简介：Thedevelopmentofthehydrogenelectrodeisvitalfortheapplicationofalkalinepolymerelectrolytefuelcells(APEFCs).Inthisstudy,aseriesofNi(OH)2decoratedNi/Ccatalysts(Ni(OH)2-Ni/C)werepreparedbyathree-stepelectrochemicaltreatmentofNi/C.TheexistenceofNi(OH)2wasdemonstratedbyX-rayphotoelectronspectroscopy(XPS),andthesurfacemolarratioofNi(OH)2/Niofthesampleswasestimatedviaanelectrochemicalmethod.TheHORcatalyticactivityofthecatalystswasevaluatedbyarotationdiskelectrode(RDE)method,anda'volcanoplot'wasestablishedbetweentheHORexchangecurrent(j0)andthesurfacemolarratioofNi(OH)2/Ni.Ontopofthe'volcano',thesurfacemolarratioofNi(OH)2/Niis1.1:1,thej0ofwhichwas6.8timesofthatofNi/C.ThestabilityofthesamplestowardHORwasevaluatedtobegood.OurstudyaddedasystematicexperimentalevidencetotheHORresearch,showingthattheHORcatalyticactivityofNicanbedeliberatelycontrolledviadecorationofNi(OH)2,whichmayhelpunderstandingtheHORmechanismonNi.

简介：由Synechcoccus在Ni的简历累积上影响因素在这篇论文被学习。当到干燥重量集中ofSynechcoccus的Ni的集体比率是16-18%时，简历累积在附近是在水的solution.Bioaccumulation数量的80min的Ni的使平衡时间到达了最大值。Bioaccumulation数量与增加pH增加了。最佳pHwas9-10和更高的pH导致了Ni的降水(哦)_2。Bioaccumulation数量被在35℃到达他们的optima的温度和轻紧张也影响，无生命的水藻的3000Ixrespectively.Bioaccumulation比生活水藻的大。

简介：用浸渍法制备了一系列含镍的催化剂，以ＴＰＲ、ＴＰＤ、ＸＲＤ及ＸＰＳ等手段分别对Ｎｉ／海泡石及Ｎｉ／Ｓｍ海泡石催化剂进行了表征。结果表明，助剂钐的加入不仅使镍粒变小，而且也降低了镍原子结合能，除此以外，镍的分散亦有提高。ＴＰＲ与ＴＰＤ测试表明钐的加入亦能引起峰温的变化。更多还原

简介：HomogeneousNi2+-dopedtitaniagelwassynthesizedbyasol-gelprocess,andthexerogelwasthenobtainedthroughaginganddrying,leadingtotheformationofNi/TiO2nanocompositeafterheattreatmentunderasuitablereducingatmosphere.TheresultingnanocompositewascharacterizedbyTGA-DSC,TEM,XRDandBETmethods.Theresultsshowthatthestructureandgrainsizeofthenanocompositescouldbemanipulatedbyalteringtheheat-treatmentconditions,andthatthenanocompositepossessesamesoporousstructurewithaporeradiusofca.28nmandaspecifictheanatase-rutilephasetransformation.

简介：Threetypesofcarbonnano-onions（CNOs）includingNi@CNOs.Fe3C@CNOsandFe0.64Ni0.36@CNOsnanoparticleshavebeensynthesizedbycatalyticdecompositionofmethaneat850℃usingnickel,ironandiron-nickelalloycatalysts.Comparativeandsystematicstudieshavebeencarriedoutonthemorphology,structuralcharacteristicsandgraphiticcrystallinityoftheseCNOsproducts.Furthermore,theelectrochemicalhydrogenstoragepropertiesofthreetypesofCNOshavebeeninvestigated.MeasurementsshowthattheNi@CNOshavethehighestdischargecapacityof387.2mAh/g,coiTespondingtoahydrogenstorageof1.42%.ThiscomparisonstudyshowstheadvantagesofeachcatalystinthegrowthofCNOs.enablingthecontrollablesynthesisandtuningthepropertiesofCNOsbymediatingdifferentmetalsandtheiralloyforusinginthefuelcellsystem.

