简介:DNAcondensationisanimportantprocessinmanyfieldsincludinglifesciences,polymerphysics,andappliedtechnology.Inthenucleus,DNAiscondensedintochromosomes.Inpolymerphysics,DNAistreatedasasemi-flexiblemoleculeandapolyelectrolyte.Manyagents,includingmulti-valentcations,surfactants,andneutralpoorsolvents,cancauseDNAcondensation,alsoreferredtoascoil–globuletransition.Moreover,DNAcondensationhasbeenusedforextractionandgenedeliveryinappliedtechnology.ManyphysicaltheorieshavebeenpresentedtoelucidatethemechanismunderlyingDNAcondensation,includingthecounterioncorrelationtheory,theelectrostaticzippertheory,andthehydrationforcetheory.Recentlyseveralsingle-moleculestudieshavefocusedonDNAcondensation,sheddingnewlightonoldconcepts.Inthisdocument,themulti-fieldconceptsandtheoriesrelatedtoDNAcondensationareintroducedandclarifiedaswellastheadvancesandconsiderationsofsingle-moleculeDNAcondensationexperimentsareintroduced.
简介:UsingaDMT(DropletMeasurementTechnologies)continuousflowstreamwisethermalgradientcloudcondensationnuclei(CCN)countermountedonaCheyenneⅢAaircraft,about20flightsforaircraftmea-surementsofCCNoverNorthChinawereconductedintheautumnof2005andspringof2006.Accordingtothedesignforaircraftobservation,themethodofspiralascentordescentinthetropospherewasusedfortheverticalmeasurementofCCN,andsomecertainlevelswerechosenforhorizontalmeasurement.TheverticaldistributionsofCCNconcentrationsshowthatmostCCNparticlesareconcentratedinthelowleveloftroposphereandCCNconcentrationdecreasedwithheightincreasing.ItsuggeststhatthemainsourceofCCNisfromthesurface.Thisresultisconsistentwithformerstudiesduring1983-1985inChinawithastaticthermalgradientCCNcounter.ThecomparisonofverticalobservationsbetweenpollutedruralareanearShijiazhuangandnon-pollutedruralareanearZhangjiakoushowsthatthereisaboutfivetimesdifferenceinCCNconcentration.Butovertwopollutedcities,ShijiazhuangandHandan,thereisnonotabledifferenceinCCNconcentration.ThehorizontalflightmeasurementsforpenetratingthecumuluscloudsexperimentshowtheapparentdecreaseofCCNinclouds.ItconfirmsthatcloudhasadefiniteconsumptiveeffectonCCNparticlesbecausesomeCCNparticlescanformclouddroplets.ThesurfacemeasurementsofCCNinShijiazhuangCityweremadeduringJune-August2005.Thesta-tisticalCCNdatashowthegreatdifferenceinconcentrationatthesamesupersaturation(S)inShijiazhuangsummertime.TheminimumCCNconcentrationswere584,808,and2431cm~(-3),andthemaximumconcen-trationswere9495,16332,and21812cm~(-3)atS=0.1%,0.3%,and0.5%,respectively.CCNhasadiurnalvariationcycle.From0600BT,theconcentrationbegantoincreaseandreachedthemaximumataboutnoon.Thenitgenerallydecreasedthroughouttheafternoon.Thereasonmaybeisrelatedtotheonsetofemissionsfromvehiculartraffi
简介:Amodificationofthetransitionstatetheoryforevaporationandcondensationispresentedbyanalysingthekineticcharacteristicsofliquid-vapourinterphasetransport.Inthemodifiedtransitionstatetheory,themovingorientationofmoleculesisintroducedintothecalculationofthefreevolumeoftheactivatedcomplex.Thecondensationcoefficientsofargonatdifferenttemperaturesarecalculatedwiththemodifiedtransitionstatetheory.Theresultsagreewellwiththosefrommoleculardynamicssimulations.
简介:Themajorflowphysicsoftheunsteadycondensationinthesubsonicflowsinducedbytheunsteadyexpansionwavesinshocktubewasstudiedinthispaper.Theunsteadycondensationphenomenonwasanalyzedbyusingthetwo-dimensional,unsteady,Navier-Stokesequations,whichwerefullycoupledwithadropletgrowthequation.Thethird-orderTVDMUSCLschemewasappliedtosolvethegoverningequationsystems.Thecomputationalresultswerecomparedwiththepreviousexperimentaldata.Thetime-dependentbehaviorofunsteadycondensationofmoistairinshocktubewasinvestigatedindetails.Theresultsshowthatthemajorcharacteristicsoftheunsteadycondensationphenomenoninshocktubeareverydifferentfromthoseinthesupersonicwindtunnels.
