简介：DuetofastdevelopmentofChinesesteelindustry,continuousadjustmentofproduct,improvementofquality,researchofvalue-addedproduct,RHtechnologyissignificantlydeveloped.MoreandmoresteelplantsarecoveredwithRHfacilities.RHratioisgrowingrapidlyaswell.Overpastdecade,throughassimilatingadvancedforeigntechnologiesandfurtherrefiningthem,ChineselargescalesteelplantsmasterthetechnologyofRHproduction,operation,maintenanceandmakeitmorewidespread.RHfunctionsarewellappliedandimproved.RHismorewidelyeffectivelyputintouse.Throughindependentinnovation,RHcoredevicesandtechnology,suchasRHvacuumpump,oxygentoplance,vacuumvesselpreheatinglance,ladleliftingdeviceetc.haverealizedlocalization.Thedevelopmentofequipmentdesign,softwaredesign,equipmentmanufacturingtechnology,equipmentmounting,testtechnologyandEPCmanagementmakesequipmentconfigurationmoreflexible,equipmentmorefunctionalandstable,easiertooperateandmaintain.Italsoguaranteeshighlyeffectiveandlowenergyconsumptionproductionandqualityofsteel,reachesinternationaladvancedlevel,lowersthecostofRHconstructionandoperation,makesafter-sakeservicemoreconvenient.HowtocontinuouslyoptimizeanddevelopRHprocess,equipmentandcontroltechnology,inordertomeettheneedsofproductwithmorereasonableandeconomicprocess,exploitpotentialities,buildmoreeffective,lowercost,lowerenergyconsumption,protectingenvironmentRHfacilitieswillbethekeypointoffutureRHtechnologydevelopmentinChina.

简介：CeO2andCuOx-CeO2supportedpotassiumcatalystsweresynthesizedbywetnessimpregnationmethod.ThecatalystswerecharacterizedbyBET,NO-TPO,NOx-TPDandsoot-TPOmeasurements.Bythedecorationofpotassiumandcopper,themaximumsootcombustiontemperatureoftheceria-basedcatalystdecreasedto338and379°CinthepresenceandabsenceofNOunderaloosecontactmode,re-spectively.ThepronouncedlyenhancedNOoxidationabilitybycopperintroductionandNOxstoragecapacitybypotassiummodif...

简介：Thecrackingandaromatizationofn-hexaneoverH-ZSM-5modifiedbyvariousrareearthswereinvestigatedbymeansofcontinuousflowmicro-reactor.ThesurfacepropertiesofmodifiedH-ZSM-5catalystswereobtainedfromIR,XRDandXPS.Theresultsshowthattherareearthsenhancethearomatizingpropertiesofthecatalystswhicharepreparedbymechanicalmixturemethod.Theresultsofn-hexanecrackingandaromatizationarecorrelatedwiththeacidity.TheBrnstedacidicsitesaretheactivesitesofn-hexanearomatization,whileLewisacidsiteplaysanimportantroleinn-hexanecracking.

简介：Thehistoryofthedevelopmentofthetube&pipedivisionofBaosteelwasreviewedinthearticle,focusingontheprocessoftechnicalinnovationandtheproductcategoryenrichment.Thankstothetechnicalinnovation,theφ140productlinehasbecomethemostefficientoneintheworld.Withtheadvanceofconglomeracyandtheconstructionofthemostadvancedweldpipelineandtheφ460premiumqualityfinishing(PQF)line,thecatalogueofBaosteeltube&pipeproductshascoveredtheextensiverangefromthehotrolltocoldroll,theseamlesstothewelded,andalloftheproductdimensionscopefrom25.4mmto610mm.Tomeettherequirementsofrelevantindustriessuchasenergy,transportation,machinery,ammunitionandotherrelevantindustries,theproductvarietyisdivertingfromcarbonsteeltoalloysteel,stainlesssteelandspecialalloys.AstheBaosteelSteelTubingPlantincreaseditsnumberofproductionunits,expandeditsproductioncapacityanddevelopednewproducts,ithasgrownintoapipeandtubesupplierwithglobalcompetitiveness.

