学科分类
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58 个结果
  • 简介:ThecharacteristicsofsuspendedsedimentimagecanbereflectedbythecoefficientsofbiorthogonalwavelettransformofCDF(2,2).Basedonthepowerdistributionindifferentscales,anadaptivealgorithmisproposedinthispaper,wherebythecoefficientsareadjustednon-linearly.Theparticleinformationcanbewellretainedwhiletheuselessbackgroundisremoved.Inthisway,satisfactorybinaryimagecanbeobtainedforfurtheranalysisofthesedimentparticle.

  • 标签: 沉积物 悬浮图像 颗粒物 双正交微波 能量分布
  • 简介:TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM),传播电子显微镜学(TEM),X光检查光电子光谱学(XPS),X光检查衍射(XRD),和荧光spectrophotometry。结果证明合成粒子有coremultishell结构,球形的形态学,和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应;为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高

  • 标签: 光致发光特性 二氧化钛 氧化锆 铕核 Y2O3 纳米TiO2
  • 简介:TheinfluenceofNa2SO4ontheformationofZnOwhiskerswasinvestigatedinthispaper.ZnOwhiskerswithaspectratiosofupto50weresynthesizedbydissolvingε-Zn(OH)2precursorinNaOH/Na2SO4solutionatroomtemperature,followedbyagingoftheresultingsolutionat140℃for6h.Fouriertransforminfraredspectroscopy,Ramanspectroscopy,andX-rayphotoelectronspectroscopyanalysesrevealedthatSO42-ionswereprimarilyadsorbedonthe(100)planeoftheZnOwhiskersviaanouter-spherecomplexconfiguration(O-H…O),therebypromotingtheone-dimensionalgrowthofZnOwhiskersalongthec-axis.

  • 标签: 氧化锌晶须 硫酸钠溶液 水热合成 X射线光电子能谱分析 傅立叶变换红外光谱 ZnO晶须
  • 简介:TiO2nanoparticlesweresynthesizedbyahomogeneouscontrolledprecipitationmethodusingindustrialtitaniumsulfate(Ti(SO4)2).TheobtainedpowderswerecharacterizedbyX-raydiffraction(XRD),transmissionelectronmicroscope(TEM),Fouriertransforminfraredspectroscopy(FTIR)andICPplasmaspectrometer.EDTAwasusedascomplexingagenttoimprovethepurityandtheformationofTiO2nanoparticles.Experimentalresultsindicatedthatthehigh-purityTiO2nanoparticleswere20nminmeansizeandnearlymonodispersed.

  • 标签: 二氧化钛 纳米粒子 乙二胺四乙酸 配位
  • 简介:PureAl2O3-2SiO2powderswerepreparedbysol-gelandcoprecipitationmethods,andtheiralkaliactivationreactivitieswerecompared.Thealkali-activationreactivityofthepowderpreparedbythesol-gelmethodwashigherthanthatofthepowderpreparedbythecoprecipitationmethod.Thepowderswereinvestigatedby27AIand29Simagic-anglespinningnuclearmagneticresonancespectroscopy(MASNMR)tounderstandtherelationshipbetweentheirstructureandalkali-activationreactivity.The27AlMASNMRdatashowedthatthefive-coordinateAIcontentofthepowderpreparedbythesol-gelmethodwashigherthanthatofthepowderpreparedbycoprecipitation.Thehighercontentoffive-coordinateAlcorrespondedtohigheralkali-activationreactivity.The29SiMASNMRdatashowedthatforthepowderpreparedbythesol-gelmethod,siliconwasreplacedbyaluminumatsecondarycoordinationsitesofthecentralSiatomsduringcalcination.However,forthepowderpreparedbysingle-batchcoprecipitation,themainchangewasfromalowdegreeofpolycondensationtoahighdegreeofpolycondensation.

  • 标签: 魔角旋转核磁共振 活化反应 固体碱 核磁共振光谱 粉末 化学合成
  • 简介:HomogeneousNi2+-dopedtitaniagelwassynthesizedbyasol-gelprocess,andthexerogelwasthenobtainedthroughaginganddrying,leadingtotheformationofNi/TiO2nanocompositeafterheattreatmentunderasuitablereducingatmosphere.TheresultingnanocompositewascharacterizedbyTGA-DSC,TEM,XRDandBETmethods.Theresultsshowthatthestructureandgrainsizeofthenanocompositescouldbemanipulatedbyalteringtheheat-treatmentconditions,andthatthenanocompositepossessesamesoporousstructurewithaporeradiusofca.28nmandaspecifictheanatase-rutilephasetransformation.

