学科分类
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148 个结果
  • 简介:材质为2A14铝合金深孔杯形毛坯件,由于壁薄,材料热变形温度范围窄,合金流变困难,若采用常规锻造的反挤压成形方法,势必造成杯体内、外壁变形不均,温度下降过快,变形抗力大,成形难度较大。等温成形工艺是零件毛坯精化和优化的一个重要途径,但对设备和模具的要求较高,成本高。因此运用有限元数值模拟结合试验对铝合金杯形件挤压成形工艺进行可行性研究,以减少研究试验成本。

  • 标签: 成形工艺 等温挤压 铝合金 杯形件 有限元数值模拟 试验成本
  • 简介:用单辊甩带法制备了不含高生物毒性元素的Ti60Zr10Ta15Si15非晶薄带,并在高于其晶化开始温度的不同温度下对该非晶薄带进行了真空退火,研究了该非晶薄带在磷酸盐缓冲溶液(PBS)中的电化学腐蚀行为及热处理对其显微组织及其电化学行为的影响。结果表明,用单辊甩带法制备的Ti60Zr10Ta15Si15金属薄带为完全的非晶态结构,其玻璃转变温度和晶化开始温度分别为759K和833K,经过878K真空热处理后,薄带发生了部分晶化,在非晶的基底上析出了Ti相;经过938K热处理后,薄带发生了完全晶化,晶化相主要由Ti、Si3Ta5和SiZr以及TiSi组成。动电位极化测试表明,该非晶合金在PBS溶液中可表现出较为优异的耐蚀性能,部分晶化可进一步提高该合金的耐蚀性能,而完全晶化的合金抗腐蚀性能明显下降。

  • 标签: 钛基非晶合金 晶化 电化学腐蚀
  • 简介:研究了不同风速下激光辐照C/C复合材料的氧化速率,利用温度场计算结果,结合氧气在空气中的传质速率,计算了激光辐照下C/C复合材料氧化放热.结果表明,在亚音速的风速下,氧化对C/C复合材料烧蚀的贡献很小,因此,作为激光防护材料,可以忽略C/C复合材料在激光辐照期间的氧化烧蚀.

  • 标签: 氧化烧蚀 氧化放热 C/C复合材料 风速 激光辐照
  • 简介:Anenvironmentallyfriendlyprecursor,adenosine,hasbeenusedasadualsourceofCandNtosynthesizenitrogen-dopedcarboncatalystwith/withoutFe.Ahydrothermalcarbonizationmethodhasbeenusedandwateristhecarbonizationmedia.Themorphologyofsampleswith/withoutFecomponenthasbeencomparedbyHRTEM,andtheresultshowsthatFecanpromotethegraphitizationofcarbon.Furtherelectro-chemicaltestshowsthattheoxygenreductionreaction(ORR)catalyticactivityofFe-containingsample(C–FeN)ismuchhigherthanthatoftheFe-freesample(C–N).Additionally,theintermediatesofC–FeNformedduringeachsyntheticprocedurehavebeenthoroughlycharacterizedbymultiplemethods,andthefunctionofeachprocedurehasbeendiscussed.TheC–FeNsampleexhibitshighelectro-catalyticstabilityandsuperiorelectro-catalyticactivitytowardORRinalkalinemedia,withitshalf-wavepotential20mVlowerthanthatofcommercialPt/C(40wt%).Itisfurtherincorporatedintoalkalinepolymerelectrolytefuelcell(APEFC)asthecathodematerialandledtoapowerdensityof100mW/cm~2.

  • 标签:
  • 简介:Variousagriculturalcropresiduesincludingcornstover,corncob,andsorghumstalkwithamoisturecontentof75wt%weresubjectedtoalongpretreatment(12-60h)withsupercriticalCO2(scCO2),atlowtemperature(50-80℃)andapressureof17.5-25.0Mpa.Thesugaryieldsfromtheenzymatichydrolysis(EH)ofthepretreatedsampleswereasmuchasthree-tofourfoldgreaterthanthoseaffordedbytherawmaterials.However,whenpretreatmentwasconductedwithinashorttime(e.g.0.5h),aspreviouslyreportedintheliterature,onlyaslightincreaseintheEHsugaryieldswasobserved.TheproposedscCO2pretreatmentmechanismdemonstratedtheroleofmoistureinthesystem.Wetting,softening,andswellingwereobservedtomainlyaffectthelignocellulosewhenasuitableamountofwaterwasadded.Finally,thesampleswereanalysedbyX-raydiffractionandscanningelectronmicroscopy,beforeandafterpretreatment,toinvestigatethechangesinthemicroscopicstructureofthebiomass.

