简介:继创新小石头后,创新最新推出了ZenMoo和ZenMooPlus两款福牛系列MP3,"牛"主题在2009年牛年别具卖点,小巧可爱的外观设计也对年轻时尚一族很有吸引力。
简介:Molybdenumoxidenanostructuredthinfilmsweregrownonfluorinedopedtinoxide(FTO),indiumdopedtinoxide(ITO)andordinaryglasssubstratesbythermalevaporationprocesswithoutvacuumandcatalystsusingmolybdenumtrioxide(MoO3)powderasasourcematerialandoxygenasacarriergas.Variousmorphologiesincludingnanobelts,disksandhexagonalrod-likenanostructureswereobtainedbychangingthesourceandsubstratetemperaturesduringthegrowthofMoO3thinfilms.Structuralparameters,morphology,compositionandsurfacefeaturesofthefilmswerecharacterizedbyXRD,SEM,EDAX,XPS,AFMandRamanspectroscopy.Thefilmswereorthorhombicinstructurewithpreferredorientationalong(010)plane.Morphologyanalysisrevealsrandomlyalignednanobeltswith40nminthicknessandawidthof800nmand3–12mminlength.Thediskshave1.5μmdiameters,1μmthicknessandhexagonalrod-likenanostructureswithalength,breathandwidthof2μm,1μmand100nmareformed.ThesampleswereinvestigatedunderdarkandphotocurrentconditionsinH2SO4aqueoussolutionasafunctionofappliedpotential.ThephotocurrentdensityofsamplespreparedonITOandFTOsubstratesampleswerecomparedandtheresultsarediscussed.
简介:AnovelsolidsolutionCe6MoO15wasachieved.Theirstructureandoxideionicconductivitywerestudied.BasedonCe6MoO15,rareearthelementsubstitutiononceriumsiteshowsthatallresultingoxidesenhancetheconductivityfurther,andhavehighoxide-ionconductivity,whichmaybeakindofpromisingmaterialforSOFCs.
简介:Thenanocompositefilmswerepreparedbydirectintercalationofpoly(ethyleneoxide)andPEOintoMoO3xerogelviasol-gelroute,TheelectrochromicbehaviorandthechemicalconditionwsofLi^+ionswereinvestigatedbycyclicvoltammograms,UV-visiblespectraltransmittanceandXPS,Thetesultsshowthatthecyclingefficiencyandthereversibilityofinsertion/extracitonofLi^+ionsin(PEO)1MoO3.nH2Onanocompositefilmwereimproved.TheintercalationofPEOintoMoO3xerogelmodulatedthewavelengthrangeofelectrochromismandenhancedtheelectrochromicefficiney,TwodifferentchemicalconditionsofLi^+ionsexistingintheinterlayerandinterstitialpositionsofMoO3latticewereobservedinMoO3XEROGELAND(PEO)1MoO3.nH2Onaocompositefilms.
简介:APt-MoO3/Ccatalyst,aimedtoeliminatetheharmfuleffectofsulfurdioxide(SCb)ontheperformanceofPtnanoparticles(NPs)forcatalysisofoxygenreductionreaction(ORR)inprotonexchangemembranefuelcells(PEMFC),isdevelopedandcharacterizedbyTEM,XRDandXPS.TheresultsrevealthatPt-MoO3/Ccatalystexhibitsnotonlyahighercatalyticactivity,butalsoabetterSO2poisoningresistanceandabetterrecoveryperformancethanthecommercialPt/Ccatalystdoes.
简介:Nearlysingle-phaseandpolycrystallinecharge-density-wavecompoundK_(0.3)MoO_3havebeenpreparedbyusingasimplemethod.Inthiswork,K_2CO_3andMoO_3wereusedasstartingmaterialsandreactedbyhotisostaticpressing(HIP)sintering.TheproductisnearlysinglephaseK_(0.3)MoO_3determinedbyX-raypowderdiffraction(XRD)andenergydispersivespectroscopy(EDS).MeasurementoftemperaturedependenceofresistivityrevealsthatthetransportpropertyofpolycrystallineK_(0.3)MoO_3obviouslydiffersfromthatofsinglecrystalduetothegrainboundariesandtheanisotropicstructureinthiskindofcompound.
简介:采用凝胶-燃烧法合成了LiY(MoO4)2:Dy3+黄色荧光粉,借助XRD、FE-SEM、荧光光谱仪对样品的晶体结构、形貌、发光特性等进行了分析。结果表明:所得LiY(MoO4)2:Dy3+样品为四方白钨矿型结构,平均粒径为600nm左右;样品的发射光谱由位于488nm较强的蓝光发射、575nm很强的黄光发射和663nm较弱的红光发射组成,CIE1931色坐标为(0.3999,0.4448),位于黄光区;Dy3+最佳掺杂量为x=0.050mol;柠檬酸的最佳加入量为n(NO3-)/n(C6H8O7)=4.5。
简介:AseriesofSm~(3+)dopedY_2MoO_6werepreparedthroughhightemperaturesolidstatereactiontechnique.Theirphasestructures,morphologiesandluminescencepropertieswereinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andphotoluminescencespectrometry.ThemostintenseabsorptionofY_2MoO_6hostoccurredat367nm.EnergytransferfromhostlatticetoSm~(3+)ionscouldbeobserved,andtheschematicdiagramofenergytransferwasconstructed.ThecriticalenergytransferdistanceandenergytransfermechanismbetweenSm~(3+)ionswerediscussedindetail.Consideringthehighcolorpurityandappropriateemissionintensity,Sm~(3+)dopedY_2MoO_6couldbeapromisingphosphorundernearultravioletlightexcitation.
简介:用正丁醇和柠檬酸为原料,WO3/MOO3/SiO2为催化剂催化合成柠檬酸三丁酯。通过考察醇与酸的物质的量比,反应温度和反应时间,催化剂用量和溶剂用量对酯化反应的影响。确定合成柠檬酸三丁酯的最佳反应条件为n(正丁醇)/n(柠檬酸)=4.5,催化剂用量为反应物柠檬酸质量的6%,反应温度130—140℃,反应时间3.5h,酯化率最高达98.5%,产率最高迭94.3%。WO3/MOO3/SiO2催化剂可重复使用,其催化活性基本不变。实验对合成的产品进行了红外光谱分析及折光率的测定,与文献值相符。
简介:采用高温固相法制得Eu^3+掺杂的Lu2MoO6荧光粉,通过X射线衍射(XRD)及激发、发射光谱和衰减寿命等手段对样品的结构和发光性质进行了表征。XRD结果表明:制备的荧光粉均为单斜结构。实验结果表明该样品在可见光谱范围内能够被近紫外光有效地吸收,该吸收来自Mo^6+–O^2-吸收带。在掺杂10%Eu^3+的情况下,发光最强。详细地研究最佳临界距离Rc和能量机制。Lu2MoO6:Eu^3+红色荧光粉是一种可应用于近紫外激发白光LED用的新型红色荧光粉。