学科分类
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19 个结果
  • 简介:研究了钙钛矿太阳能电池材料CH3NH3PbI3(CH3NH3=MA,MAPbI3)的输运特性,理论分析了有机分子MA对晶格结构的影响。发现:MA沿[110]方向排布且近邻MA分子相互垂直的构型最稳定,将此构型作为MAPbI3的标准结构,使用第一性原理方法,通过分析晶格的振动散射或声子散射,计算了MAPbI3材料中形变势散射主导的载流子迁移率,分析了材料的输运特性,讨论了载流子迁移率理论计算值和实验值之间的差异。

  • 标签: CH3NH3PbI3 几何结构 形变势散射 迁移率
  • 简介:Temperature-dependentphotoluminescencecharacteristicsoforganic-inorganichalideperovskiteCH3NH3PbI3-xClxfilmspreparedusingatwo-stepmethodonZnO/FTOsubstrateswereinvestigated.Surfacemorphologyandabsorptioncharacteristicsofthefilmswerealsostudied.Scanningelectronmicroscopyrevealedlargecrystalsandsubstratecoverage.Theorthorhombic-to-tetragonalphasetransitiontemperaturewas140K.Thefilms’excitonbindingenergywas77.6±10.9meVandtheenergyofopticalphononswas38.8±2.5meV.TheseresultssuggestthatperovskiteCH3NH3PbI3-xClxfilmshaveexcellentoptoelectroniccharacteristicswhichfurthersuggeststheirpotentialusageinperovskitebasedoptoelectronicdevices.

  • 标签: 金属卤化物 有机-无机 光致发光 钙钛矿 氧化锌 两步法
  • 简介:9to12,April,2018Suzhou,ChinaInternationalSymposiumseriesonHighPowerLaserScienceandEngineering,aimingatbringingtogetherworldwidescientistsandengineersworkingonhighpowerlaserandphysics,isheldeverytwoyearssince2014.Onbehalfofthe3rdInternationalSymposiumonHighPowerLaserScienceandEngineering(HPLSE2018),

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  • 简介:ZnOfilmscontainingErandGenanocrystals(nc-Ge)weresynthesizedandtheirphotoluminescence(PL)propertieswerestudied.Visibleandnear-infraredPLintensitiesarefoundtobegreatlyincreasedinnc-Ge-containingfilm.Er-related1.54μmemissionhasbeeninvestigatedunderseveralexcitationconditionsupondifferentkindsofGe,ErcodopedZnOthinfilms.1.54μmPLenhancementaccompaniedbytheappearanceofnc-Geimpliesasignificantcorrelationbetweennc-GeandPLemissionofEr3+.Theincreasedintensityof1.54μminGe:Er:ZnOfilmisconsideredtocomefromthejointeffectofthelocalpotentialdistortionaroundEr3+andthepossibleenergytransferfromnc-GetoEr3+.

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  • 简介:针对DC/DC的质子位移效应,选取具有抗TID能力的DC/DC器件作为试验样品,在3MeV质子辐照条件下获取了器件的失效位移损伤剂量.结果表明,DC/DC功能失效是PWM控制器输出异常导致的.通过等效^60Coγ辐照及退火试验,排除了TID效应的影响,确定器件功能失效是由位移损伤引起的.高温退火后器件功能恢复,并立即对该器件进行了测试.结果表明,输出电压、电压调整度、负载调整度、交叉调整度、纹波及负载跃变时的输出电压均大幅衰退.利用这些敏感参数,获取了位移损伤导致的电源性能衰退模式.根据位移损伤缺陷类型及退火温度,分析了DC/DC的退火规律,可为DC/DC质子辐射损伤模拟试验方法的建立及其空间应用提供依据.

