学科分类
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31 个结果
  • 简介:Thepotentialenergycurves(PECs)ofBOmolecule,includingΣ+andΠsymmetrieswithdoubletspinmultiplicities,areobtainedemployingmulti-referenceconfigurationinteraction(MRCI)methodandDunning'scorrelationconsistentbasissets.Theanalyticalpotentialenergyfunctions(APEFs)arefittedusingtheMurrell-Sorbie(MS)functionandtheleastsquaremethod.BasedonthePECs,thespectroscopicconstantsofthestateshavebeendeterminedandcomparedwiththetheoreticalandexperimentalresultsavailabletoaffirmtheaccuracyandliabilityofthecalculations.Theroot-mean-square(RMS)errorsbetweenthefittedresultsandtheabinitiovaluesaretoolittleincomparisonwiththechemicalaccuracy(349.755cm-1).ItisshownthatthepresentAPEFsareaccurateandcandisplaytheinteractionbetweentheatomswell.ThepresentAPEFscanbeusedtoconstructmorecomplicatedAPEFordosomedynamicinvestigations.

  • 标签: 组态相互作用 分子势能函数 势能曲线 分析势能函数 最小二乘法 光谱常数
  • 简介:Theeffectofλ/2SiO2overcoatonthelaserdamagecharacteristicsofHfO2/SiO2high-reflector(HR)coatingsisinvestigatedwith1-on-1andN-on-1laserdamagetestmethods.Thelaserdamagesurfaceof1-on-1isanalyzedbyastepanalyzer.ThesurfacemorphologiesshowthatlaserdamagemakesthecoatingdamagedareaprotrudentandroughforHRcoatingwithoutλ/2silicaovercoat,butconcaveandsmoothforHRcoatingwithλ/2silicaovercoat.Theresultof10-on-1multi-pulseirradiationonthesamepointofthecoatingshowsthatthereisanenergydensitystageonthedamagecurve.Ifthelaserenergydensityiswithintherangeofthestage,HfO2/SiO2HRcoatingswithλ/2silicaovercoatwillnotbedamagedmorethan2timesformulti-shots,andthesurfacedamagesareveryslightsothatthereisnoimpactonthecoatingperformance.Anotherinterestingresultisthattheenergydensitystageextendsfromthedamagethresholdtothepointofabout3timesofthreshold,whichissimilartotheeffectofthelaserconditiononcoating.

  • 标签: 激光损伤 高能激光装置 光学涂层 高反射涂层 二氧化硅 HFO2/SIO2
  • 简介:SiO_2thinfilmscontainingSi_(1-x)Ge_xquantumdots(QDs)arepreparedbyionimplantationandannealingtreatment.Thephotoluminescence(PL)andmicrostructuralpropertiesofthinfilmsareinvestigated.ThesamplesexhibitstrongPLinthewavelengthrangeof400—470nmandrelativelyweakPLpeaksat730and780nmatroomtemperature.Blueshiftisfoundforthe400-nmPLpeak,andtheintensityincreasesinitiallyandthendecreaseswiththeincreaseofGe-dopingdose.Weproposethatthe400—470nmPLbandoriginatesfrommultipleluminescencecenters,andthe730-and780-nmPLpeaksareascribedtotheSi=OandGeOluminescencecenters.

  • 标签: SIO2薄膜 光致发光 量子点 硅锗 掺杂比 底片
  • 简介:Thenonlinearswitchingcharacteristicsoffusedfiberdirectionalcouplerswerestudiedexperimentally.Byusingfemtosecondlaserpulseswithpulsewidthof100fsandwavelengthofabout1550nmfromasystemofTi:sapphirelaserandopticalparametricamplifier(OPA),thenonlinearswitchingpropertiesofanullcoupleranda100%couplerweremeasured.Theexperimentalresultswerecoincidentwiththesimulationsbasedonnonlinearpropagationequationsinfiberbyusingsuper-modetheory.Nonlinearlossinfiberwasalsomeasuredtogettheinjectedpoweratthecoupler.Afterdeductingthenonlinearlossandinputefficiency,thenonlinearswitchingcriticalpeakpowersfora100%andanullfusedcouplerswerecalculatedtobe9410and9440W,respectively.ThenonlinearlossparameterPNinanexpressionofαNL=αP/PNwasobtainedtobePN=0.23W.

