Influence on Conductivity of Polyparaphenylene by Chemical Doping and Ion Implantation

(整期优先)网络出版时间:1999-02-12
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Polyparaphenylene(PPP)ispreparedbyAlCl3-CuCl2catalystswithbenzeneasthemonomerandisdopedbychemicalmethodandN^+ionimplantation.Theinfluencesoftheconcentration,temperatureandtimeofchemicaldopingandthedose,energyandtemperatureofionimplantation,onPPPconductivityareinvestigated.TheresultsshowedthattheconductivityofPPPcanbeimproved4-5ordersofmagnitudebyionimplantationandtheconductivityofPPPcanreachabout0.11S·cm^-1bychemicaldoping.Thecomparisonofstabilityofthematerialconductivebehaviorbyusingthetwodopingmethodsispresented.Itshowsthationimplantationisbetterthanchemicaldopinginstabilizingtheelectricconductivebehaviorforthematerial.