简介:ThreeseriesofCeO2/CuOsampleswerepreparedbyimpregnationmethodandcharacterizedbyXRD,N2adsorption-desorption,temperatureprogrammedreduction(TPR),XPSandTEMtechniques.IncomparisonwiththesamplespreparedwithCuOasinitialsupport,thesampleswithCu(OH)2asinitialsupporthavehigherreducibilitiesandsmallerrelativeTPRpeakareas,andalsolargerspecificsurfaceareasatcalcinationtemperaturesof400℃–600℃.Asaresult,Cu(OH)2isbetterthanCuOasinitialsupportforpreferentialoxidationofCOinexcessH2(CO-PROX).Thebestcatalyticperformancewasachievedonthesamplecalcinedat600℃andwithanatomicratioofCe/Cuat40%.XPSanalysesindicatethatmoreinterfacelinkagesCe-O-Cucouldbeformedwhenitwascalcinedat600℃.AndtheatomicratioofCe/Cuat40%ledtoaproperreducibilityforthesampleasillustratedbytheTPRmeasurements.
简介:ThemorphologyeffectofZr-dopedCeO2wasstudiedintermsoftheiractivitiesintheselectiveoxidationofstyrenetostyreneoxideusingtert-butylhydroperoxideastheoxidant.Inthepresentwork,ZrdopedCeO2nanorodsexhibitedthehighestcatalyticperformance(yieldofstyreneoxideandTOFvalue)followedbynanoparticlesandnanocubes.FortheZr-dopedCeO2nanorods,theapparentactivationenergyis56.3kJ/mol,whichismuchlowerthanthevaluesofcatalystssupportedonnanoparticlesandnanocubes(73.3and93.4kJ/mol).Thehighresolutiontransmissionelectronmicroscopyresultsindicatedthat(100)and(110)crystalplanesarepredominantlyexposedforZr-dopedCeO2nanorodswhile(100)and(111)fornanocubes,(111)fornanoparticles.TheremarkablyincreasedcatalyticactivityoftheZrdopedCeO2nanorodsismainlyattributedtothehigherpercentageofCe3+speciesandmoreoxygenvacancies,whichareassociatedwiththeirexposed(100)and(110)crystalplanes.Furthermore,recyclingstudiesprovedthattheheterogeneousZr-dopedCeO2nanorodsdidnotloseitsinitialhighcatalyticactivityafterfivesuccessiverecycles.
简介:以钛酸四丁酯为前驱体,采用溶胶一凝胶一超声波法制备得到了纳米TiO2溶胶,在单面抛光的硅片上采用旋转涂膜法涂上TiO2溶胶,快速烘干,再经烧结得到TiO2薄膜,并利用XRD,XPS与AFM对其结构性能进行表征,结果表明,膜厚度大约可控在3-5nm,膜表面颗粒大小约20nM,膜的组成主要为锐钛矿型TiO2和少量有机碳化物。在制备TiO2薄膜时,发现膜层随着镀膜次数变化显示不同的颜色差异,并有着良好的对应关系。以此现象入手研究不同颜色的TiO2薄膜在同一光催化条件下甲醛的降解分析,实验结果发现呈蓝色光的TiO2薄膜表现良好的光催化效果,其原因可能是蓝色光对光的吸收较好。
简介:以TiC14为源物质采用常压化学气相沉积法制备了TiO2薄膜。用紫外光谱测定了膜的透过率,进而计算出折光率、消光系数、光学带隙能等光学参数。结果发现,在不同气流量、沉积温度为100~250℃的条件下制备的TiO2膜,其折射率在2.16~2.82范围内,消光系数在0.04×10-3~6.70×10-3范围内,光学带隙能在2.8~3.08eV范围内。在光催化作用下,TiO2膜用于处理苯酚溶液,苯酚的转化率高达54.05%。关键词##4化学气相沉积(CVD);沉积率;折光率;消光系数;光催化更多还原
简介:薄膜物理与制备技术研究对于惯性约束聚变(ICF)实验具有重要意义,2003年开展的研究工作主要包括几个方面的内容:低压等离子体化学气相沉积(LPPCVD)法微球CH涂层及掺杂(溴等)技术研究;脉冲激光沉积(PLD)法Fe/Al合金薄膜研制;磁控溅射法Au/Gd,Ti/A1,Ti/Cr支撑薄膜研制;碳氢氮(CxNyH1-x-y)薄膜制备技术研究。相应主要结果如下:(1)利用低压等离子体化学气相沉积(LPPCVD)装置深入考察了以反式-2-丁烯如下:
简介:CuO-CeO2catalystswerepreparedbyaureaprecipitationmethodfortheoxidativesteamreformingofethanolatlow-temperature.Thecatalyticperformancewasevaluatedandthecatalystswerecharacterizedbyinductivelycoupledplasmaatomicemissionspectroscopy,X-raydiffraction,temperature-programmedreduction,fieldemissionscanningelectronmicroscopyandthermo-gravimetricanalysis.OverCuOCeO2catalysts,H2withlowCOcontentwasproducedinthewholetestedtemperaturerangeof250–450C.Thenon-noblemetalcatalyst20CuCeshowedhigherH2productionratethan1%Rh/CeO2catalystat300–400Candtheadvantagewasmoreobviousafter20htestingat400C.TheseresultsfurtherconfirmedthatCuO-CeO2catalystsmaybesuitablecandidatesforlowtemperaturehydrogenproductionfromethanol.
简介:O484.599042623用喇曼散射光谱估算纳米Ge晶粒平均尺寸=Estimationofcrystal—sizeofnano—GebyRamanscatteringspectra[刊,中]/王印月,郑树凯,杨映虎,郭永平(兰州大学物理系.甘肃,兰州(730000)),奇莉,甘润今(北京机械工业学院基础部.北京(100085))//光学学报.—1998,18(9).—1265—1268用射频共溅射技术和真空退火方法制备了埋入SiO2基底中的纳米Ge复合膜(nc—Ge/SiO2。测量了不同温度退火后该复合膜的喇曼散射光谱,其结果与晶体Ge的喇曼谱相比,纳米Ge的喇曼峰位红移峰形变宽;用喇曼谱的参数计算了纳米Ge晶粒的平均尺寸。所得
简介:O484.52003053772厚度具有线性变化的吸收平板或膜层的非相干透射率和反射率=Incoherenttransmissivityandreflectivityofanabsorbingplaneplateorlayerwithlinearvariationsinthickness[刊,中]/钟迪生(辽宁大学物理系.辽宁,沈阳(110036))//应用光学.-2002,23(1).-40-43计算了垂直入射下厚度具有线性变化的吸收平板样品的非相干透射率和反射率(正面和反面),给出了直接确定无基底样品以及透明基底上薄膜能量(强度)系数的精确表达式。图3参3(郑锦玉)