简介:利用角分辨紫外光电子谱对乙烯和乙炔气体在Ru(1010)表面的吸附及与K的共吸附的研究结果表明:当衬底温度超过200K,乙烯即发生脱氢反应,σCH和σCC能级均向高结合能方向移动。在室温下,σCH和σCC能级位置与乙炔在Ru(1010)表面的吸附时的分子能级完全一致。乙烯发生脱氢反应后的主要产物为乙炔。衬底温度从120K到室温,Ru(1010)表面上乙炔的σCH和σCC能级均未发现变化。室温下乙炔仍然可以在Ru(1010)表面以分子状态稳定吸附。在有K的Ru(1010)表面上,室温时σCC谱峰几乎。碱金属K的存在促进了乙炔的分解。
简介:Carbonnanotube(CNT)-supportedRunanoparticleswithmeansizesrangingfrom2.3to9.2nmwerepreparedbydifferentpost-treatmentsandstudiedforFischer-Tropsch(FT)synthesis.TheeffectsofRuparticlesizeoncatalyticbehaviorswereinvestigatedatbothshorterandlongercontacttimes.Atshortercontacttime,wherethesecondaryreactionswereinsignificant,theturnoverfrequency(TOF)forCOconversionwasdependentonthemeansizeofRuparticles;TOFincreasedwiththemeansizeofRuparticlesfrom2.3to6.3nmandthendecreasedslightly.Atthesametime,theselectivitiestoC5+hydrocarbonsincreasedgraduallywiththemeansizeofRuparticlesupto6.3nmandthenkeptalmostunchangedwithafurtherincreaseinRuparticlesize.Atlongercontacttime,C10-C20selectivityincreasedsignificantlyattheexpenseofC21+selectivity,suggestingtheoccurrenceoftheselectivehydrocrackingofC21+toC10-C20hydrocarbons.
简介:墨玉祥云,雅致外观HPMINI1010TU的机身外壳采用流行的膜内漾印技术,黑色如墨玉般的顶盖上印着不规则的祥云暗纹,雅致的外观让它脱俗于变幻不定的流行风潮,发散出中国风情的艺术品味。外观尺寸方面MINI1010与一般上网笔记本大小相
简介:Polyamide-1010sampleswereirradiatedinvacuumatroomtemperaturebyCobalt-60γ-rays.Thefreeradicalsformedinirradiationwerestudiedbymeansofelectronspinresonance(ESR)techniques.TheESRspectraconsistedofaquartetandasuperimposedsingletwhichwereattributedtoradical-CO-NH-CH-CH2and-CH2-C=O,respectively.TheeffectsoftemperatureandcrystaUinityontheradicalswerediscussedandthemechanismfortheproductionanddecayoftheradicalswasalsoproposed.