简介:Anewμ3-Otriiron(Ⅲ)complex[Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2(HOBZ=benzoicacid)hasbeensynthesized,itsstructurehasbeendeterminedandvariabletemperaturemagneticsusceptilityhasalsobeenmeasured.Inthemolecule,threeironatomsformedanequilateraltrianglewithu3-Oincenter.ThefittingtothemagneticsusceptibilityshowedthatanintramolecularantiferromagneticexchangeinteractionoccurredbetweenironatomswithJ=-25.51cm-1,andaweakerintermolecularantiferromagneticexchangeinteractionoccurredwithzJ’=-2.30cm-1.
简介:目的:探究季铵型聚合物CO2解吸附过程温度和CO2浓度等变量对解吸附热力学和动力学的影响;研究空气CO2捕集供给植物增产的耦合方法,降低空气CO2捕集与利用的能耗与成本。创新点:1.基于变湿吸附技术,探究了季铵型聚合物CO2解吸附过程的热力学及动力学特性;2.获得了CO2作为气肥供给植物增产的关键影响参数;3.建立并优化了空气CO2捕集与植物利用的耦合模型。方法:1.通过CO2吸附平衡与动力学实验,获得季铵型聚合物CO2解吸附的平衡常数和动力学常数的影响参数;2.通过植物CO2吸收实验,获得CO2供给植物增产过程中CO2浓度和光照强度对吸收速率的影响;3.通过理论推导,构建解吸附CO2浓度与吸附剂质量、温度以及吹扫气流量等的关系,获得空气CO2捕集与植物增产的耦合模型并计算CO2捕集的能耗与成本。结论:1.季铵型聚合物材料吸附CO2的平衡常数随温度的升高而降低;吸附、解吸附动力学常数随温度的升高而升高。2.CO2供给植物增产的最佳浓度和光照强度为1000ppm和8000lux。3.基于优化的空气捕集与植物利用的耦合算法,CO2的捕集能耗与成本分别为35.67kJ/mol和34.68USD/t。
简介:Pureandneodymium-dopedgadoliniumcalciumoxoboratecrystalsofhighqualityweregrownbytheCzochralskimethod.Theorientationofcrystalwaspreciselydetermined,andthesamplesformeasurementswereprepared.Throughsynchrotronx-raytopographyandhigh-resolutionx-raydiffractometry,thetwinstructurewasdiscovered.Somepropertiessuchasthefigureofmeritvalue,anddielectric,piezoelectric,andelasticconstantsweremeausuredalongwithadiscussionoftheanisotropyofthelaserproperties.
简介:At-hyperwheel(t≥3)oflengthl(orW(t)lforbrevity)isat-uniformhypergraph(V,E),whereE={e1,e2,...,el}andv1,v2,...,vlaredistinctverticesofV=∪eii=1lsuchthatfori=1,...,l,vi,vi+1∈eiandei∩ej=P,j∈/{i1,i,i+1},wheretheoperationonthesubscriptsismodulolandPisavertexofVwhichisdifferentfromvi,1≤i≤l.Inthispaper,theminimumcoveringproblemofMCλ(3,W(3)4,v)isinvestigated.DirectandrecursiveconstructionsonMCλ(3,W(3)4,v)arepresented.Thecoveringnumbercλ(3,W(3)4,v)isfinallydeterminedforanypositiveintegersv≥5andλ.
简介:Europium(Ⅲ)-dopedYF3ispreparedbyahydrothermalprocessat200℃.X-raydiffraction(XRD)patternidentifiestheformationofYF3phasewithoutdetectableimpurity.Environmentscanningelectronmicroscopy(ESEM)imageshowstheevensizedistributionofthesampleswithcubicmorphology.TheexcitationandemissionspectraoftherareearthionsdopedYF3areinvestigatedbyfluorescencespectrophotometer.Theexcitationspectrumfor591nmemissionhasseveralexcitationbandsat320,365,386,397and467nm,andthemainpeakvaluewas397nm.TypicalEu3+emissionpeaksat591nm(5D0→7F1)and612nm(5D0→7F2)areobservedwhenexcitedby397nm,andthestrongestemissionis591nm,demonstratingthattherareearthionsoccupythecentrosymmetricalsitesinYF3.
简介:Ca3Y2(BO3)(4):Eu3+黄磷被高温度solid-statereaction方法综合,并且光特征被调查。排放光谱在相应于电的dipoleD-5(0)的613和621nm展出二强壮的红排出物在365nm刺激下面的Eu3+的-F-7(2)转变,原因是Eu3+代替forY3+在Ca3Y2(BO3)(4)的水晶结构占据非中心对称的位置。为613nm的Theexcitation光谱显示黄磷能是有效地激动的由紫外(紫外)(254nm,365nm和400nm)并且蓝色(470nm)光。Ca3Y2(BO3)(4)的排放紧张上的Eu3+集中的效果:Eu3+黄磷被测量,排放紧张与增加Eu3+集中增加的结果表演,然后减少。Ca3Y2(BO3)(4)的CIE颜色坐标:Eu3+黄磷是(0.639,0.357)在15mol%Eu3+。
简介:[Co3(1,2-S2C6H4)3(PPh3)3][CoBr3(DMF)].sol(1,sol=CHCl3,O(C2H5)2,H2O)wasobtainedfromthereactionofCoBr(PPh3)3withNa2(S2C6H4)inchloroform.TheCo3coreinthecationof1exhibitsametal-metalbondedisoscelestriangle,inwhichthetwolongerCo-CobondsarebothbridgedbyS2C6H4ligandsontwosidesofthetriangleplanerespectively,whilethebottomshortCo-CobondisbridgedbythethirdbidentateS2C6H4ligand.Aseriesofpolynu-clearcobaltclustercompoundswithphosphine,thiolateand/orsulphurligandswerepreparedbylowoxidationstateCo+withthiolatesinorganicsolvents.Thesetri-,tetra-,hexa-,heptanuclearclustercompounds1-8withvarioustypesofcrystalstructurescanbeviewedasthecondensedpolynuclearcobaltcomplexesthatthecobaltatomframeworkswithsulphurbridgedwerebuiltthroughthesmalltriangularunitsof[Co3S3nL3](n=1,2)withorwithout[CoL](L=PR3,Br,Cl,5-C5H5)fragments.
简介:Asanimportantmulti-functionalmaterialappliedinsurfaceacousticwavedevices,opticalcommunications,laserandoptoelectronicsduetoitsgoodphotoelectricandpiezoelectricproperties,lithiumtantalate(LiTaO3)hasdrawnextensiveinterests[1].NumerousphysicalpropertiesofLiTaO3,suchasacoustical,electronicstructures,opticalpropertiesandeffectivemass,thermodynamicproperties,havebeenreportedinseveralpapers.Pointdefectswillaffecttheelectronicstructurewhichshouldberesponsibleformanyphysicalproperties,especiallyopticalproperties.
简介:Reactionsofthe6-hydroxy-thiopyrano[3,4-c]pyridine-5-carbonitrilederivative1withα-halo-carbonylcompoundsgavetheortho-substitutedintermediates2a-cwhichwereconvertedintofuro[2,3-b]thiopyrano[4,3-d]pyridines3a-cbyfusionofafuranmoietyunderbasicconditions.Furthercyclizationof3a-cledtoafusionofapyrimidinering,yieldingthetetracyclicproducts6,7and8.Inaddition,condensationof6withvariousaromaticaldehydesaffordedthecorrespondingimines9a,b.Mannichreactionof7gaveproducts10a,b.