简介：Withcoalgasasareducingagent,thecatalyticreductionofSO2tosulfurinthefluegasproducedinmetallurgicalprocesseswasstudiedovercatalystsofrareearth-Fe/Al2O3(REFe/Al2O3).ThecatalyticactivityoftheREFe/Al2O3catalystonthereductionofSO2tosul-furwasinvestigatedbasedonkindsandthecontentsofrareearthsanddifferentpreparationmethodofthecatalyst.Additionally,themecha-nismofthiscatalyticreductionreactionwasalsoexplored.ResultsshowedthatdifferentrareearthimposeddifferenteffectontheactivityoftheFe/Al2O3catalyst.Especially,theadditionofSmandDygreatlyimprovedthecatalyticactivityofFe/Al2O3.TheyieldofsulfuroverSmFe/Al2O3wasincreasedto86.62%at360℃,whichwas40.5%higherthanthatoverFe/Al2O3atthesametemperature;andthesulfuryieldoverDyFe/Al2O3wasincreasedto91.62%at400℃,26.4%higherthanthatoverFe/Al2O3.ThecatalyticactivityofREFe/Al2O3wassomehowdependentonthecontentofrareearth.ForSmFe/Al2O3,thecontentofSmwasoptimizedtobeabout1.0wt.%.Therareearthcatalystpreparedwithdifferentmethodsalsoshowedvariedactivity.Thesulfuryieldoverrare-earthtransitionmetalcatalystsfollowstheorder:SmandironsolutionmixingimpregnationSmfirst,thenironsolutionimpregnationironfirst,thenSmsolutionimpregnation.ThereactionmechanismofSO2reductiontosulfurwithcoalgaswasproposedtobeanintermediatemechanism.

简介：Aseriesofcoal-basedactivecarbon(AC)catalystsloadedbyFe-Cu,Fe-Cu-CeandFe-Cu-Lawerepreparedbythesol-gelmethodforcarbondisulfide(CS2)hydrolysisandtheirperformancesforCS2hydrolysisinafixed-bedreactorwereinvestigatedinthiswork.TheresultsshowedthatthekindofrareearthoxideanditscontenthadobviouseffectonhydrolysisremovalofCS2.Theeffectsoftemperature,spacevelocity,CS2concentrationandO2concentrationwerealsodiscussedrespectively.Furthermore,thesuitableoperatingconditionswereobtained.Itwasfoundthatthepoisoningofhydrolysisactivesitescouldresultintheformationofsulfuricacidonthecatalystsurface.

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简介：TwonovelwashcoatsCe0.8Zr0.15La0.05OδandCe0.8Zr0.2O2waspreparedbyanimpregnationmethod,whichactedasahostfortheactivePdcomponenttopreparePd/Ce0.8Zr0.15La0.05Oδ/substrateandPd/Ce0.8Zr0.2O2/substratemonolithiccatalystsfortoluenecombustion.ThewashcoatswascharacterizedbyX-raydiffraction(XRD),Ramanspectroscopy,Brunauner-Emmett-Teller(BET),andH2-temperature-programmedreduction(H2-TPR).Theresultindicatedthatboththewashcoatshadstrongvibration-shockresistanceaccordingtoultrasonictest.DopingLa3+intoCeO2-ZrO2solidsolutioncouldgeneratemoreoxygenvacancies,andcouldinhibitthesinterofCeO2-ZrO2solidsolutionwhencalcinedathightemperatures(800,900and1000°C).ThewashcoatCe0.8Zr0.15La0.05Oδhadmuchbetterredoxproperties.ThereductivetemperatureofCe4+speciesshiftedtolowtemperatureby60°Cwhenthewashcoatscalcinedathightemperatures(800,900and1000°C).ThePd/Ce0.8Zr0.15La0.05Oδ/substratemonolithiccatalystcalcinationat500°Chadthebestcatalyticactivityandthe95%tolueneconversionatatemperatureaslowas190°C.Whencalcinedatlowtemperature(500and700°C),thecatalyticactivityhaslittleimprovement,however,whencalcinedathightemperature,thecatalyticactivityofPd/Ce0.8Zr0.15La0.05Oδ/substratemonolithiccatalystshadsignificantimprovement.Ascatalystwashcoat,theCe0.8Zr0.15La0.05OδhadbetterthermalstabilitythanthewashcoatCe0.8Zr0.2O2,thedevelopedPd/Ce0.8Zr0.15La0.05Oδ/substratemonolithiccatalystinthisworkwaspromisingforeliminatingVolatileorganiccompounds.

简介：混合氧化物(Ce0.6Zr0.4O2)由帮助微波的加热一起沉淀准备了的CeO2-ZrO2被用作支持经由早期湿的受精的方法与各种各样的CuO内容(0wt.%15wt.%)准备一系列CuO/Ce0.6Zr0.4O2催化剂。获得的CuO/Ce0.6Zr0.4O2样品被N2吸附，XRD，拉曼，TEM和H2-TPR技术，和他们的催化活动描绘因为公司氧化被调查。结果证明CuO/Ce0.6Zr0.4O2催化剂的活动被CuO的内容强烈影响，并且有10wt.%CuO的催化剂在公司氧化展出了最好的催化活动，它能在催化剂被归因于CuO，和高氧空缺集中的高分散和reducibility。

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