  • 标签: LIGNOCELLULOSE scCO2 PRETREATMENT ENZYMATIC HYDROLYSIS SUGAR
  • 简介:分子的动态模拟被执行在交流上调查事件精力的效果:从C和H的H电影生长原子流动。我们的模拟证明在低事件精力(1eV)的电影生长被H和C原子的吸附统治。在中等事件精力(10和20eV),有在表面吸附的H原子的事件H原子的抽象反应变得重要。在高事件精力(30和40eV),交流:H电影生长是一个二拍子的圆舞过程:一个人是吸附和C原子的浅培植,并且其它是H原子的深培植。[从作者抽象]

  • 标签: 分子动力学模拟 薄膜生长 入射能量 H原子 交流 流量
  • 简介:Anovelgas-phaseelectrocatalyticcellcontainingalow-temperatureprotonexchangemembrane(PEM)wasdevelopedtoelectrochemicallyconvertCO2intoorganiccompounds.TwodifferentCu-basedcathodecatalysts(CuandCu-C)werepreparedbyphysicalvapordepositionmethod(sputtering)andsubsequentlyemployedforthegas-phaseelectroreductionofCO2atdifferenttemperatures(70-90℃).ThepreparedelectrodesCuandCu-CwerecharacterizedbyX-raydiffraction(XRD),X-rayphotoemissionspectroscopy(XPS)andscanningelectronmicroscopy(SEM).Asrevealed,CuispartiallyoxidizedonthesurfaceofthesamplesandtheCuandCu-Ccathodiccatalystswerecomprisedofaporous,continuous,andhomogeneousfilmwithnanocrystallineCuwithagrainsizeof16and8nm,respectively.Theinfluenceoftheappliedcurrentandtemperatureontheelectro-catalyticactivityandselectivityofthesematerialswasinvestigated.Amongthetwoinvestigatedelectrodes,thepureCucatalystfilmshowedthehighestCO2specificelectrocatalyticreductionratesandhigherselectivitytomethanolformationcomparedtotheCu-Celectrode,whichwasattributedtothehigherparticlesizeoftheformerandlowerCuO/Curatio.Theobtainedresultsshowpotentialinterestforthepossibleuseofelectrical「enewableenergyforthetransformationofCO2intovaluableproductsusinglowmetalloadingCubasedelectrodes(0.5mgCucm2)preparedbysputtering.

  • 标签: C02 VALORIZATION ELECTRO-REDUCTION CU catalyst PEM
  • 简介:我们针对金属和合金纳米固体提出了简化的电阻模型,并据此得到了纳米固体总电阻与纳米粒子电阻的关系。依据这一模型,我们对纳米固体电阻特性的尺寸效应、温度效应和压力效应及其与常规多晶材料的差别等进行了有效的物理解释。

  • 标签: 纳米固体 电阻特性 简化模型 物理解释
  • 简介:在电阻点焊过程中喷溅的产生直接降低焊接接头的强度,是最不希望出现的焊接缺陷,而在镁合金的电阻点焊过程中,使用大电流短时间的强规范会使低熔、高导热、高线胀系数的镁合金极易产生喷溅。镁合金对于喷溅的敏感性远远大于钢和铝合金。对镁合金电阻过程中喷溅产生的原因进行分析,对控制和减少焊接过程中的喷溅现象,保证焊点质量具有重要的意义。

