简介：Twooxo-vanadium(IV)complexes,[VO(C2O4)(2,2′-bipy)(H2O)]·C2H5OH(1)andVO(C2O4)(phen)(H2O)(2),where2,2′-bipy=2,2′-bipyridyl,phen=1,10-phenanthroline,weresynthesizedaspotentialfunctionalmodelsofvanadiumhaloperoxidases(VHPOs)inmixedsolventofethanolandwateratroomtemperature.Thecomplexeswerecharacterizedbyelementalanalysis,infrared(IR),UV-VisandX-raycrystallography.Structuralanalysesshowedthatvanadiumatomwascoordinatedbyaterminaloxygen,oneoxygenatomfromcoordinatedwater,twooxygenatomsfromthecarboxylategroupofoxalicacid,andtwonitrogenatoms(N1andN2)from2,2′-bipy/phen.Centralvanadiumatomsincomplexes1and2werebothinadistorted-octahedralenvironment,andsomeintermolecularhydrogenbondinglinkageswerealsoobservedineachcomplex.BrominationreactionactivityofthetwocomplexeswasevaluatedwithphenolredasorganicsubstrateinthepresenceofH2O2,Br-andphosphatebuffer,indicatingthattheycanbeconsideredasapotentialfunctionalmodelofVHPO.Inaddition,thermalanalysiswasalsoperformedanddiscussedindetail.
简介：我们证明复杂c0上的每个2-homogeneous多项式有一个唯一的标准保存扩展到它的双性人双ℓ∞。
简介：Thispaperreportstwolanthanidecomplexesofformula（C9H7）Ln（C8H8）·（THF）2whereLnisProrNd,C9H7isindenyl,andC8H8iscyclooctatetraene（COT）.ThecomplexeswerepreparedbythereactionofLnCl3withK（C9H7）andK2（C8H8）inTHF.（C9H7）Pr（C8H8）·（THF）2crystallizesinTHFat-15℃inthemonoclinicspacegroupP21:withunitcelldimensionsa=8.446（0）,b=10.083（2）,c=13.407（3）,β=105.48（1）°,V=1100.43（35）3,Dc=1.52g/cm3andZ=2.ThefinalRvalueis0.033,Rwvalueis0.030,respectively.In（C9H7）Pr（C8H8）·（THF）2afive-memberedringcentroidofC9H7,theC8H8ringcentroidandthetwooxygenatomsfromthetwoTHFmoleculesformadistortedtetrahedralgeometryaroundthemetal.
简介：Thecrystalandmolecularstructuresof[(C3H7O)2PS2]2(CCDCNo.217201)weredeterminedbymeansofX-raycrystallography.ItcrystallizedinatriclinicsystemwithspacegroupP1^-andlatticeparametersa=0.82794(3)nm,b=0.84764(2)nm,c=0.85034(3)nm,α=97.78(3)°β=110.77(3)°,γ=94.95(3)°,V=0.54701(9)nm^3,Z=1.Inthismolecule,thetwodiisopropyldithiophosphategroups,[(C3H7O)2PS2]2,whichareparalleltoeachother,arelinkedbyanS--Sbondandthereexistinversioncentersinthemolecule,Inthestructure,theP=Sbondsinthetwodithiophosphateunitsaretrans-orientedtoeachother.
简介：Halfsandwichirondicarbonylcomplex[η5-C5H3(t-Bu)2]Fe(CO)2Cl(1)reactswith1,2-dilithiumdiselenocarboraneLi2Se2C2B10H10(2)togiveabinuclearironcarboranecomplex[η5-C5H3(t-Bu)2]2Fe2(CO)3*Se2C2B10H10(3).TheX-raydiffractionanalysisofcomplex3revealsthatoneoftheironatomsischiral.
简介：AnefficientmethodforC2nearlyarc-lengthparameterizedcurveispresented.Anideaofapproximationforthearc-lengthfunctionofparametriccurvewhichinterpolatesCADdatapointsisdiscussed.Theparameterizationisimplementedbyusingparametertransformation.Finally,twonumericalexamplesaregiven.
简介：Theroleofpulseparametersonnanoparticlepropertyisinvestigatedself-consistentlybasedonacoupleoffluidmodelandaerosoldynamicsmodelinacapacitivelycoupledparallel-plateacetylene(C2H2)discharge.Inthismodel,themasscontinuityequation,momentumbalanceequation,andenergybalanceequationforneutralgasaretakenintoaccount.Thus,thethermophoreticforceariseswhenagastemperaturegradientexists.Thetypicalresultsofthismodelarepositiveandnegativeiondensities,electronimpactcollisionsrates,nanoparticledensity,andchargedistributions.Thesimulationisperformedfordutyratio0.4/0.7/1.0,aswellaspulsemodulationfrequencyfrom40kHzto2.7MHzforpureC2H2dischargesatapressureof500mTorr.Wefindthatthepulseparameters,especiallythedutyratio,haveagreataffectonthedissociativeattachmentcoefficientandthenegativedensity.Moreimportantly,bydecreasingthedutyratio,nanoparticlesstarttodiffusetothewall.Undertheactionofgasflow,nanoparticledensitypeakiscreatedinfrontofthepulseelectrode,wherethegastemperatureissmaller.