简介:Thehomogeneousnucleationwithsubsequentspontaneouscondensationofwater,pentanol,andethanolvaporsinacarriergasareinvestigatedexperimentallyandtheoreticallyintheexpansionpartofashocktube.TheprecisepressureandMCWmeasurementsgiveadditionalinformationaboutthewetness,sothatthenucleationandcondensationrateswhicharecloselycoupledforstrongerexpansionratesaredetermiedmoreaccurately,Predictionsoftheprincipleoftheminimumofentropyproductionarecomparedwithexperimentsperformedforwater,ethanolandpentanolatdifferentpressures.
简介:Thispaperintroducesamethodforstudyingcondensationheattransferinsideatubeinmicrogravityenvironment.Themodelassumeslaminarflowinthecondensatefilmandanannularflowpattern,Thelocalheattransfercoefficinetisthecalculatedbygravitationalacceleration,g,from0to9.8m/s^2.themodelwastestedindirectlybymeasuringcondensationheattransferinsideaverticaltubeinanormalgravityenvironmentthroughexperiments.
简介:Amodelwasestablishedtopredictcondensationheattransfercoefficientonhorizontalrectangularfinnedtube.Drop-Offzoneatthetubebottomwasconsideredanddetermined,theknownHonda(andOwen)expressionofretentionanglewasalsomodifiedasaresultofconsideringdrop-offzone.Heatfluxonfintipsintheunfloodedregion,finflanks,finspacingsandfintipsinthefloodedregionwereanalyzedrespectively.COndensationonfintipsinemphasizedbyconsideringthevariationoffilmthicknessalongcircumferenceaswellashorizontally.FInefficiencywasconsideredincalculation.Thepredictionresultswerecomparedwithseveralresearchers'experimentaldataforthreekindsofworkingfluidsonsevendifferenttubegeometriesandforvarioustemperaturedifferences,Thesedataunderabout60testconditionswerepredictedwithdiscrepancyof±10%.PredictionbythepresentmodelforsteamandR-113condensationwerecomparedwithpreviousmodels.
简介:HyperbranchedaromaticpolymerswerepreparedbyFriedel-CraftsreactionwithLewisacid,AlCl3andZnCl2,asthecatalysts.Inthiswork,hyperbranchedpolybenzyl(PB)andpoly(methylene)naphthalene(PN)weresynthesizedandcharacterizedby1H-NMRandGPC.Inaddition,theirflorescencepropertiesweremeasuredwithsteady-stateflorescencespectrainTHFandethylenedichloride.Thequantumyieldsofpolybenzylandpoly(methylene)naphthaleneinethylenedichloridearemuchlargerthanthoseinTHF.``
简介:干燥冷却的联合使用(DC)系统和奉献通风(DV)到decouple为精力效率冷却和除去湿气过程的系统为象香港一样的副热带的气候被建议。在这研究,DCDV系统的使用的精力性能和冷凝作用风险被在香港在一座典型办公大楼分析它的应用程序检验。通过用实际设备性能数据和现实主义的大楼和系统特征的hour-by-hour模拟,与DCDV系统的使用,年度精力消费能被54%与常规系统比较减少,这被发现(经常的空气体积与再热系统)。关于冷凝作用风险,DC卷上的冷凝作用的出现的年度频率是35h,这被发现。另外的模拟被进行在DCDV系统的冷凝作用风险上检验不同参数的影响。保证的措施在DC上没有冷凝物卷也被讨论。
简介:Whencondensationoccursinsupersonicflowfields,theflowisaffectedbythelatentheatreleased.Inthepresentstudy,Navier-Stokesequationsweresolvednumericallyusinga3rd-orderMUSCLtypeTVDinite-differenceschemewithasecond-orderfractional-stepfortimeintegration,Baldwin-Lomaxmodel,thatisthealgebraicmodel,calledthezeroequationmodelwasusedinthecomputations.Theeffectsofinitialconditions(initialdegreeofsupersaturationandtotaltemperatureinthereservoir)oncondensingflowofmoistairinasupersoniccircularhalfnozzlewereinvestigated.Inthiscase,theeffectofcondensationontheboundarylayerwasalsodiscussedindetail.Asaresultthesimulatedflowfieldswerecomparedwithexperimentaldataingoodagreement,andthevelocityandtemperatureprofileswerelargelychangedbycondensation.