  • 标签: 电阻点焊 镁合金 喷溅 原因 焊接接头 焊接缺陷
  • 简介:Carbon-supportedPdnanoparticleswerepreparedbymicrowaveheating-glycolreductionmethod,andcharacterizedbyawidearrayofexperimentaltechniquesincludingX-raydiffractionspectroscopy(XRD)andtransmissionelectronmicroscopy(TEM).TheelectrooxidationbehaviorsofethanolonthePd/Celectrodeinalkalinemediawereinvestigatedusingcyclicvoltammetry(CV),chronoamperometry(CA),electrochemicalimpedancespectroscopy(EIS)andsinglecellperformancemethods.Pd/Celectrodeforethanoloxidationshowedhighelectro-catalyticactivityandlongtermstability.However,itisobservedthatthecurrentdensitydecreaseswiththeincreasingofthepotentialandnegativeimpedancepresentsinthepotentialfrom-0.1to0.1V.Thedecreasingcurrentdensityandthenegativeimpedancecouldbeduetotheadsorbedintermediatesspeciesthatinhibitedthefurtheroxidationofethanol.BasedonthechemicalreactionanalysisandEISspectra,equivalentcircuitsrelatingtovariouspotentialzoneshavebeenobtained.TheseresultsrevealthedynamicadsorptionofintermediatesspeciesonPdsurfaces.Significantly,itisclarifiedthattheadsorptionbehaviorbeginsfromthemaximumcatalysisofelectro-catalysisandendsintheformationofthepalladium(II)oxidelayerontheelectrodesurface.

  • 标签: 纳米颗粒 碱性介质 氧化钯 乙醇 X射线衍射谱 电化学阻抗谱
  • 简介:TheCprogramminglanguageisexpressiveandflexible,butnotsafe;asitsexpressivepowerandflexibilityareobtainedthroughunsafelanguagefeatures,andimproperuseofthesefeaturescanleadtoprogrambugswhosecausesarehardtoidentify.SinceCiswidelyused,anditisimpracticaltorewriteallexistingCprogramsinsafelanguages,sowaysmustbefoundtomakeCprogramssafe.ThispaperdealswiththeunsafefeaturesofCandpresentsasurveyonexistingsolutionstomakeCprogramssafe.Wehavestudiedbinary-levelinstrumentationtools,sourcecheckers,source-levelinstrumentationtoolsandsafedialectsofC,andpresentacomparisonofdifferentsolutions,summarizedthestrengthsandweaknessesofdifferentclassesofsolutions,andshowmeasuresthatcouldpossiblyimprovetheaccuracyoralleviatetheoverheadofexistingsolutions.

  • 标签: C语言 程序设计语言 信息安全 编译工具
  • 简介:ThefirststarsintheearlyUniversewereformedabout400millionyearsafterthebigbang.VerificationoftheexistenceofthesestarsisimportantforourunderstandingoftheevolutionoftheUniverse[1].IthasbeenpredictedthatforPopulation-IIIstellarproductionyields,theabundancesofodd-Zelementsareremarkablydeficientcomparedtotheiradjacenteven-Zelements[2].Astronomersaresearchingforlong-lived,lowmassstarswiththeuniquenucleosyntheticpatternmatchingthepredictedyields[3].

  • 标签: FIRST DIRECT MEASUREMENT
  • 简介:薄壁曲面铅合金铸件(简称铅铸件)采用砂模或金属模铸造,经机械加工成壁厚约3-4mm的变壁厚曲面回转体,要求精加工后内部不得有大于φ0.4mm以上的渣孔类缺陷。

  • 标签: 合金铸件 射线检测技术 曲面 薄壁 金属模铸造
  • 简介:金属V作为贮氢材料具有良好的增压性能因而在ICF靶丸制备工艺中备受关注,但是金属V难活化,严重影响了其在增压材料方面的应用。为了改善金属V的活化性能,向金属V中掺杂少量的金属Ni以期达到对其改性和改善其贮氢性能的目的。

  • 标签: 吸氘性能 NI合金 制备工艺 贮氢材料 活化性能 ICF靶丸
  • 简介:利用原子参数一模式识别方法研究了若干二元系合金化行为的规律,并在此基础上,提出了二元系合金相的判据。

  • 标签: 合金相 模式识别 原子参数
  • 简介:介绍一种新型智能材料———形状记忆合金,包括其主要性能及应用,着重阐述NiTi形状记忆合金在医学领域的应用状况。

  • 标签: 形状记忆合金 医学材料