学科分类
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3 个结果
  • 简介:Therestrictiononsulfurlevelingasolinehasbeenincreasinglytightened.TheU.S.TierⅡregulationrequiresareductionfromaverage340ppmto30ppmfrom2004to2008.Recentlysignificantprogresshasbeenmadeineffectivehighsulfurremoval,suchasposttreatmentofFCCgasolinebyselectivehydrotreating,SZorbsulfurremovaltechnology,OATSprocessetc.ThesulfurcontentofFCCgasolinecanbedeceasedtolessthan10ppm.WithregardtogasolinepoolcompositioninChina,itisveryimportanttolookforeffectivedesulfurizationprocessesthataresimple,straightforward,withlesshydrogenconsumption.Post-treatmentofFCCgasolineisapreferredoption.Fromthepointofviewofcomprehensiveutilization,alkylation,polymerization,isomerisationetc.canbeaddedtodesulfurizationprocesstomeettherequirementofultralowsulfur,premium.

  • 标签: 汽油 硫含量 加氢脱硫 催化裂化 吸附
  • 简介:Thebasic-nitrogenaromaticcompoundsinfeedstocksandliquidproductsfromthemicro-reactorandsolublecomponentsofcokeobtainedduringfluidcatalyticcracking(FCC)processwereanalyzedbythemicro-electrosprayionization(ESI)9.4TFouriertransformioncyclotronresonancemassspectrometry(FT-ICRMS)withanaveragemassresolvingpowerof300000atamassrangeof100-1200.Theanalyticalresultsrevealedthatthecokergasoil(CGO)containedahigherabundanceofbasic-nitrogenaromaticcompoundswiththetypeof-5Nto-9Ncomparedwiththoseindeasphaltedoil(DAO)andmixedFCCfeedstock.Aftercatalyticcracking,theabundanceoflowlycondensedbasic-nitrogenaromaticcompoundswasmuchlessthanthoseofhighlycondensedaromaticsintheliquidproducts,withthecarbonnumbermainlyrangingfrom6to25andtheaveragecarbonnumberoftheside-chainsequatingto1-5.Onthecontrary,withrespecttothesolublecomponentsofcoke,theabundanceoflowlycondensedbasic-nitrogenaromaticcompoundswasmorethanthoseofhighlycondensedaromatics,andthecarbonnumberrangedfrom12to30,whichwasmuchsmallerthanthatofthemixedFCCfeedstockbutslightlylargerthanthatofthecrackedliquidproducts.TheseresultshaveprovidedsomefundamentalinformationonFCCprocess.

  • 标签: 离子回旋共振 催化裂化过程 傅立叶变换 碱性氮 质谱 FCC原料