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简介：针对甲酸乙酯(H(CO)OCH2CH3)与羟基自由基(OH)的反应动力学展开了理论与实验研究.在理论方面,首先通过量化计算得到了在M06-2x/ma-TZVP水平下准确的反应势能面,随后利用多结构-扭转(multi-stucturetorsionMS-T)方法对转动非谐效应进行了研究,获得了非谐校正系数,最后基于传统过渡态理论并考虑Eckart隧穿效应获得了200~2000K温度范围的反应速率常数.在实验方面,开展了激波管实验来测定H(CO)OCH2CH3与OH的反应速率常数,基于激光吸收光谱技术探测OH自由基306.7nm的吸收线,并对反射激波后高温反应过程的OH浓度变化进行测量,从而获得了900~1321K温度范围的反应速率常数,并论证了理论计算结果的合理性与准确性.

简介：BSTOdielectricceramicwaspreparedfromSrTiO3andBaTiO3powderssynthesizedbyhydrothermalmethod,aswellasfromBa0.6Sr0.4TiO3powdersynthesizedbyconventionalsolid-statereaction.Theformercanbesinteredatarelativelylowtemperatureof1120℃.CharacterizationbySEMshowedthatthegrainshapesofbothceramicsarecubical,thoughthegrainsizeoftheformerismuchsmaller.Dielectricconstantsmeasuredat20℃wereshowntovarywithfrequencyintherangefrom1kHzto2MHzanddcbiasfield,andfurtherthatthedielectriclossoftheformertobelessthan2×10-3inthefrequencyrangeof20kHzto1MHz,muchsmallerthanthatofthelattersample.Fortheformer,temperaturedependenceofdielectricconstantismuchflatterandthereexistsanextendedphasetransitiondiffusioncoveringawidetemperaturerangeofCurietemperatureTc.Thesmallergrainsizeoftheformerdepressesthedcbiaselectricalfielddependenceofdielectricconstant.Thetunabilityis7%underabiasfieldof0.6kV/mmdc.

简介：TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM)，传播电子显微镜学(TEM)，X光检查光电子光谱学(XPS)，X光检查衍射(XRD)，和荧光spectrophotometry。结果证明合成粒子有coremultishell结构，球形的形态学，和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应；为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高

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简介：3阶段的水动力学反的使流体化的床为不同液体和煤气的速度用低密度粒子试验性地被学习。水动力学特征学习了包括压力落下，最小的液体和气体使液化速度和阶段劫盗。用床压力坡度决定的最小的液体使液化速度，随气体的增加减少速度。液体劫盗沿着床高度增加的阶段劫盗表演的轴的侧面，而稳固的劫盗减少，击倒床。然而，煤气的劫盗在床上是几乎一致的。

简介：A3-DnonlinearproblemofsupercavitatingflowpastanaxisymmetricbodyatasmallangleofattackisinvestigatedbymeansoftheperturbationmethodandFourier-cosine-expansionmethod.Thefirstthreeorderperturbationequationsarederivedindetailandsolvednumericallyusingtheboundaryintegralequationmethodanditerativetechniques.Computationalresultsofthehydrodynamiccharacteristicsandcavityshapesofeachorderarepresentedfornonaxisymmetricsupercavitatingflowpastconeswithvariousapex-anglesatdiffer-entcavitationnumbers.Thenumericalresultsarefoundingoodagreementwithexperimentaldata.

简介：Soilconsolidationwouldinducevariationsofitstransportcoefficientssuchashydraulicconductivityanddiffusioncoefficient.Thispaperpresentsastudyoftheinfluenceofbarrierconsolidationontransportcoefficients,anda3Dtransportmodelbasedonmixturetheoryisproposedfordescribingthelinersthatinvolvecirculardefectsinthegeomembrane.TheelastoplasticALPHAmodelisrevisedbyusingthespatiallymobilizedplane(SMP)criterionforsimulatingthedeformationofthesoils.Then,the3Dmodelcouplingthenonlinearconsolidationandcontaminantadvection-diffusionissolvedusingthefiniteelementsoftwareABAQUS.Theresultsshowthattheimportanceofreducingthedefectsizeinthegeomembraneandthelinerporositytocontrolthecontaminantconcentrationincrease.

简介：TheIsodynetechniquebasedonthescatteredlightscanningfromathinlaserbeamcanbeusedtoobtaintheinformationinsidetheloadedobjectintheroomtemperaturenondestructively,soitisaverypowerfultechniquein3Dstressanalysis.Theproblemsarehowtointerprettheinformationandhowtogetsufficientinformationfromthefewinterferencefringe.Birefringencephaseshifttechniquecandistinguishthefringeordersautomaticallyandenrichtheinformationin256graylevelsbetweenmaximandminimlightintensity.InthepapertheIsodynebirefringencephaseshiftmethodwithanobliqueincidenceandequilibriumequationispresented,bywhichthe3DstressesinthemiddleplaneofaplatewithUshapenotchareseparatedsuccessfully.

简介：Basedonthegeneralconservationlawsincontinuummechanics,theEulerianandLagrangiandescriptionsofthejumpconditionsofshockwavesin3-dimensionalsolidswerepresentedrespectively.Theimplicationofthejumpconditionsandtheirrelationsbetweeneachother,particularlytherelationbetweenthemassconservationandthedisplacementcontinuity,werediscussed.Meanwhiletheshockwaveresponsecurvesin3-dimensionalsolids,i.e.theHugoniotcurveswereanalysed,whichprovidethefoundationforstudyingthecouplingeffectsofshockwavesin3-dimensionalsolids.