简介：Ourobjectivesweretodevelopanewchemicalmethodforthepolymerizationofpyrrole.CuCl2dissolvedinC2H5OHsolventisprimarilyusedfortheinitiationpolymerizationofpyrrole.ThepolymerswithdifferentyieldandconductivitywereobtainedbyraringtheinitialconcentrationofCu2+.TheinitialconcentrationsofCu2+variedfrom1.2×10-4moleto6.48×10-3moleCu2+with2.16×10-2molepyrrole.Thepolypyrroleobtainedwascharacterizedwithelementalanalyzer,XPS,IRspectroscopy,Four-pointprobeandSEM.
简介：ThefirststarsintheearlyUniversewereformedabout400millionyearsafterthebigbang.VerificationoftheexistenceofthesestarsisimportantforourunderstandingoftheevolutionoftheUniverse[1].IthasbeenpredictedthatforPopulation-IIIstellarproductionyields,theabundancesofodd-Zelementsareremarkablydeficientcomparedtotheiradjacenteven-Zelements[2].Astronomersaresearchingforlong-lived,lowmassstarswiththeuniquenucleosyntheticpatternmatchingthepredictedyields[3].
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![Vanadium Haloperoxidases Model Compounds： Synthesis, Structural Characterization and Mimic Catalytic Bromination Activity of [VO（<b style='color:red'>C</b>_<b style='color:red'>2</b>O_4）（<b style='color:red'>2</b>,<b style='color:red'>2</b>′-bipy）（H_<b style='color:red'>2</b>O）]·<b style='color:red'>C</b>_<b style='color:red'>2</b>H_5OH and VO（<b style='color:red'>C</b>_<b style='color:red'>2</b>O_4）（phen）（H_<b style='color:red'>2</b>O）](/image/thesis2 "Vanadium Haloperoxidases Model Compounds： Synthesis, Structural Characterization and Mimic Catalytic Bromination Activity of [VO（<b style='color:red'>C</b>_<b style='color:red'>2</b>O_4）（<b style='color:red'>2</b>,<b style='color:red'>2</b>′-bipy）（H_<b style='color:red'>2</b>O）]·<b style='color:red'>C</b>_<b style='color:red'>2</b>H_5OH and VO（<b style='color:red'>C</b>_<b style='color:red'>2</b>O_4）（phen）（H_<b style='color:red'>2</b>O）")
![Crystal Structure and Bioactivity of Complex [Gd（<b style='color:red'>C</b>10H9N<b style='color:red'>2</b>O4）（<b style='color:red'>C</b>10H8N<b style='color:red'>2</b>O4）（H<b style='color:red'>2</b>O）3]<b style='color:red'>2</b>·phen·4H<b style='color:red'>2</b>O](/image/thesis10 "Crystal Structure and Bioactivity of Complex [Gd（<b style='color:red'>C</b>10H9N<b style='color:red'>2</b>O4）（<b style='color:red'>C</b>10H8N<b style='color:red'>2</b>O4）（H<b style='color:red'>2</b>O）3]<b style='color:red'>2</b>·phen·4H<b style='color:red'>2</b>O")
![Crystal Structure of Bis （0, O＇-diisopropyl dithiophosphate） ： [（<b style='color:red'>C</b>3H7O）<b style='color:red'>2</b>PS<b style='color:red'>2</b>]<b style='color:red'>2</b>](/image/thesis12 "Crystal Structure of Bis （0, O＇-diisopropyl dithiophosphate） ： [（<b style='color:red'>C</b>3H7O）<b style='color:red'>2</b>PS<b style='color:red'>2</b>]<b style='color:red'>2</b>")
![Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex [η5-<b style='color:red'>C</b>5H3(t-Bu)<b style='color:red'>2</b>]<b style='color:red'>2</b>Fe<b style='color:red'>2</b>(CO)3Se<b style='color:red'>2</b><b style='color:red'>C</b><b style='color:red'>2</b>B10H10](/image/thesis13 "Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex [η5-<b style='color:red'>C</b>5H3(t-Bu)<b style='color:red'>2</b>]<b style='color:red'>2</b>Fe<b style='color:red'>2</b>(CO)3Se<b style='color:red'>2</b><b style='color:red'>C</b><b style='color:red'>2</b>B10H10")
