简介:Nickelhydroxidewasusedasthepositiveelectrodematerialinrechargeablealkalinebatteries,whichplaysasignificantroleinthefieldofelectricenergystoragedevices.β-nickelhydroxide(β-Ni(OH)_2)waspreparedfromnickelsulphatesolutionusingpotassiumhydroxideasaprecipitatingagent.Pureβ-phaseofnickelhydroxidewasconfirmedfromXRDandFT-IRstudies.TheeffectsofTiO_2additiveontheβ-Ni(OH)_2electrodeperformanceareexamined.ThestructureandpropertyoftheTiO_2addedβ-Ni(OH)_2werecharacterizedbyXRD,TG-DTAandSEManalysis.Apasted–typeelectrodeispreparedusingnickelhydroxidepowderasthemainactivematerialonanickelsheetasacurrentcollector.Cyclicvoltammetryandelectrochemicalimpedancespectroscopystudieswereperformedtoevaluatetheelectrochemicalperformanceoftheβ-Ni(OH)_2andTiO_2addedβ-Ni(OH)_2electrodesin6MKOHelectrolyte.Anodic(Epa)andcathodic(Epc)peakpotentialsarefoundtodecreaseaftertheadditionofTiO2intoβ-Ni(OH)_2electrodematerial.Further,additionofTiO_2isfoundtoenhancethereversibilityoftheelectrodereactionandalsoincreasetheseparationoftheoxidationcurrentpeakoftheactivematerialfromtheoxygenevolutioncurrent.Comparedwithpureβ-Ni(OH)_2lectrode,TiO_2addedβ-Ni(OH)_2electrodeisfoundtoexhibithigherprotondiffusioncoefficient(D)andlowerchargetransferresistance.ThesefindingssuggestthattheTiO_2addedβ-Ni(OH)_2electrodepossessimprovedelectrochemicalpropertiesandthuscanberecognizedasapromisingcandidateforthebatteryelectrodeapplications.
简介:Thermodynamicpropertiesandphasediagramsofamixedspin-(1,2)Isingferrimagneticsystemwithsingleionanisotropyonhexagonalnanowirearestudiedbyusingeffective-fieldtheorywithcorrelations.Thesusceptibility,internalenergyandspecificheatofthesystemarenumericallyexaminedandsomeinterestingphenomenainthesequantitiesarefound.TheeffectoftheHamiltonianparametersonphasediagramsareexaminedindetail.Besidessecond-orderphasetransition,linesoffirst-ordertransitionandtricriticalpointsarefound.Inparticular,wefoundthatforsomenegativevaluesofsingle-ionanisotropies,thereexistfirst-orderphasetransitions.
简介:TheLHCDantennathatwillbeusedinHL-2AistheoriginaloneusedinHL-1M,whichwillbemodified.Wemeasuredthefeatureoftheantenna.Thefeaturesincludethereflectionofmainwaveguide,VSWR,theadjacentphrasingbetweenthesub-waveguidesandsoon.Thepaperdescribesthemeasuredresultsandspectrumcalculationbasedonthemeasuredparameters.FromtheworkswecanappreciateourantennacorrectlywhichwillbeusefulforLHCDexperimentonHL-2Aintheyear.
简介:
简介:
简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.
简介:P-typenitrogen-dopedZnOfilmsarepreparedsuccessfullybyin-situthermaloxidationofZn_3N_2films.Thepreparedfilmsarecharacterizedbyx-raydiffraction,non-Rutherfordbackscattering(non-RBS)spectroscopy,xrayphotoelectronspectroscopy,andphotoluminescencespectrum.TheresultsshowthattheZn_3N_2filmsstarttotransformtoZnOat400°Candthetotalnitrogencontentdecreaseswiththeincreasingannealingtemperature.Thep-typefilmsareachievedat500℃withalowresistivityof6.33Ω·cmandahighholeconcentrationof+8.82×10~(17)cm~(-3),aswellasalowlevelofcarboncontamination,indicatingthatthesubstitutionalnitrogen(N_O)isaneffectiveacceptorintheZnO:Nfilm.ThephotoluminescencespectrashowclearUVemissionsandalsoindicatethepresenceofoxygenvacancy(V_O)defectsintheZnO:Nfilms.Thep-typedopingmechanismisbrieflydiscussed.
简介:Carbonnanotubeswithjunctionsmayplayanimportantroleinfuturenanoelectronicsandfuturenanodevices.Inparticular,junctionsconstructedwithmetalandsemiconductingnanotubeshavepotentialapplications.Basedontheorthogonaltight-bindingmoleculardynamicsmethod,wepresentourstudyofthestructurestabilityofI-typecarbonnanotubejunctions.
简介:Thevolumeexpansionofthestuff(e.g.tobaccostem)isofgreatimportancetoanincreaseintheproductqualityandadecreaseintheproductioncost.Thispaterputsforwardthebasicconfigurationandtheexpansionmechanismofanewtypeofjetpressurizationevaporationexpansionapparatur.Bythethermodynamiccalculationoftheapparatus,wegivevariationsinsteampressureonvariouscrosssectionsoftheflowsystemfortheapparatus,manufactureasamplemachine,andfinishruntestsofthemachine.Thetestresultsshowthattheapparatusmaymaketherelativeincreaseinfillvalueoftobaccostemhigherthan75%,andmaycausethesteamconsumptionrequiredintheexpansionprocessofeachkilogramstemtoreducedabout40%comparedwithconventionalexpansionapparatus.Additionally,theconfigurationoftheapparatusissimpleandsmall,itscostofmanufactureisverylow,andbothitsoperationandmaintenanceareextremelyconvenient.