简介：The1/3subharmonicsolutionfortheDuffing'sequationisinvestigatedbyusingthemethodsofharmonicbalanceandnumericalintegration.Thesensitivityofparametervariationforthetransientprocessandthetransientprocessfortheperturbanceinitialconditionsarestudied.Overandabove,theprecisionofnumericalintegrationmethodisdiscussedandthenumericalintegrationmethodiscomparedwiththeharmonicbalancemethod.Finally,asymptoticalstabilityofthepuresubharmonicoscillationselementisinspected.

简介：Uniformlysizedα-Fe2O3hexagonalplateletsweresynthesizedbyahydrothermalprocessusingFe(OH)3suspensionandlargeamountofNaOH.ThereactionproductswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),selectedareaelectrondiffraction(SAED),andavibratingsamplemagnetometer(VSM).Theresultsshowthatthehexagonalplateletsarefine,monodisperseandconsistingofsingle-crystals.Themagnetichysteresis(M-H)curveofthesamplesmeasuredatroomtemperatureindicatesthattheα-Fe2O3micro-plateletsexhibitferromagneticbehaviorswithrelativelylowcoercivity.

简介：Becausemostpiezoelectricdeviceshaveinterfaceswithfluidinengineering,itisvaluabletostudythecoupledfieldbetweenfluidandpiezoelectricmedia.Asthefundamentalproblem,the3DGreen'sfunctionsforpointforcesandpointchargeloadedinthefluidandpiezoelectricbimaterialsarestudiedinthispaper.Basedonthe3Dgeneralsolutionsexpressedbyharmonicfunctions,weconstructedthesuitableharmonicfunctionswithundeterminedconstantsatfirst.Then,thecouplefieldinthefluidandpiezoelectricbimaterialscanbederivedbysubstitutionofharmonicfunctionsintogeneralsolutions.Theseconstantscanbeobtainedbyvirtueofthecompatibility,boundary,andequilibriumconditions.Atlast,thecharacteristicsoftheelectromechanicalcoupledfieldsareshownbynumericalresults.

简介：Thisletterobtainsatyphoon-likevortexsolutionbysolvingtheBragg-Hawthorneequation.ThesolutiondescribesspiralpathsoffluidmaterialelementontheBernoullisurface,whereassomenewexactsolutionsareobtainedwhichareboundedinthewholeregion.Thefirstoneisacontinuedumbrellavortexsolution,whichisatyphoon-likevortex.Thesecondoneisamulti-planarsolution,whichisperiodicinz-coordinate.Withineachlayer,thereisanumbrellavortexsolutionsimilartothefirstone.Theabove...

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简介：ThisstudypresentsanovelprocessofinsitusurfacemodificationofCaCChnanoparticlesusingamultipleorificedispersionmicroreactor.CO2/Ca（OH）2precipitationreactionwasemployedtoprepareCaCO3nanoparticleswithsodiumstearatesurfactant.SynthesizedCaCChproductswerecharacterizedbythermogravimetricanalysis（TGA）,infra-red（IR）,X-raydiffraction（XRD）,transmissionelectronmicroscopy（TEM）andBrunauer-Emmet-Telleranalysis（BET）.Theeffectofvariousoperationparametersonnanoparticlesandthedosageofsodiumstearateweredetermined.Theresultsshowedthatthepreparationprocesscouldbepreciselycontrolledwithefficientmasstransferprocess.Theparticleswerehighlyhydrophobicwithacontactangleof117andmonodispersewithanaveragesizeof30nm.Theadsorptionsofsodiumstearateandcalciumiononsolidparticlesduringtheinsitusurfacemodificationprocesswereinvestigated.

简介：AnovelmethodformodelingcellularmaterialsisproposedbasedonMATLABimageprocessingandsynchrotronX-raycomputedtomographyscanningtoobtainanaccuratecalculationresultofaluminumfoambasedonfiniteelementmodel.Themaximumentropyalgorithmisemployedtoobtainthebinarizationimage,andthemedianfilteringalgorithmisusedtoreducethenoiseafterbinarization.Theexternalcontourandinternalporesboundaryisextractedbythe"edge"functioninMATLAB,andthegeometricalmodelisreconstructed.Atwo-stepmeshalgorithmisadoptedtomeshthereconstructedgeometricalmodel.Accordingly,thefiniteelementmodelofaluminumfoamisestablishedbytheproposedmethodbasedonreconstructiongeometricalmodel.Thecompressionbehaviorofaluminumfoamisobtainedat25℃,100℃,200℃byABAQUS,andgoodagreementswithexperimentsareachievedbyapplyingthepresentreconstructionalgorithmandmodelingmethod.

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简介：3-degree-of-freedom(3-DOF)的一个新分析模型旋转罗盘加速表系统由一个1-DOF驱动器和2-DOF感觉模式组成被介绍。模型构造微分方程由向量分析与系统的每DOF联系了的lumped。因此建立的联合微分方程是为他们在时间和频率领域的回答的解决的经分解。就这些频率反应方程而言，新奇设备设计概念被强迫感觉阶段到零导出，它导致在结构的频率之间的某个关系，从而在系统的表演上引起抑制效果的最小化。而且，现在的旋转罗盘加速表结构的可行性在他们的事件为旋转罗盘行动和线性加速的察觉用一个唯一的差别对待的计划被学习。这个计划把旋转罗盘加速表的提出的解决的短暂解决方案与同步解调和过滤的进程相结合，它导致同相并且系统输出的照部件发信号。这二个部件能在尖运动和线性加速的察觉被利用。获得的分析结果被模拟在MATLAB/Simulink环境验证，并且结果在对对方的优秀同意，这被发现。

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