简介：MgO-Al2O3-Cr2O3rammingmixesmadeofdifferentrawmaterialshavedifferentmineralstructureanddifferentphysicalpropertiesthoughwiththeidenticalparticlesizedistribution,thesameamountofbinderandchemicalcomposition.Theresidualcarboncontentofthefusedmagnesia-chromematerialmadeinreducingatmosphereisveryhigh,ifthismaterialsisusedintheMgO-Al2O3-Cr2O3rammingmix,itwouldcausespallingofthefurnaceliningduringdrying-out.

简介：AnO'-Sialon-Al2O3compositerefractorywaspreparedbyinsitureactionofSi3N4-ZrSiO4-Al2O3mixturewithfusedaluminaaggregates.Densification,insitureactionprocedureandmicrostructureofthematerialwereinvestigatedbymeansofX-raydiffraction,opticalandscanningelectronicmicroscopesandEDAX.

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简介：TherearemanyprocessestoproduceCr2O3fromchrome-ores,DifferentparticlesizerangesofCr2O3powder,finepinmentgradegreenCr2O3andcoarsemetallurgygradeblackCr2O3,aremadebydifferentprocessesinChina,GreenCr2O3assuperfineandadditionandmetallurgygradeblackCr2O3usedtosynthesizeCr2O3graincanbeappliedtorefractories.ItisverydifficultforhighpurityCr2O3tosintertodensificationandTiO2additioniscontributedtodensificationofCr2O3sinteredathightemperature,Cr2O3grainswithrelativedensityof91%-95%aregainedbysinteringCr2O3withTiO2additionandelectrofusingCr2O3rawmaterials.

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简介：β-sialon/alumina/silicamixturesweresinteredinflowingnitrogenat1500℃and1600℃respectively.ThesinteringpropertiesandmorphologyofsampleswereinvestigatedbySEM,EDSandXRD.Resultsshowthatsinteredpropertiesofthesamplesareinfluencedbysoakingtemperaturesandcompositions.Bulkdensitiesofsamplesareincreasedwiththeincreaseofthesoakingtemperature,whereastheapparentporositiesaredecreased.Masslossofthesinteredsamplesat1500℃islowerthanthatat1600℃,butallthemasslossremainsapproximatelyconstantwiththeincreaseofsialoncontent.Fromthepointofthermodynamicanalysis,ComplexchemicalreactionstakeplaceinsamplesduringsinteringprocessandthevolatileofSiO(g)isresponsibleforthemasslossofsamples.Comparedtocrosssectionmicrostructureofβ-sialon/Al2O3/SiO2mixturessinteredincokepowderbedconsistingofthedensecenterwithwell-developedcolumnofsialonphase,thetransitionalpartwithneedlelikegrainnitrogen-containingphaseandtheloosepartwithshortgranularAl2O3phase,thoseofmixturessinteredinflowingnitrogenisofwell-developedsialonindensecenterandslightlyloosepartwithsialondebris.

简介：MicrostructureandgrainboundarycharacterofhotpressedbinaryAl2O3(mullite,ZrO2)-SiCompositesandquaternaryAl2O3-mullite-ZrO2-SiCcompositewerestudiedbyelectronmicroscopyandmicroanalysis,ResultssuggestthatthereexistgrainboundarysolidsolutionsduetoelementaldiffusionnearSiCandmatrixoxidesgrainboundaries.

简介：Themicrostructureandslagerosionfractaldimensionofreactioninterfaceofβ-Sialon-Al2O3brickusedin300MtironladleofBaosteelhavebeenstudiedbySEMandXRD.Theresultsindicatedthatβ-Sialon-Al2O3brickexhibitedexcellentslagresistance.Themainwearmechanismofβ-Sialon-Al2O3brickismainlyfromthespallingcausedbythermalmechanicalstressandattackedbyslagsecondly.