  • 标签: DC/DC 位移损伤效应 电离损伤效应 位移缺陷 退火
  • 简介:Thisworkpresentsthesaturableabsorption(SA)propertiesofCsPbBr3perovskitequantumdots(QDs).TheperovskiteQDsshowexcellentSAperformancewithanonlinearabsorptioncoefficientof-35×10-2cm∕GWandafigureofmeritof3.7×10-14esucm.Further,theiruseassaturableabsorbersinapassivelyQ-switchedvisiblesolid-statelaserforthegenerationofsolitonpulsesisdemonstrated.TheseresultsdemonstratethepotentialfortheperovskiteQDstoactassaturableabsorbers.

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  • 简介:在这份报纸,我们在场一三维(3D)在为收音机频率的晶片水平的真空包装技术微机电的系统(RFMEMS)共鸣器,低损失的硅vias在被用来播送RF发信号。Au-Sn焊接结合被采用象电的导体一样提供真空封装。封装帽子的一个RF模型被建立评估包装的寄生效果,它提供3DRFMEMS封装的一个有效设计答案。与建议包装结构,24dB的signal-to-background比率(SBR)被完成,以及共鸣器的优秀因素(Q因素)在包装以后从8000~10400增加。包装共鸣器有线性频率温度(英尺)在在0楨?慰数?之间的一个温度范围特征?牵敶?牡?牰癯摩吗??

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  • 简介:Strongnonlinear,electro-optical,andthermo-opticalpropertiesoflithiumniobate(LN)havegainedmuchattention.However,theimplementationofLiNbO3inrealdevicesisnotatrivialtaskduetodifficultiesinmanufacturingandhandlingthin-filmLN.Inthisstudy,weinvestigateanopticaldevicewheretheBlochsurfacewave(BSW)propagatesonthethin-filmLNtounlockitsproperties.First,accesstotheLNfilmfromair(oropenspace)isimportanttoexploititsproperties.Second,forsustainingtheBSW,one-dimensionalphotoniccrystal(1DPhC)isnecessarytobefabricatedunderthethin-filmLN.Weconsidertwomaterialplatformstorealizesuchadevice:bulkLNandcommercialthin-filmLN.Clearreflectancedipsobservedinfar-fieldmeasurementsdemonstratethepropagationofBSWsontopoftheLNsurfaceofthedesigned1DPhCs.

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  • 简介:Two-dimensional(2D)graphitecarbonnitride(g-C3N4)nanosheetshavebeensuccessfullyusedasasaturableabsorber(SA)inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles(g-C3N4-NPs)andthree-dimensionalorderedmesoporousg-C3N4(mpg-C3N4)werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.

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  • 简介:Inthisstudy,weinvestigatetheinfluenceofdopingonthechargetransferanddevicecharacteristicsparametersinthebulkheterojunctionsolarcellsbasedonpoly(3-hexylthiophene)(P3HT)andamethanofuUerenederivative(PCBM).Organicsemiconductorsarealsoknowntobenotpureandtheyhavedefectsandimpurities,someofthemarebeingchargedandactasp-typeorn-typedopants.Calculationsofthesolarcellcharacteristicsparametersversusthep-dopinglevelhavebeendoneatthreedifferentn-dopings(N_d)thatconsistof5×10~(17)cm~(-3),10~(18)cm~(-3),and5×10~(18)cm~(-3).Weperformtheanalysisofthedopingconcentrationthroughthedrift-diffusionmodel,andcalculatethecurrentandvoltagedopingdependency.Wefindthatatthreedifferentn-dopantlevels,optimump-typedopingisaboutN_p=6×10~(18)cm~(-3).Simulationresultshaveshownthatbyincreasingdopinglevel,V_(oc)monotonicallyincreasesbydoping.CellefficiencyreachesitsmaximumatsomewhathigherdopingasFFhasitspeakatN_p=3×10~(18)cm~(-3).Moreover,thispaperdemonstratesthattheoptimumvalueforthep-dopingisaboutN_p=6×10~(18)cm~(-3)andoptimumvalueforn-dopantisN_d=10~(18)cm~(-3),respectively.Thesimulatedresultsconfirmthatdopingconsiderablyaffectstheperformanceoforganicsolarcells.