  • 标签: 纳米混合物 二氧化钛 二氧化镍 热处理 微观结构
  • 简介:DrivenbycuriosityaboutpossibleflightoptionsfortheChang’e-2spacecraftafteritremainsattheSun-EarthL2point,effectiveapproachesweredevelopedfordesigningpreliminaryfuel-optimalnear-Earthasteroidflybytrajectories.Theapproachesincludetheuseofmodifiedunstablemanifolds,gridsearchofthemanifolds’parameters,andatwo-impulsemaneuverfororbitalphasematchingandz-axisbiaschange,andaredemonstratedtobeeffectiveinasteroidtargetscreeningandtrajectoryoptimization.Asteroidflybysareexpectedtobewithinadistanceof2×107kmfromtheEarthowingtotheconstrainedEarth-spacecraftcommunicationrange.Inthiscase,thespacecraft’sorbitalmotionissignificantlyaffectedbythegravitiesofboththeSunandtheEarth,andtherefore,theconceptofthe"heliocentricoscillating-Keplerorbit"isproposed,becausetheclassicalorbitalelementsoftheflybytrajectoriesreferencedintheheliocentricinertialframeoscillatesignificantlywithrespecttotime.Theanalysisandresultspresentedinthisstudyshowthat,amongtheasteroidswhoseorbitsarethemostaccuratelypredicted,"Toutatis","2005NZ6",or"2010CL19"mightbeencounteredbyChang’e-2inlate2012or2013withtotalimpulseslessthan100m/s.

  • 标签: 近地小行星 飞行轨迹 地球 太阳 轨道运动 不稳定流形
  • 简介:Lithium-aluminum-cobalt-nickeloxideLiAlxCoyNi1xyO2particles,generallyusedascathodeoflithiumbattery,werepreparedbychemicalcoprecipitationfromanaqueoussolutionofLiOH,Al(NO3)3,Co(NO3)2andNi(NO3)2withNH4OH.XRD,SEMandFTIRwereusedtoexaminetheeffectofnickelcontentontheproduct.FTIRpatternsshowedthatincreaseinnickelcontentdecreasedtheabsorptionstrengthofthepeakofspinelstructureoftheproduct,attributedtotheoccupationbynickelinthealuminumsites.Particlesizeandelectricalpropertiesofthelithium-aluminum-cobalt-nickeloxide(abbreviatedasLACNO)particleswerealsodetermined.

  • 标签: LiAlxCoyNi1-x-yO2 Chemical coprecipitation Particle size Electrical
  • 简介:The(2+1)-dimensionalBKPequationintheHirotabilinearformisstudiedduringthiswork.WronskianandGrammiantechniquesareappliedtotheconstructionofWronskianandGrammiansolutionsofthisequation,respectively.ItisshownthatthesesolutionscanbeexpressedasnotonlyPfaffiansbutalsoWronskiansandGrammians.

  • 标签: Wronski行列式 KP方程 双线性形式 可表
  • 简介:Thecoordinationpolymer,(Nd(H2O)5)2(2,6-AQDS)3·2H2Owhere2,6-AQDS=2,6-anthraquinonedisulfonate,hasbeensynthesisedviaahydrothermalroute.Structurally,itconsistsoflayersofmonomericNdpolyhedrawhicharelinkedby2,6-AQDSanionsformingapolymeric,three-dimensionalnetwork.EachNdatomisninecoordinate,bondingtofivewatermoleculesandtofouroxygenatomsfromfour2,6-AQDSanionswhichinturnpillarthelayersbybridgingtwoNdatomsinonelayer,andcoordinatingtoasingleNdintheother.

  • 标签: 配位聚合物 水热法合成 晶体结构 络阴离子 氧原子
  • 简介:NanocrystallineSnO2wassynthesizedbydirectmixingandgrindingofSnCI4-5H2OandNaOHatroomtemperature,followedbycalcinationatdifferenttemperaturesfordifferenttimesinair.ProductsampleswerecharacterizedbyX-raydiffractionandtransmissionelectronmicroscope,revealingthattheamorphousprecursorSnO2wastransformedtocrystalsat200℃for3h,andthattheaverageparticlesizeincreaseduponraisingthecalciningtemperatureorprolongingthecalciningtime.Themechanismofthephasetransformationoftheproductsisdiscussed.

  • 标签: 二氧化锡纳米晶体 纳米材料 固态反应 焙烧 X射线衍射分析 透射电子显微镜分析
  • 简介:连贯的多角形的粒子的二维的分离元素模型(DEM)模拟被开发了估计点来源颤动的利益在楔形的hoppers导致流动。使用的particleparticle相互作用模型基于一个多接触原则。没有颤动,学习的第一部分在严肃下面调查了粒子分泌物决定批评的孔尺寸(Bc)就作为粒子形状的功能支撑流动。多角形形状的粒子比圆形的粒子需要一个更大的孔,这被显示出。当粒子顶点的数字增加,Bc减少,这也被显示出当粒子顶点的数字增加。圆形的粒子的增加以一种线性方式支持多角形的流动。学习的第二部分证明那颤动能提高流动,有效地减少Bc。模型表明了震荡器地点(高度)的重要性,与在提高的以前的连续统模型结果,和颤动振幅一致流动。

  • 标签: 动力效应模型 固体 振动 仿真
  • 简介:Uniformlysizedα-Fe2O3hexagonalplateletsweresynthesizedbyahydrothermalprocessusingFe(OH)3suspensionandlargeamountofNaOH.ThereactionproductswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),selectedareaelectrondiffraction(SAED),andavibratingsamplemagnetometer(VSM).Theresultsshowthatthehexagonalplateletsarefine,monodisperseandconsistingofsingle-crystals.Themagnetichysteresis(M-H)curveofthesamplesmeasuredatroomtemperatureindicatesthattheα-Fe2O3micro-plateletsexhibitferromagneticbehaviorswithrelativelylowcoercivity.