简介：金属V作为贮氢材料具有良好的增压性能因而在ICF靶丸制备工艺中备受关注，但是金属V难活化，严重影响了其在增压材料方面的应用。为了改善金属V的活化性能，向金属V中掺杂少量的金属Ni以期达到对其改性和改善其贮氢性能的目的。

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简介：Ｎｉ／Ｍｏ２ＮａｓａＨｉｇｈｌｙＡｃｔｉｖｅＨｙｄｒｏｄｅｎｉｔｒｏｇｅｎａｔｉｏｎＣａｔａｌｙｓｔＮｉ／Ｍｏ２ＮａｓａＨｉｇｈｌｙＡｃｔｉｖｅＨｙｄｒｏｄｅｎｉｔｒｏｇｅｎａｔｉｏｎＣａｔａｌｙｓｔ￥ＷｅｎＹｕＺＨＡＮＧ；ＸｉｎＰｉｎｇＷＡＮＧ；...

简介：HydrotalciteprecursorsofLamodifiedNi-Al2O3andNi-SiO2catalystspreparedbyco-precipitationmethodandthecatalyticactivitieswereexaminedfortheproductionofCOx-freeH2byCH4decomposition.Physico-chemicalcharacteristicsoffresh,reducedandusedcatalystswereevaluatedbyXRD,TPRandO2pulsechemisorptions,TEMandBET-SAtechniques.XRDstudiesshowedphasesduetohydrotalcite-likeprecursorsinovendriedformproduceddispersedNiOspeciesuponcalcinationinstaticairabove450C.Ramanspectraofdeactivatedsamplesrevealedthepresenceofbothorderedanddisorderedformsofcarbon.Ni-La-Al2O3catalystwithamoleratioofNi:La:Al=2:0.1:0.9exhibitedtremendouslyhighlongevitywithahydrogenproductionrateof1300molH2mol1Ni.AdirectrelationshipbetweenNimetalsurfaceareaandhydrogenyieldswasestablished.

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简介：ThepartialoxidationofethanoltohydrogenwasinvestigatedoverNi/Fe/Lacatalystspreparedbytheco-precipitationmethod.TheeffectsofintroductionofLapromoterandthereactiontemperatureonthecatalyticperformancewerestudied.ItwasfoundthattheintroductionofLaintoNi/Fecatalystsishelpfultoincreasetheselectivitytohydrogenandthestabilityofthecatalysts.TheresultsofXRDandXPScharacterizationshowthatthestructureofthecatalystwaschangedduringthereaction.TheexistenceofLaFeO3speciesispossiblythemainreasonoftheincreaseofthecatalyststability.

简介：当考虑热传导时，阶段地建模途径被用来学习纯Ni的氧化行为。在这计算，温度T上的Cahn-Hilliard方程Lc的系数的依赖被考虑。到这个目的，为纯Ni当模特儿的高温度的氧化实验和阶段地在600点在气压下面在空中被执行，700，并且\(800\，^{\circ}\hbox{C}\)。氧化率被thermogravimetry测量，在这些温度的Lc经由交互算法是坚定的。与Lc\({构造的-}T\)关系，Ni的氧化行为当考虑热时，传导被调查。氧化度，氧化物电影厚度，和特定的重量获得上的温度边界的影响被讨论。当模特儿的途径在这研究建议了的阶段地将给氧化抵抗分析的一些热点和热保护材料的冷却措施设计。

简介：AMonteCarlosimulation,withtheenergeticsdescribedbytheembeddedatommethod,hasbeenemployedtostudythephysicalbehaviourofboronatomsduringrelaxationoftheNi3AlBxgrainboundary,IthasalsobeenusedtocalculatenotonlythepeakconcentrationsofNiandBandthevalleyconcentrationofAlatthegrainboundary,butalsothedependenceofthegrainboundarycohesionontheBbulkconcentration.DuringrelaxationofimpureNi3Algrainboundaries,wesuggestthat,asthesegregatingspecies,theBatomseitherinsertintointersticesinthegrainboundaryorsubstituteNiatoms.Meanwhile,astheinducingspecies,theyinduceNiatomstosubstituteforAlatoms.Calculationsshowthatintheequilibrium,whentheBbulkconcentrationxincreasesfrom0.1to0.9thepeakconcentrationofBincreases,thepeakconcentrationofNimaximizeswhilethevalleyconcentrationofAlminimizesatx=0.5,Thecalculationsalsoshowthebestcohesionofthegrainboundaryatx=0.5。

简介：Asamemberof1Dnanostructuredmaterials,theferromagneticandnonmagneticmultilayernanowiresexhibittremendouspotentialapplicationsinmanyfieldsduetotheiruniquemagneticandelectricalproperties.Thebasicpropertyofmultilayernanowirearrays,suchascoercivity,iscrucialimportantforthefutureapplication.Inordertoobtainthecoercivityinformation,besidesdirectlymeasuringitthroughexperiment,theoreticalcalculationalsoprovidesausefulandfastwaytoevaluatethemultilayer’scoervicity.Fig.1(a)and(b)demonstrateasinglemultilayernanowireandnanowirearraysembodiedinamatrix,respectively.Inthiswork,byimprovingPant’smodel,wedevelopedthenewmodelandsuccessfullypredictedtherelationshipbetweenthecoercivitychangingofCu/Nimultilayernanowirearraysandstructualparameters.Fig.