简介:Theauthorshaveinventedtheuniqueoceanwavepowerstation,whichiscomposedofthefloatingtypeplatformwithapairofthefloatsliningupattheintervalofonewavepitchandthecounter-rotatingtypewavepowerunit,itsrunnersaresubmergedintheseawateratthemiddlepositionoftheplatform.Suchprofilesmaketheflowvelocityattherunneristwicefasterthanthatofthetraditionalfixed/caissontypeOWC,ontheidealflowconditions.Besides,therunnerscounter-rotatetheinnerandtheouterarmaturesofthepeculiargenerator,respectively,andtherelativerotationalspeedisalsotwicefasterthanthespeedofthesinglerunner/armature.Suchcharacteristicsmaketherunnerdiameterlarge,namelytheoutputhigher,asrequested,becausethetorqueofthepowerunitneveractonthefloatingtypeplatform.Atthepreliminaryreseach,thispaperverifiestogetthepowerusingaWellstypesinglerunnerinstalledinthemodelstation.Therunnertakestheoutputwhichisaffectedbytheoscillatingamplitudeoftheplatform,therotationalspeedandtheinertiaforceoftherunner,etc.
简介:Wepresentintegral-typeDarbouxtransformationforthemKdVhierarchyandforthemKdVhierarchywithself-consistentsources.IncontrastwiththenormalDarbouxtransformation,theintegral-typeDarbouxtransformationscanoffernon-auto-Backlundtransformationbetweentwo(2n+1)-thmKdVequationswithself-consistentsourceswithdifferentdegrees.ThiskindofDarbouxtransformationenablesustoconstructtheN-solitonsolutionforthemKdVhierarchywithself-consistentsources.Wealsoproposetheformulasforthemtimesrepeatedintegral-typeDarbouxtransformationsforbothmKdVhierarchyandmKdVhierarchywithself-consistentsources.
简介:WestudyspectroscopicsignaturesofamonochromaticbosonmodeinteractingwithaT-shapedoublequantumdotcoupledbetweenthemetallicandsuperconductingleads.Focusingonaweakinterdotcoupling,wefindthattheproximityeffecttogetherwiththebosonicmodeareresponsiblefortheseriesofFano-typeresonancesappearingsimultaneouslyatnegativeandpositiveenergies.WeinvestigatetheseinterferometricfeaturesanddiscusstheirinfluenceonthesubgapAndreevconductancetakingintoaccountthecorrelationeffectsdrivenbytheCoulombrepulsion.
简介:Ba1.0Co0.7Fe0.2Nb0.1O3-δ(BCFN)oxidewithperovskitecubicstructurewassynthesizedbysolidstatereactionmethod.CO2corrosionofBCFNmembranewasinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),diffusereflectanceinfraredFouriertransformedspectroscopy(DRIFT)andX-rayabsorptionfinestructurespectroscopy(XAFS).Cobalt(Co)K-edgeabsorptionspectraofBCFNannealedinCO2revealthattheoxidationstatesofCoinallthesampleswerelargerthan+3andtheydecreasedwiththeincreaseofcalcinationtime.At800℃,1%CO2introducedintoHecouldspeedupthereductionofCocationsincomparisonwithpureHe.Inaddition,sulfateionsinthebulkofBCFNmembranepreferredtomigratetothesurfaceunderCO2calcinationandformmonoclinicBa(CO3)0.9(SO4)0.1besidesorthorhombicwitherite.Moreover,SEMresultsindicatethatthenucleationandgrowthofcarbonatesgrainsstartedatthegrainboundaryofthemembrane.
简介:InthisworkweanalyzethecharacteristicsofquantumentangleinentoftheDiracfieldinnoninertialreferenceframesinthecontextofanewtypepseudo-purestate,whichiscomposedoftheBellstates.Thiswillhelpustounderstandtherelationshipbetweentherelativityandquantuminformationtheory.SomestateswillbechangedfromentangledstatesintoseparableonesaroundthecriticalvalueF=1/4,butthereisnosuchacriticalvalueforthevariableyrelatedtoaccelerationa.WefindthatthenegativityNas(ρ^TAAB1)increaseswithFbutdecreaseswiththevariabley、whilethevariationofthenegativityNb1b11(ρ^TB1B1B11)isoppositetothatofthenegativityNAB1(ρ^TAAB1).WealsostudythevonNeumannentropiesS(ρAB1)andS(ρB1B11)、WefindthattheS(ρAB1)increaseswithvariableybutS(ρB1B11)isindependentofit.However,bothS(ρAB1)andS(ρB1B11)firstdecreaseswithFandthenincreaseswithit.TheconcurrencesC(ρAB1)andC(ρB1B11)arealsodiscussed.WefindthattheformerdecreaseswithywhilethelatterincreaseswithybutbothofthemfirstincreasewithFandthendecreasewithit.
简介:WeobservetheAutler-Townessplittingeffectina△-typequantumthree-levelsystem,usingthelowestthreelevelsofaSQUID-typeAl/AlOx/Altransmonqubitembeddedinathree-dimensionalcoppermicrowavecavity.Acontroltoneatdifferentstrengthsisappliedinresonancewiththetransitionbetweenthefirstandsecondexcitedstates,whilethespectrabetweeneachofthemandthegroundstateareprobedbyanothermicrowavetone.Theexperimentalresuitshowsthedifferencebetweenthetwospectra,andfitswellwiththeLindbladmasterequationmodel.