学科分类
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500 个结果
  • 简介:Nickelhydroxidewasusedasthepositiveelectrodematerialinrechargeablealkalinebatteries,whichplaysasignificantroleinthefieldofelectricenergystoragedevices.β-nickelhydroxide(β-Ni(OH)_2)waspreparedfromnickelsulphatesolutionusingpotassiumhydroxideasaprecipitatingagent.Pureβ-phaseofnickelhydroxidewasconfirmedfromXRDandFT-IRstudies.TheeffectsofTiO_2additiveontheβ-Ni(OH)_2electrodeperformanceareexamined.ThestructureandpropertyoftheTiO_2addedβ-Ni(OH)_2werecharacterizedbyXRD,TG-DTAandSEManalysis.Apasted–typeelectrodeispreparedusingnickelhydroxidepowderasthemainactivematerialonanickelsheetasacurrentcollector.Cyclicvoltammetryandelectrochemicalimpedancespectroscopystudieswereperformedtoevaluatetheelectrochemicalperformanceoftheβ-Ni(OH)_2andTiO_2addedβ-Ni(OH)_2electrodesin6MKOHelectrolyte.Anodic(Epa)andcathodic(Epc)peakpotentialsarefoundtodecreaseaftertheadditionofTiO2intoβ-Ni(OH)_2electrodematerial.Further,additionofTiO_2isfoundtoenhancethereversibilityoftheelectrodereactionandalsoincreasetheseparationoftheoxidationcurrentpeakoftheactivematerialfromtheoxygenevolutioncurrent.Comparedwithpureβ-Ni(OH)_2lectrode,TiO_2addedβ-Ni(OH)_2electrodeisfoundtoexhibithigherprotondiffusioncoefficient(D)andlowerchargetransferresistance.ThesefindingssuggestthattheTiO_2addedβ-Ni(OH)_2electrodepossessimprovedelectrochemicalpropertiesandthuscanberecognizedasapromisingcandidateforthebatteryelectrodeapplications.

  • 标签: NI(OH)2电极 TIO2光催化剂 电化学性能 电极性能 碱性电池 粘贴
  • 简介:Thermodynamicpropertiesandphasediagramsofamixedspin-(1,2)Isingferrimagneticsystemwithsingleionanisotropyonhexagonalnanowirearestudiedbyusingeffective-fieldtheorywithcorrelations.Thesusceptibility,internalenergyandspecificheatofthesystemarenumericallyexaminedandsomeinterestingphenomenainthesequantitiesarefound.TheeffectoftheHamiltonianparametersonphasediagramsareexaminedindetail.Besidessecond-orderphasetransition,linesoffirst-ordertransitionandtricriticalpointsarefound.Inparticular,wefoundthatforsomenegativevaluesofsingle-ionanisotropies,thereexistfirst-orderphasetransitions.

  • 标签: HEXAGONAL ISING NANOWIRE mixed spin-(1 2)
  • 简介:TheLHCDantennathatwillbeusedinHL-2AistheoriginaloneusedinHL-1M,whichwillbemodified.Wemeasuredthefeatureoftheantenna.Thefeaturesincludethereflectionofmainwaveguide,VSWR,theadjacentphrasingbetweenthesub-waveguidesandsoon.Thepaperdescribesthemeasuredresultsandspectrumcalculationbasedonthemeasuredparameters.FromtheworkswecanappreciateourantennacorrectlywhichwillbeusefulforLHCDexperimentonHL-2Aintheyear.

  • 标签: HL-2A LHCD 子波导 多节发射天线阵 波谱 数值计算
  • 简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.

  • 标签: 半导体光催化剂 可见光照射 Mott-Schottky图 P型 制氢 密度泛函理论
  • 简介:P-typenitrogen-dopedZnOfilmsarepreparedsuccessfullybyin-situthermaloxidationofZn_3N_2films.Thepreparedfilmsarecharacterizedbyx-raydiffraction,non-Rutherfordbackscattering(non-RBS)spectroscopy,xrayphotoelectronspectroscopy,andphotoluminescencespectrum.TheresultsshowthattheZn_3N_2filmsstarttotransformtoZnOat400°Candthetotalnitrogencontentdecreaseswiththeincreasingannealingtemperature.Thep-typefilmsareachievedat500℃withalowresistivityof6.33Ω·cmandahighholeconcentrationof+8.82×10~(17)cm~(-3),aswellasalowlevelofcarboncontamination,indicatingthatthesubstitutionalnitrogen(N_O)isaneffectiveacceptorintheZnO:Nfilm.ThephotoluminescencespectrashowclearUVemissionsandalsoindicatethepresenceofoxygenvacancy(V_O)defectsintheZnO:Nfilms.Thep-typedopingmechanismisbrieflydiscussed.