简介：Al2O3-MgOcastableshavebeenwidelyusedforworkingliningsofsteelladleduetotheirsuperiorhotstrengthandcorrosionresistance.Inthiswork,effectsofmicrosilica,ultrafinealuminaandMgOfinesadditionsontherheologicalbehaviorofthecastableswereinvestigatedbymeansofIBBrheometerV1.0tomeasuretorque(shearstress)undervaryingshearrates.Theresultsshowthatrheologicalpropertiesofcastablesatvaryingshearratesaresignificantlyimprovedwithincreaseofmicrosilicaadditions(from1mass%to5mass%)andcorrespondingdecreaseinwateraddition;thereisonlylittlechangeinrheologicalbehaviorwithvariationofultrafinealuminaandMgOfinesadditions.Optimumultrafinealuminaandmicrosilicaadditionsarerecommendedforcastableswithgoodrheologicalbehavior.

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简介：TheinfluencesoffourkindsofadditivesaddedintothematrixofMgO-Al2O3unbunedproductswereinvestigated,TheresultsshowthatsampleswithproperMgO/Al2O3rationandproperadditionofCr2O3(2%-4%)havegoodthermalshockresistanceandslagcorrosionresistanceaswell,XRDandSEMdeterminationresultsindicatethatakindofcompoundspinel(Mg,Al,Cr)O4wasformedandthemicrostuctureofthesamplesaredenser.

简介：TiN-Al2O3compositepowderswithdifferentTiNcontents(0,10vol%,20vol%,30vol%and40vol%)werepreparedwithmicrometerTiNandα-Al2O3powder(theirpuritieswere99%)asstartingmaterialsbywetballmillingfor5h.TiN-Al2O3compositewerethenpreparedbypressingtheabovecompositepowders,dryingat200℃for12handfiringat1800℃for3hinnitrogenatmosphereinhot-pressingfurnace.TheinfluencesofTiNcontentonmechanicalpropertiesandelectricalconductivityofTiN-Al2O3compositeswerestudied.TheresultsshowedthatthemechanicalpropertiesofthecompositeincreasedwithTiNcontentincreasing,whiletheresistivityofcompositesdecreased.Acompositewith40%TiNhad498MPabendingstrength,4.285MPa·m1/2fracturetoughness,1.34×10-3Ω·cmresistivity.TheSEManalysisshowedthatthefineTiNcrystalsdistributedamongthecrystalboundaryofAl2O3matrix.Theybondedtogetherforminganet-likestructurewhichplayedaroleofrestrainingAl2O3grainsfromgrowingup,tougheningandstrengthening,sothemechanicalpropertiesofTiN-Al2O3compositewereenhanced.

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简介：LowcementAl2O3-SiO2castableswaspreparedusingsupergradebauxite(w(Al2O3)>85%)asaggregate,brownfusedcorundum,siliconcarbide,Secar71CAcement,α-Al2O3micropowderandmicrosilicaasfinepowders.TheinfluenceofSiC(0,5wt%,10wt%,and15wt%)onresistancetoPbO-richslagwasinvestigatedbystaticcrucibleslagtest(1300℃for5h,inair).TheslagcorrosionmechanismofthecastableswasanalyzedbymeansofSEM,EDSandXRD.TheresultsshowthattheresistanceofAl2O3-SiO2castablestoPbO-richslagisimprovedobviouslybytheadditionofSiC.ThecorrosionmechanismofthePbO-richslagcanbediscribedasthatPbOintheslagreactswithSiO2andCaOinAl2O3-SiO2castables,forminglow-meltingcompounds(suchasPbO·SiO2and2PbO·SiO2).

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简介：TheinfluenceofthreedifferentAl2O3powderonself-flowingaluminacastablewasstudied.MaximumcompactionofsamplewascomputedbyAndresenEquation.TheresultshowedthattheAl2O3powder,whichhasmuchsmallerparticlesize,couldimprovethemicrostructureandthemechanicalpropertiesofcastableunderroomtemperatureandhightemperature.Withthesamepowdersize,theroomtemperaturestrengthofthecastableaddedwithAl2O3powderproPertiesofwhichwerealteredbyaddingmineralizingagent,washigherthanthatofthecastableaddedwithcommonAl2O3powder,buttheflowabilityofthesethreedifferentcastablewasalmostthesame.