  • 标签: Fe2O3 六角片状 单分散 水热法合成 振动样品磁强计 扫描电子显微镜
  • 简介:Commerciallyavailablelatticescontainvariouskindsofmorphologicalimperfectionswhichresultingreatdegradationinlattices’mechanicalproperties,therefore,toobtainimperfectioninsensitivelatticestructureisobviouslyapracticalresearchsubject.Hierarchicalstructurematerialswerefoundtobeaclassofpromisinganti-defectmaterials.Thispaperbuildshierarchicallatticebyaddingsoftadhesiontolattice’scelledgesandnumericalresultsshowthatitsimperfectionsensitivitytomissingbarsisminorcomparedwiththeclassiclattice.Softadhesionwithappropriatepropertiesreinforcecelledge’sbendingstiffnessandthusreducethebendingdeformationinlatticecausedbymissingbarsdefect,whichisconfirmedbystatisticalanalysisofnormalizednodedisplacementsofimperfectlatticesunderhydrostaticcompressionandshearloads.

  • 标签: 敏感性 缺陷 晶格结构 二维 结构材料 力学性质
  • 简介:Inthisarticle,low-pressurecontrolmethodsforacombinedarcsubmergednanoparticlesynthesissystem(ASNSS)wasproposedanddevelopedforTiO2nanoparticlefabrication.Thephotocatalyticreactioniscarriedoutinaphotochemicalreactor.TheUVlightisobtainedfromUV-lampswithwavelengthof(253.7±0.8)nm.TheUV-Visspectrometryisusedtomonitortheabsorbancespectraofmethyleneblueasafunctionofilluminationtime.ExperimentalresultsshowthattherateconstantofphotocatalyticreactionofTiO2nanoparticlesformethyleneblueis0.0365min^-1.Thesurfaceadsorptionplaysanimportantroleinthedecompositionofmethyleneblue.ExperimentalresultsindicatethattheTiO2nanoparticlefluidpossessesexcellentphotocatalyticactivityinphotodegradationofmethyleneblue.

  • 标签: 二氧化钛 纳米颗粒流 光催化性质 ASNSS
  • 简介:Thereisaneedtostandardizemethodsassociatedwiththedispersionofnanomaterialsinnano(eco)toxicologicalinvestigations.Thefirststeptowardthisgoalistounderstandthedegreeofvariabilitythatexistsinnanomaterialdispersionspreparedbyusingdifferentprotocols.Usingtwocasestudies,thedegreeofvariabilityinTiO2nanomaterialdispersionswasassessedbydifferentialcentrifugalsedimentation(DCS)methods.Casestudy1addressesthevariabilitythatarisesfromvariationswithinoneprotocol,investigatingtheeffectsofdispersionaging,sonicationexposuretime,sonicationinthepresence/absenceofanicebath,materialsubsampling,particleconcentrationandhavingapre-wettingstep.Casestudy2addressesthevariabilitybetweenfourdifferentprotocolsdevelopedthroughpastresearchactivitiesandprojects.Theresultsindicatethatthereisalargedegreeofvariability(relativestandarddeviation(RSD)ofmeanparticlediameter=26%)inthedispersionofTiO2nanomaterialsbetweenthefourdifferentprotocolsstudiedandthatseveralstepsinadispersionprotocolarepotentialsourcesofvariation,withfinalparticleconcentrationbeingthemostsignificant.Theimplicationofthisstudyisclear:forthepurposeofdatacomparability,thereisaneedtoprovidetheexactdetailsofallstepsinvolvedinadispersionprotocol.

  • 标签: 分散体 协议 粒度分布 TIO2 纳米材料 相对标准偏差
  • 简介:Laminatedcompositematerialsarewidelyimplementedinseveralengineeringconstructions.Foritsrelativelightweight,thesematerialsaresuitableforaerospace,military,marine,andautomotivestructuralapplications.Toobtainsafeandeconomicalstructures,themodellinganalysisaccuracyishighlyrelevant.Sincemeshlessmethodsintherecentyearsachievedaremarkableprogressincomputationalmechanics,thepresentworkusesoneofthemostflexibleandstableinterpolationmeshlesstechniqueavailableintheliterature—theRadialPointInterpolationMethod(RPIM).Here,a2Dapproachisconsideredtonumericallyanalysecompositelaminatedbeams.Boththemeshlessformulationandtheequilibriumequationsrulingthestudiedphysicalphenomenonarepresentedwithdetail.Severalbenchmarkbeamexamplesarestudiedandtheresultsarecomparedwithexactsolutionsavailableintheliteratureandtheresultsobtainedfromacommercialfiniteelementsoftware.Theresultsshowtheefficiencyandaccuracyoftheproposednumerictechnique.

  • 标签: RADIAL POINT interpolators RPIM LAMINATED BEAM