简介：AdsorptionofhydrogenmoleculesonanNi-doped(8,0)single-walledcarbonnanotube(SWNT)isinvestigatedbyusingfirst-principlesdensityfunctionalcalculations.TheresultshowsthatasingleNiatomadsorbedonthebridgesiteofthetubecouldcannotdissociatetheH2,howeveritcanchemisorbthreeH2atmost,withtheaveragebindingenergyperH2suitableforthehydrogenstorageattheroomtemperature.MoreH2wouldphysisorbaroundanNiatomweakly.AsfortheSWNTwithanNidimeradsorbed,wefindthatwhentheH2approachestheNi-Nibond,itdissociateswithoutovercominganybarrierandmakesbondswithNiatom.

简介：Immobilizingbiocomponentsonsolidsurfacesisacriticalstepinthedevelopmentofnewdevicesforfuturebiological,medical,andelectronicapplications.Therefore,numerousintegratedfilmswererecentlydevelopedbyimmobilizingdifferentproteinsorenzymesonelectrodesurfaces.Inthiswork,hemeproteinsweresafelyimmobilizedontomacroporousnickel-basedelectrodeswhilemaintainingtheirfunctionality.Suchmodifiedelectrodesshowedinterestingpseudo-capacitivebehavior.Amonghemeproteins,hemoglobin(Hb)filmhasahigherelectrochemicalperformanceandgreatercharge/dischargecyclingstabilitythanmyoglobin(Mb)andcytochromeC(CytC).Thehemegroupinanalkalinemediumcouldinducetheformationofsuperoxidesontheelectrodesurface.Thesecapacitivefeaturesofhemeprotein-NielectrodewererelatedtostrongbindingsitesbetweenhemeproteinsandporousNielectrode,theaccumulationofsuperoxideorradicalsontheNisurface,andfacileelectrontransferandelectrolytediffusionthroughthethree-dimensionalmacroporousnetwork.Thus,thesenewprotein-basedsupercapacitorshavepotentialuseinfree-standingplatformtechnologyforthedevelopmentofimplantableenergy-storagedevices.

简介：一个各向异性的micromechanics模型基于相等的包括方法被开发调查基于Ni的单个水晶superalloys的rafting方向。micromechanical模型考虑实际立方的结构和直角的anisotropy性质。当适用时，在micromechanical模型的不同包括的von协定压力，有弹性的紧张精力密度，和静水力学的压力被计算一张力或压缩装载[001]方向。计算结果能成功地为展出的合金预言rafting方向一积极或否定失配，它与能接受的试验性、理论的研究一致。而且，矩阵的有弹性的经常的差别和失配度并且猛抛rafting方向上的阶段和他们的影响小心地被讨论。

简介：Wehaveshownthat,incontrasttotheresultsintheliterature,theBraggpeakintensityofNi80Fe20/Cusuperlatticesisenhancedattheincidentx-rayenergyslightlyhigherthantheabsorptionedgeoftheheavierelement(Cu).TheatomicdensityatNi80Fe20/Cuinterfacewasanalysedbythediffractionanomalousfinestructuretechnologywiththeincidentangleofx-rayfixedatthefirstBraggpeak.OurresultsdemonstratetheepitaxygrowthofNi80Fe20/Cusuperlattices.Uponannealing,theepitaxityofNi80Fe20/Cumultilayersbecomespoorbutthelocalcrystallinityineachlayerisimproved.

简介：Thecrystalstructureof[Ni（TAAB）（py）2]（BF4）2,whereTAABisthetetradentatemacrocyclicligandtetrabenzo[b,f,j,n][1,5,9,13]tetraazacyclohexadecine,hasbeendeterminedfromX-raydiffractionanalysis.Thecrys.taibeiongstomonoclinic,spacegroupP21/nwithcellparameters

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