  • 标签: 有机太阳能电池 掺杂剂 异质结 聚合物 基质材料 模拟
  • 简介:One-potachievementofethyllevulinatefromcassavawasconductedinethanol-watersystemoverseveralsimplesulfatesaltcatalysts.Al2(SO4)3catalysthadthebestperformanceinsynthesizingethyllevulinatecomparingwiththoseofaseriesofsulfatesalts.Thehighestyieldsofethyllevulinatewasupto39.27%aswellas7.78%levulinateacidwhencassavawascatalyzedinethanolmediumbyadding10wt%water.13Cand1HNMRspectroscopicinvestigationsconfirmedthatisomerizationofglucosetofructoseoverAl2(SO4)3catalystisanimportantstepinproducingethyllevulinateandlevulinateacid.DuetoaggregationsofAl3+underhydrothermalconditions,tinyamountofAl3+weredetectedinfiltrateatthepercentageof0.32%evenifinabsolutewater.BronstedandLewisacidscouldimprovetheyieldofethyllevulinateandlevulinateacidbysynergisticeffect.AllresultssuggestedthatA12(SO4)3wasasimpleandefficientcatalystforethyllevulinateandlevulinateacidproduction.

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  • 简介:TheEarth’ssustainabledevelopmentisthreatenedbytheincreasingatmosphericCO2levelwhichcanbeattributedtotheimbalanceofCO2duetotherapidconsumptionoffossilfuelscausedbyhumanactivitiesandtheslowabsorptionandconversionofCO2bynature.OneoftheefficientmethodsforreconstructingthebalanceofCO2shouldinvolvetherapidconversionofCO2intofuelsandchemicals.ThehydrogenationofCO2withgaseoushydrogeniscurrentlyconsideredtobethemostcommerciallyfeasiblesyntheticroute,however,thesupplyofsafeandeconomicalhydrogensourcesposesasignificantchallengetoup-scalingapplication.Directutilizationofhydrogenfromdissociationofwater,themostabundant,cheapandcleanhydrogenresource,forthereductionofCO2wouldbeoneofthemostpromisingapproachesforCO2utilization.ThispaperprovidesanoverviewofthecurrentadvancesinresearchonhighlyefficientreductionofCO2orNaHCO3,arepresentativecompoundofCO2,intoformicacid/formatebyinsituhydrogenfromwaterdissociationwithametal/metaloxideredoxcycleundermildhydrothermalconditions.

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  • 简介:Theeffectofbismuth(Bi)forbothVO2+/VO2+andV3+/V2+redoxcouplesinvanadiumflowbatteries(VFBs)hasbeeninvestigatedbydirectlyintroducingBionthesurfaceofcarbonfelt(CF).TheresultsshowthatBihasnocatalyticeffectforVO2+/VO2+redoxcouple.Duringthefirstchargeprocess,BiisoxidizedtoBi3+(neverreturnbacktoBimetalinthesubsequentcycles)duetothelowstandardredoxpotentialof0.308V(vs.SHE)forBi3+/BiredoxcouplecomparedwithVO2+/VO2+redoxcoupleandBi3+exhibitno(orneglectable)electro-catalyticactivity.Additionally,therelationshipbetweenBiloadingandelectrochemicalactivityforV3+/V2+redoxcouplewasstudiedindetail.2wt%Bi-modifiedcarbonfelt(2%-BiCF)exhibitsthehighestelectrochemicalactivity.Usingitasnegativeelectrode,ahighenergyefficiency(EE)of79.0%canbeachievedatahighcurrentdensityof160mA/cm2,whichis5.5%higherthanthepristineone.Moreover,theelectrolyteutilizationratioisalsoincreasedbymorethan30%.Eventhecelloperatedat140mA/cm2forover300cycles,theEEcanreach80.9%withoutobviousfluctuationandattenuation,suggestingexcellentcatalyticactivityandelectrochemicalstabilityinVFBs.

