(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),particlesizeandspecificsurfaceareadetermination.TheresultsshowedthatthecubicY2O3didnottransferintohexagonalY(OH)3inpurewater.Therefore,purehexagonalY(OH)3withnanotubeandmicrorodmorphologieswereobtainedbyhydrothermaltreatingY2O3at150℃for12hin15mlof2mol/LNaOHsolutionwithandwith-outPVAorPEGItwassuggestedthatthecharacteristicpreferentialgrowthofY(OH)3wasattributedtothestructureanisotropyofhexahedronY(OH)3.TheadditionofPVAorPEGcouldpromotetheformingprocessofnanotubesbyselectiveadsorptionondifferentcrystalplanes,whichalteredthegrowthratealongdifferentdirectionsandresultedinthediffusionlimitofconstructingionsinthecentertopofrods.Finally,Y(OH)3:EuandY2O3:Eunanotubeswerealsosynthesizedbyusingthismethod,andtheirphotoluminescencepropertieswereevaluated.

  • 标签: HYDROTHERMAL synthesis Y(OH)3 Y(OH)3:Eu Y2O3:Eu NANOTUBE
  • 简介:本文论述了通过理念引领、行为训练、机制保证的综合效能,培育“想安全、会安全、懂安全”的本质安全人,探索建立安全生产的长效机制,对于实现企业长治久安、健康发展具有十分重要的现实意义。

  • 标签: 培育 本质型安全员工 建立 安全文化 机制
  • 简介:MeltspinningtechnologywasusedtopreparetheMg2Ni-type(Mg24Ni10Cu2)100–xNdx(x=0,5,10,15,20)alloysinordertoobtainananocrystallineandamorphousstructure.TheeffectsofNdcontentandspinningrateonthestructuresandelectrochemicalhydrogenstorageperformancesofthealloyswereinvestigated.ThestructurecharacterizationsofX-raydiffraction(XRD),transmissionelectronmicroscopy(TEM)andscanningelectronmicroscopy(SEM)linkedwithenergydispersivespectroscopy(EDS)revealedthattheas-spunNd-freealloydisplayedanentirenanocrystallinestructure,whereastheas-spunNd-addedalloysheldananocrystallineandamorphousstructureandthedegreeofamorphizationvisiblyincreasedwiththerisingofNdcontentandspinningrate,suggestingthattheadditionofNdfacilitatedtheglassformingoftheMg2Ni-typealloy.TheelectrochemicalmeasurementsindicatedthattheadditionofNdandmeltspinningimprovedtheelectrochemicalhydrogenstorageperformancesofthealloyssignificantly.Thedischargecapacitiesoftheas-castandspunalloysexhibitedmaximumvalueswhenNdcontentwasx=10,whichwere86.4,200.5,266.3,402.5and452.8mAh/gcorrespondingtothespinningrateof0(As-castwasdefinedasthespinningrateof0m/s),10,20,30and40m/s,respectively.Thecyclestability(S20,thecapacitymaintainrateat20thcycle)oftheas-castalloyalwaysrosewiththeincreasingofNdcontent,andthoseoftheas-spunalloysexhibitedthemaximumvaluesforNdcontentx=10,whichwere77.9%,83.4%89.2%and89.7%,correspondingtothespinningrateof10,20,30and40m/s,respectively.

  • 标签: 电化学测试 铸态合金 储氢性能 纳米晶体 NDX 非晶化