  • 标签: 非线性开关 熔融光纤定向耦合器 费秒激光脉冲 光学参数放大器
  • 简介:Ablationdynamicsoftungstenirradiatedwitha70fslaserpulseisinvestigatedwithX-rayinterferometryandX-rayimagingusinga13.9nmsoftX-raylaserof7pspulseduration.Theevolutionofhigh-densityablationfrontoftungsten(i.e.,W)ispresented.Theablationfrontexpandsto~120nmabovetheoriginaltargetsurfaceat160psafterfemtosecond-laserirradiationwithanexpansionspeedofapproximately750m∕s.TheseresultswillprovideimportantdataforunderstandingablationpropertiesofW,whichisacandidatematerialofthefirstwallofmagneticconfinementfusionreactors.

  • 标签: 飞秒激光脉冲 烧蚀性能 激光观测 软X射线 激光驱动 X射线成像技术
  • 简介:Usingamicrowavegenerator,chlorinedilutedbyheliumwasdissociatedtochlorineatomsthatsubse-quentlyreactedwithhydrogenazidetoproducetheexcitedstatesofNCl(a1△).Meanwhile,moleculariodinewithcarriergasofheliumreactedwithatomicchlorinetoproduceatomiciodinewhichthenwaspumpedtoexcitedstateofI(2P1/2)byanenergytransferreactionfromNCl(a1△).Inthispaper,thechangesofNCl(a1△)andNCl(bi∑)emissionintensityispresentedwhenI2/HeisintroducedintothestreamofCl/Cl2/He/HN3/NCl(a1△)/NCl(b1∑).ThedependencesofatomiciodineI(2P1/2)onflowratesofgaseswerealsoinvestigated.TheoptimumparametersforI(2P1/2)productionaregiven.

  • 标签: 化学激光器 微波发生器 实验研究
  • 简介:FourkindsofY2O3stabilizedZrO2(YSZ)thinfilmswithdifferentY2O3contents(from0to12mol%)aredepositedonBK7glasssubstratesbyelectron-beamevaporationmethod.TheeffectsofdifferentY2O3dopantcontentsonresidualstress,structure,andopticalpropertiesofZrO2thinfilmsareinvestigated.TheresultsshowthatresidualstressinYSZthinfilmsvariesfromtensiletocompressivewiththeincreaseofY2O3molarcontent.TheadditionofY2O3isbeneficialtothecrystallizationofYSZthinfilmandtransformationfromamorphoustohightemperaturephase,andtherefractiveindexdecreaseswiththeincreaseofY2O3molarcontent.Moreover,thevariationsofresidualstressandtheshiftsofrefractiveindexcorrespondtotheevolutionofstructuresinducedbytheadditionofY2O3.

  • 标签: 光学 感光底层 氧化锌薄膜 研究
  • 简介:Ag-MgF2cermetfilmswithdifferentAgfractionswerepreparedbyvacuumevaporation.Themicrostruc-tureofthefilmswasexaminedbyRamanscatteringtechnique.Thesurface-enhancedRamanspectrumforMgF2moleculesinthecermetfilmstronglysuggeststheexistenceofAgnanoparticlesdispersedinMgF2matrix.TheintensitiesoftheRamanspectraofAg-MgF2cermetfilmsincreasewithAgfraction.TheenhancementofRamanscatteringdisappearswhenAgcontentreacheswt.20%.TheanalyseswiththetransmissionelectronmicroscopyshowedthatAg-MgF2cermetfilmsaremainlycomposedofamor-phousMgF2matrixwithembeddedfaced-center-cubicAgnanoparticles.Itsuggeststhatthepercolationthresholdshouldbearoundwt.20%ofAgcontent.