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  • 简介:通过溶胶-凝胶法、离子束磁控溅射法和化学腐蚀法分别制备了PZT薄膜、PbZr_(0.52)Ti_(0.48)O_3/Ni(PZT/Ni)复合薄膜材料的鼓包样品。采用X射线衍射仪(X-raydiffraction,XRD)表征了PZT/Ni复合薄膜材料的物相结构;利用自主研制的多功能新型鼓包测试平台,在力场、电场、磁场作用下分别测试分析了PZT/Ni复合薄膜材料体系的力电磁耦合性能。结果表明:随着电场强度的增加,PZT薄膜的弹性模量E先增大后减小;PZT/Ni复合薄膜在电场作用下实现了电磁调控,矫顽磁场强度Hc提高了33.4%;随着测试平台油压的增大,PZT薄膜的剩余极化强度和矫顽场分别增加了17.1%和32.1%,PZT/Ni复合薄膜的矫顽磁场强度提高了46.1%。

  • 标签: PZT/Ni 鼓包法 多场耦合 弹性模量 矫顽场
  • 简介:结合脉冲中子管的结构特征,建立了一套基于Al_2O_3单晶闪烁屏和CCD相机的中子管氘离子束束流截面测量系统。闪烁屏直径为15mm,厚度为0.5mm。为了降低测量本底,CCD相机工作在触发模式。利用有限元分析软件,模拟计算了典型中子管束流参数下的闪烁屏温度,并利用该测量系统获得了中子管氘离子束在靶面处的典型强度分布。结果表明,该测量系统可以准确地反映脉冲离子束束流的横向强度分布特征。

  • 标签: 脉冲离子束 闪烁屏 束流截面
  • 简介:Byusingtheultrasound-assistedliquidphaseexfoliationmethod,Bi2Te3nanosheetsaresynthesizedanddepositedontoaquartzplatetoformakindofsaturableabsorber(SA),inwhichnonlinearabsorptionpropertiesaround2μmareanalyzedwithahome-mademode-lockedlaser.Withtheas-preparedBi2Te3SAemployed,astablepassivelyQ-switchedall-solid-state2μmlaserissuccessfullyrealized.Q-switchedpulseswithamaximumaverageoutputpowerof2.03Waregeneratedunderanoutputcouplingof5%,correspondingtothemaximumsingle-pulseenergyof18.4μJandpeakpowerof23W.Thedeliveredshortestpulsedurationandmaximumrepetitionrateare620nsand118kHzunderanoutputcouplingof2%,respectively.ItisthefirstpresentationofsuchBi2Te3SAemployedinasolid-stateQ-switchedcrystallinelaserat2μm,tothebestofourknowledge.Incomparisonwithother2Dmaterialssuitableforpulsed2μmlasers,thesaturableabsorptionperformanceofBi2Te3SAisprovedtobepromisingingeneratinghighpowerandhigh-repetition-rate2μmlaserpulses.

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  • 简介:我们在Mn50Ni40SnSbx(x=1,2,3,和4)合金。所有准备样品在房间温度与空间组一起展出B2类型结构。Sb的替换增加原子价电子集中并且减少联合起来的房间体积。作为结果,当x增加,magnetostructural转变向更高的温度很快变。在在不同磁场变化下面的磁性的熵的变化在这转变附近被探索。等温的磁化曲线展出典型metamagnetic行为,显示magnetostructural转变能被一个磁场导致。悦耳的martensitic转变和磁性的熵变化建议那Mn50Ni40SnSbx合金是应用在的吸引人的候选人固态制冷。

  • 标签: 马氏体相变 Sb掺杂 磁热效应 Mn 合金 磁熵变化