简介:Twoseriesofnewcompounds:thealiphaticacylaminoethylglycines(Ⅰ)andtheircyclo-condensationproducts-allphaticacylaminoethylplperazlnones(Ⅱ)weresynthesized.Theresultsofbactericidalandbacteriostatictestsshowthatthetwoseriesofcompoundsaregoodbactericldalagents.
简介:在这研究,在比率AR是其方面的攻击=00的角度的接近音速的流动过去NACA0012侧面1.0被数字分析用一个TVD计划与非平衡冷凝作用分析并且用一种断断续续的吸入类型被调查超声的风隧道。在有停滞亲戚湿度(0)的变化的免费溪流马赫数字的0.780.90的接近音速的流动被测试。为一样的免费溪流马赫数字,在是的侧面的drag系数的0原因减少的增加形式的drag部件创作了,粘滞并且波浪。在一样的M和T0的情况中,为超过0=30%,尽管有在非平衡冷凝作用的过程的不能反逆的性能,由冲击波的drag随0的增加更加减少。在另一方面,它证明形式的drag系数上的冷凝作用的效果并且粘滞是可以忽略的。作为一个例子,在侧面的drag系数的减少的率为M=0.9和0=50%数量的案例由非平衡冷凝作用的影响引起了到34%。另外,这被生产超声的水泡的尺寸(也就是说超声的地区的最大的高度)并且从为有为一样的M的0的增加的M=1减少的价值的压力系数的偏差。
简介:Controlofsupersonicflowfieldswithshockwaveisimportantforsomeindustrialfields.Therearemanystudiesforcontrolofthesupersonicflowfieldsusingactiveorpassivecontrol.Whennon-equilibriumcondensationoccursinasupersonicflowfield,theflowisaffectedbylatentheatreleased.Manystudiesforthecondensationhavebeenconductedandthecharacteristicshavebeenalmostclarified.Further,itwasfoundthatnon-equilibriumcondensationcancontroltheflowfield.Inthesestudies,thecondensationoccursacrossthepassageoftheflowfieldanditcausesthetotalpressurelossintheflowfield.However,localoccurrenceofnon-equilibriumcondensationintheflowfieldmaychangethecharacteristicsoftotalpressurelosscomparedwiththatbythecondensationacrossthepassageofthenozzleandtherearefewforresearchesoflocallyoccurrednon-equilibriumcondensationinsupersonicflowfield.Thepurposeinthepresentstudyistoclarifytheeffectoflocaloccurrenceofnon-equilibriumcondensationonthetransonicflowfieldinanozzlewithacircularbump.Asaresult,localoccurrenceofnon-equilibriumcondensationreducedtheshockstrengthandtotalpressurelossinthetransonicflowfieldbyflowingthemoistairfromtrailingedgeofthecircularbumptothemainstream.
简介:Removalofcondensatesfromwetsteamflowinthelaststagesofsteamturbinessignificantlypromotesstageefficiencyandpreventserosionofrotors.Inthispaper,homogeneousspontaneouscondensationintransonicsteamflowinthe2-Drotor-tipsectionofastageturbineisinvestigated.Calculatedresultsagreewithexperimentaldatareasonablywell.Onthebasisoftheabovework,a2-Dnumericalsimulationofwetsteamflowinadjacentrootsectionsofacomplexsteamturbinestagewascarriedout.Computationalresultswereanalyzedandprovideinsightsintoeffectiveremovalofhumidity.
简介:Inthispaper,theannularflowmodelforin-tubecompletedcondensationisemployedtopredictthesteadyflowcondensationheattransfercharactersticsinatubeunderzero-gravitation.Inthiscase,itisproposedthatvaporcondensesontheliquidfilmsurface.Duetotheeffectofsurfacetension.Thelituidexistsintheformofliquidfilmringcontactingwall;whenthevelocityofvaporcoredecreasestozero,thecondensationprocessends.Puttingforwardthephysicalandmathematicalmodels,theproblemissolvedandthemulti-orderequationofthethicknessofliquidfilmisobtained.Whichincludestermsofthepressuregradientalongaxialdirection.thefrictionforcebetweenvaporandliquidoninterface.Bycomputationalcalculation,thismodelcanbeusednotonlytopredictthethicknessofliquidfilm,thecondensationpressuregradientalongtheaxialdirection,butalsotodeterminetheNusseltnumber,thecondensationleagthandthetotalflowprssuredropofcondensationetc.Attheend,thecalculationresultsofthenecessarycondensationlengtharecomparedapproximatelywiththosefromtheexperiments,whichareobtainedonthetestset-upplacedhorizontallyingravitationfield.andthedeviationisanalyzed.