  • 标签: ZnO薄膜 薄膜制备 氮掺杂 热氧化 p型 原位
  • 简介:Carbonnanotubeswithjunctionsmayplayanimportantroleinfuturenanoelectronicsandfuturenanodevices.Inparticular,junctionsconstructedwithmetalandsemiconductingnanotubeshavepotentialapplications.Basedontheorthogonaltight-bindingmoleculardynamicsmethod,wepresentourstudyofthestructurestabilityofI-typecarbonnanotubejunctions.

  • 标签: 碳纳米管 结构稳定性 纳米器件
  • 简介:Thevolumeexpansionofthestuff(e.g.tobaccostem)isofgreatimportancetoanincreaseintheproductqualityandadecreaseintheproductioncost.Thispaterputsforwardthebasicconfigurationandtheexpansionmechanismofanewtypeofjetpressurizationevaporationexpansionapparatur.Bythethermodynamiccalculationoftheapparatus,wegivevariationsinsteampressureonvariouscrosssectionsoftheflowsystemfortheapparatus,manufactureasamplemachine,andfinishruntestsofthemachine.Thetestresultsshowthattheapparatusmaymaketherelativeincreaseinfillvalueoftobaccostemhigherthan75%,andmaycausethesteamconsumptionrequiredintheexpansionprocessofeachkilogramstemtoreducedabout40%comparedwithconventionalexpansionapparatus.Additionally,theconfigurationoftheapparatusissimpleandsmall,itscostofmanufactureisverylow,andbothitsoperationandmaintenanceareextremelyconvenient.

  • 标签: 喷射增压 汽化延伸仪器 延伸机制
  • 简介:Theauthorshaveinventedtheuniqueoceanwavepowerstation,whichiscomposedofthefloatingtypeplatformwithapairofthefloatsliningupattheintervalofonewavepitchandthecounter-rotatingtypewavepowerunit,itsrunnersaresubmergedintheseawateratthemiddlepositionoftheplatform.Suchprofilesmaketheflowvelocityattherunneristwicefasterthanthatofthetraditionalfixed/caissontypeOWC,ontheidealflowconditions.Besides,therunnerscounter-rotatetheinnerandtheouterarmaturesofthepeculiargenerator,respectively,andtherelativerotationalspeedisalsotwicefasterthanthespeedofthesinglerunner/armature.Suchcharacteristicsmaketherunnerdiameterlarge,namelytheoutputhigher,asrequested,becausethetorqueofthepowerunitneveractonthefloatingtypeplatform.Atthepreliminaryreseach,thispaperverifiestogetthepowerusingaWellstypesinglerunnerinstalledinthemodelstation.Therunnertakestheoutputwhichisaffectedbytheoscillatingamplitudeoftheplatform,therotationalspeedandtheinertiaforceoftherunner,etc.

  • 标签: 发电站 浮动式 海洋波浪 水电机组 浮式平台 配备
  • 简介:Wepresentintegral-typeDarbouxtransformationforthemKdVhierarchyandforthemKdVhierarchywithself-consistentsources.IncontrastwiththenormalDarbouxtransformation,theintegral-typeDarbouxtransformationscanoffernon-auto-Backlundtransformationbetweentwo(2n+1)-thmKdVequationswithself-consistentsourceswithdifferentdegrees.ThiskindofDarbouxtransformationenablesustoconstructtheN-solitonsolutionforthemKdVhierarchywithself-consistentsources.Wealsoproposetheformulasforthemtimesrepeatedintegral-typeDarbouxtransformationsforbothmKdVhierarchyandmKdVhierarchywithself-consistentsources.