  • 标签: 微观结构 拉曼光谱 金属陶瓷薄膜 Ag-MgF2薄膜 二氟化镁
  • 简介:Nitridatedβ-Ga_2O_3(100)substratewasinvestigatedasthesubstrateforGaNepitaxialgrowth.Theeffectsofnitridationtemperatureandsurfaceroughnessofβ-Ga_2O_3wafersontheformationofGaNwerestudied.Itwasfoundthatthemostoptimizednitridationtemperaturewas900°C,andhexagonalGaNwithpreferredorientationwasproducedonthewell-polishedwafer.Thenitridationmechanismwasalsodiscussed.

  • 标签: 单晶体 β-Ga2O3 氮化镓 光学应用
  • 简介:AprototypeRamanlidarwasdesignedformonitoringtroposphericCO_2profileandotherscientificin-vestigations.ThethirdharmonicofNd:YAGlaser(354.7-nmwavelength)wasusedasstimulatedlightsourcetoprovidenighttimemeasurements.FilterwithhighrejectionratioperformancewasusedtoextractCO_2RamansignalsfromRayleigh-Miescatteringsignalseffectively.Toimprovetherealtimemonitoringfunction,atwo-channelsignalcollectionsystemwasdesignedtocollectCO_2andN_2Ramanscatteringsig-nalssimultaneously.TheN_2Ramanscatteringsignalswereusedtoretrieveaerosolextinctioncoefficient.TypicalfeaturesofCO_2concentrationprofileandaerosolextinctioncoefficientinHefeiwerepresented.ThemixingratioofatmosphericCO_2inHefeicanreachabout360-400ppmv.

  • 标签: 对流层 气溶胶 激光雷达 谐波
  • 简介:采用HCl与NH2·H2O分步催化制各了SiO2胶体,在同一终点pH值下可得到不同的粒度,用静电自组装法制各了PDDA/SiO2有机/无机多层复合光学增透薄膜。用TEM测试了薄膜的微观结构,用721分光光度计监测了薄膜的透射率,研究了薄膜的光学性能随薄膜层数及波长的变化。

  • 标签: SIO2 溶胶 静电自组装 增透膜
  • 简介:选用高功率脉冲TEACO2激光器,对不同颜色不同种类的油漆进行了清洗实验,运用数码照片分析程序计算出清洁率,找出了完全清洗阈值和损伤阈值.实验结果较为清晰地给出了激光输出能量和重复频率对清洗效果的影响.对红色醇酸漆来说,完全清洗阈值为10.37J/cm^2,而损伤阈值为11.43J/cm^2;红色金属喷漆的完全清洗阈值为9.66J/cm^2,其损伤阈值达10.37J/cm^2;黄色金属喷漆的完全清洗阈值为10.71J/cm^2,损伤阈值则为11.07J/cm^2.输出能量和重复频率未达指定参数时,激光清洗清洁率则低于100%.

  • 标签: TEA CO2激光器 激光除漆 清洁率 清洗阈值
  • 简介:以正硅酸乙酯为前驱体,乙醇为溶剂,盐酸为催化剂,采用溶胶-凝胶法制备了用于压敏漆基质薄膜材料的SiO2溶胶。不同的成膜助剂对SiO2溶胶的涂膜性能影响较大,其中以异丙醇作为添加剂的溶胶涂膜性能最好。吸收光谱测试结果表明SiO2溶胶不吸收激发光,同时发射光谱研究结果表明SiO2溶胶发光波长为415nm左右,不影响压敏漆探针分子的发光。

  • 标签: 压敏漆 溶胶-凝胶法 SIO2溶胶 吸收光谱 发射光谱
  • 简介:Becausepulserepetitionrateaffecteddirectlythemomentumcouplingcoefficientoftransverselyexcitedatmospheric(TEA)CO2laserpropulsion,adoublepulsetrigger,controllinghighvoltageswitchoflaserexcitationcircuit,wasdesigned.Thepulseintervalrangedbetween5and100ms.Themomentumcouplingcoefficientforair-breathingmodelaserpropulsionwasstudiedexperimentally.Itwasfoundthatthemomentumcouplingcoefficientdecreasedwiththepulserepetitionrateincreasing.