  • 标签: 孤子方程 积分型Darboux变换 自洽源 非线性偏微分方程
  • 简介:我们建议黑暗精力(DE)的一种新类型模型,DEde的状态的方程在是部分精力密度de的简单功能而不是redshiftz。我们假定这种类型的三个DE模型,并且与现在的观察适合他们得到DE的限制,它也与CPL模型相比。一个合适的de(de)模型能给,这被显示出更小2或de的更小的错误比CPL的当模特儿。DE模型的这种新类型能帮助学习DE的必要性质和性质。

  • 标签: 能量模型 观测 能量密度 状态方程 模型误差 CPL
  • 简介:WestudyspectroscopicsignaturesofamonochromaticbosonmodeinteractingwithaT-shapedoublequantumdotcoupledbetweenthemetallicandsuperconductingleads.Focusingonaweakinterdotcoupling,wefindthattheproximityeffecttogetherwiththebosonicmodeareresponsiblefortheseriesofFano-typeresonancesappearingsimultaneouslyatnegativeandpositiveenergies.WeinvestigatetheseinterferometricfeaturesanddiscusstheirinfluenceonthesubgapAndreevconductancetakingintoaccountthecorrelationeffectsdrivenbytheCoulombrepulsion.

  • 标签: 玻色子 共振 模式法 电导 诱导 光谱特征
  • 简介:Ba1.0Co0.7Fe0.2Nb0.1O3-δ(BCFN)oxidewithperovskitecubicstructurewassynthesizedbysolidstatereactionmethod.CO2corrosionofBCFNmembranewasinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),diffusereflectanceinfraredFouriertransformedspectroscopy(DRIFT)andX-rayabsorptionfinestructurespectroscopy(XAFS).Cobalt(Co)K-edgeabsorptionspectraofBCFNannealedinCO2revealthattheoxidationstatesofCoinallthesampleswerelargerthan+3andtheydecreasedwiththeincreaseofcalcinationtime.At800℃,1%CO2introducedintoHecouldspeedupthereductionofCocationsincomparisonwithpureHe.Inaddition,sulfateionsinthebulkofBCFNmembranepreferredtomigratetothesurfaceunderCO2calcinationandformmonoclinicBa(CO3)0.9(SO4)0.1besidesorthorhombicwitherite.Moreover,SEMresultsindicatethatthenucleationandgrowthofcarbonatesgrainsstartedatthegrainboundaryofthemembrane.

  • 标签: 钙钛矿型氧化物 CO2 氧化态 组织演变 退火 X射线吸收精细结构
  • 简介:InthisworkweanalyzethecharacteristicsofquantumentangleinentoftheDiracfieldinnoninertialreferenceframesinthecontextofanewtypepseudo-purestate,whichiscomposedoftheBellstates.Thiswillhelpustounderstandtherelationshipbetweentherelativityandquantuminformationtheory.SomestateswillbechangedfromentangledstatesintoseparableonesaroundthecriticalvalueF=1/4,butthereisnosuchacriticalvalueforthevariableyrelatedtoaccelerationa.WefindthatthenegativityNas(ρ^TAAB1)increaseswithFbutdecreaseswiththevariabley、whilethevariationofthenegativityNb1b11(ρ^TB1B1B11)isoppositetothatofthenegativityNAB1(ρ^TAAB1).WealsostudythevonNeumannentropiesS(ρAB1)andS(ρB1B11)、WefindthattheS(ρAB1)increaseswithvariableybutS(ρB1B11)isindependentofit.However,bothS(ρAB1)andS(ρB1B11)firstdecreaseswithFandthenincreaseswithit.TheconcurrencesC(ρAB1)andC(ρB1B11)arealsodiscussed.WefindthattheformerdecreaseswithywhilethelatterincreaseswithybutbothofthemfirstincreasewithFandthendecreasewithit.

  • 标签: NEGATIVITY pseudo-pure state noninertial frame ENTANGLEMENT
  • 简介:WeobservetheAutler-Townessplittingeffectina△-typequantumthree-levelsystem,usingthelowestthreelevelsofaSQUID-typeAl/AlOx/Altransmonqubitembeddedinathree-dimensionalcoppermicrowavecavity.Acontroltoneatdifferentstrengthsisappliedinresonancewiththetransitionbetweenthefirstandsecondexcitedstates,whilethespectrabetweeneachofthemandthegroundstateareprobedbyanothermicrowavetone.Theexperimentalresuitshowsthedifferencebetweenthetwospectra,andfitswellwiththeLindbladmasterequationmodel.

  • 标签: 三能级系统 量子 分裂型 铝/氧化铝 光谱差异 微波谐振腔
  • 简介:我们为产生一种类型建议一个计划在洞证完的四原子的纠缠的状态。在现在的计划,原子同时交往与一高度有强壮的古典域的帮助的detuned洞模式。计划对洞腐烂和热地感觉迟钝,它具有从试验性的观点的重要性。

  • 标签: 腔QED技术 原子纠缠态 原子相互作用 经典场