  • 标签: 偶合系数 二氧化碳激光器 变量脉冲重复比率 动量耦合
  • 简介:WhenfemtosecondlaserpulsesinterferewithchirpedfemtosecondlaserpulsesinAs2S3fiber,achirpedfibergratingisformed.Ananalyticalexpressionisgiventodescribethechirpedgrating,anditsBraggreflectivityiscalculated.BecauseofthehighphotosensitiveeffectofAs2S3material,thechirpedfibergratinghasawideBraggreflectivespectrumandhighreflectivitybychoosingproperparameters.Thisindicatesthatthechirpedfibergratingcanbeusedasastretcherinthefemtosecondchirpedpulseamplification(CPA)system.

  • 标签: As2S3 三硫化二砷 啁啾光纤光栅 双光子吸收效应 飞秒啁啾脉冲放大器 CPA
  • 简介:Athree-dimensionalmodelofGaAs/A1GaAsquantumdoubleringsinthelateralstaticelectricfieldisinvestigatedtheoretically.Theeigenvalueproblemwiththeeffective-massapproximationissolvedbymeansofthefinite-elementmethod.Theenergylevelsandwavefunctionsofquantum-confinedelectronsandheavyholesareobtainedandshowanagreementwithourprevioustheoreticalandexperimentalstudies.ItisshownintheapproximationofneglectingtheCoulombattractionbetweentheelectronandheavyholethatarelativelylargeStarkshiftofexcitonemissionof4meVisattainablewithanappliedelectricfieldof0.7kV/cm.

  • 标签: 横向电场 量子结构 电子 有限元方法 特征值问题 量子波函数
  • 简介:Thecombinationofdeepwetetchingandamagneto-rheologicalfinishing(MRF)processisinvestigatedtosimultaneouslyimprovelaserdamageresistanceofafused-silicasurfaceat355nm.ThesubsequentlydepositedSiO2coatingsareresearchedtoclarifytheimpactofsubstratefinishingtechnologyonthecoatings.Itisrevealedthatadeepremovalproceedingfromthesinglesideordoublesidehadasignificantimpactonthelaser-induceddamagethreshold(LIDT)ofthefusedsilica,especiallyfortherearsurface.Afterthedeepetching,theMRFprocessthatfolloweddoesnotactuallyincreasetheLIDT,butitdoesamelioratethesurfacequalitieswithoutadditionalLIDTdegradation.Thecombinationguaranteeboththeintegrityofthesurface’sfinishandthelaserdamageresistanceofthefusedsilicaandsubsequentSiO2coatings.

  • 标签: SiO2涂层 二氧化硅涂层 光学表面 熔融石英 激光损伤 后处理
  • 简介:TheCa_2SiO_4:Dy~(3+)phosphorwassynthesizedbythehightemperaturesolid-statereactionmethodinair.TheemissionspectrumofCa_2SiO_4:Dy~(3+)phosphorshowsseveralbandsat486,575,and665nmunderthe365-nmexcitation.TheeffectsofLi~+,Na~+,andK~+ontheemissionspectrumofCa_2SiO_4:Dy~(3+)phosphorwerestudied,TheresultsshowthattheemissionspectrumintensityisgreatlyinfluencedbyLi~+,Na~+,andK~+.Thechargecompensationconcentrationcorrespondingtothemaximumemissionintensityisdifferentwithdifferentchargecompensations.

  • 标签: 光谱 光反射 硫酸钙 无机发光材料
  • 简介:Higher-bandself-trappingandoscillation(rotation)ofnonlinearquadruplebeamsintwo-dimensional(2D)squarephotoniclatticesarenumericallydemonstrated.Underappropriateconditionsofnonlinearity,aquadruple-likebeamcanself-trapintolocalizedmodesthatresideinthesecondBraggreflectiongapthroughsingle-siteexcitation.Bychangingtheinitialorientationoftheincidentquadruplebeamrelatedtothelattices,periodicoscillationsofthelocalizedquadruplemodemaybeobtained.Thelocalizedquadruplestatebecomesarotatingdoublychargedopticalvortex(DCV)duringrotationandshouldundergocharge-flippingwhentherotatingdirectionisreversed.

  • 标签: 周期振荡 子晶格 自陷 二维 带隙 旋转方向