简介：ThispaperreportsthephotochemicaldegradationofMethyleneBlue(MB)innaturalseawater(NSW).Thephotode-gradationreactionconformedtothefirst-orderreactionkineticswiththerateconstant0.0158min-1.MBwasphotochemicallyde-gradatedfasterunderhigh-pressuremercurylamp(HPML)thanundersunlight.WhenMBwasinlowerconcentrations,salinitycouldinhibitthephotoreactionwhereasMBinhigherconcentration,salinitycouldacceleratethephotoreaction.Humidacidcouldalsoinhibitthephotoreactions.ToxicitytestswithmarinephytoplanktonSkeletonemacostatum(Sk)andHeterosigmaakashiwoHada(Ha)showeddecreasedacutetoxicityafterphotodegradation.

简介：

简介：Thenoveldicyanateesterresincontainingnaphthaleneunit(DNCY)wassynthesized,andcharacterizedbyFT-IR,^1H-NMR,^13C-NMRandelementalanalysis(EA),ThethermalpropertiesofDNCYresinwasstudiedbythermaldegradationanalysisataheatingrateof10℃/min^-1inN2andair,TheDNCYrdsinexhibitedbetterthermalandthrmal-oxidativestabilitythanbisphenolAdicyanate(BACY)resin.

简介：阶段PVDF水晶结构和在先存在的阶段PVDF球粒以内的豌豆的结晶化上的豌豆的效果被光显微镜学OM，红外线的光谱学红外和扫描电子显微镜学SEM调查了。结果证明阶段PVDF球粒由展出高度弄弯的像滚动的形态学的lamellae组成并且在充满豌豆的混合优先地发展。与增加豌豆集中，滚动直径增加和滚动更好与对方被分开。豌豆在interspherulitic区域使第一结晶，transcrystalline层发展。随后，豌豆的transcrystalline层继续在阶段PVDF球粒以内成长，例如在在滚动之间的区域，直到在另外的豌豆transcrystalline层或球粒上侵犯。结晶化动力学结果显示在阶段PVDF的intraspherulitic区域的豌豆晶体的生长率与阶段PVDF的结晶化温度与豌豆，而是否定豌豆的内容显示出积极关联。

简介：

简介：

简介：在这研究，我们在温和碱的条件下面与极佳的吸附性质为hydrogels的准备选了玉米stover为hemicellulose。克莱nanosheets被介绍给这个系统，hemicellulose/clay混血儿hydrogels被准备。词法、机械性质和准备hydrogels的甲又蓝色吸附行为被学习。结果建议泥土的增加不仅改进了基于hemicellulose的hydrogels的机械力量，而且在甲又蓝色上增加了吸附能力。而且，吸附被证实有或没有泥土为两胶化跟随伪秒顺序方程。为基于hemicellulose的hydrogels与或没有泥土的甲又蓝色上的最大的吸附能力分别地到达了148.8和95.6mg/g。这些结果暗示基于hemicellulose的hydrogels能从浪费水为甲又蓝色的移动被用作有希望的吸附物。

简介：PVDF的词法特征上的PBS的效果被光、原子的力量显微镜学在各种各样的条件下面调查了。整洁的PVDF在170戠?与非常地弱的birefringence形成大表格球粒，这被发现?M

简介：

简介：Aseriesofpolybenzoxazoles(co)polymersbearingcrankshaftunitsinthemainchainwassynthesizedbytheconventionalsolutionpolycondensationof4,6-diaminorescinoldihydrochloride,terephthalicacid(TA)and2,6-naphthalenedicarboxylicacid(NDA).Allofthepolymersshowlyotropicliquidcrystalbehaviorinpolyphosphoricacid(PPA)andmethanesulfonicacid(MSA).Thepolybenzoxazolesexhibitanexcellentthermalresistancealthoughthecrankshaftmonomerhasbeenintroducedintothepolymerbackbone.Thetemperatureforthe5%weightlossofallthepolymersisabove600℃.TheX-raydiffractionanalysisresultsshowthattheseriesofthepolymershasahighcrystallinity.TheintroductionofNDAmakesaslightdecreaseinthethermalresistanceofthepolymers.ThemaximumabsorptionpeakintheUV-Visspectracanbeadjustedaccordingtotheamountof2,6-naphthaleneunitsinthepolymers,whichindicatesthepotentialapplicationofthepolymersasoptoelectriematerials.

简介：茶消耗量能作为cationic染料把甲又蓝色(MB)从相应于秒顺序的浪费水移开运动模型。热力学的研究显示出那个吸附平衡常数(KL)，最大的吸附能力(Qmax)与增加温度被增加。为以最佳条件的公司0.01mmol/L的MB的移动效率是大约85%。在一个批反应堆的甲又蓝色的最大的举起能力(Qmax)是在15，25和40点的0.328，0.542和0.659mmol/g

简介：Sm(Ⅲ）wasquantitativelyadsorbedbyaminomethylenephosphonicacidresin(APAR)inthemediumofpH=5.0,Thestaticallysaturatedsorptioncapacityis251mg/g.resin.Sm(Ⅲ）adsorbedonAPARcanbereductivelyelutedby2.0mol/LHCl.Thesorptionrateconstantisk298=1.35×10^-5s^-1.ThesorptionbehaviorofAPARforSm(Ⅲ）obeystheFreundlichisotherm.TheenthalpychangeΔH°ofsorptionis24.9kJ/mol.TheapparentactivationenergyisEa=11.7kJ/mol.ThesorptionmechanismshowsthatthenitrogenandoxygenatomsofthefunctionalgroupofAPARcoordinatedwithSm(Ⅲ）toformcoordinationbond.

简介：Ithasbeenwellknownthatfluorinatedpolyurethanesexhibituniquelylowsurfaceenergy,biocompatibilityandbiostability,thermalandoxidativestabilityandnonstickingbehavior.Consequently,thesepolymershaveattractedconsiderableinterest.However,themechanicalpropertiesoffluorinatedpolyurethanesusuallydeclinewithincreasingfluorinecontents.Theblendingoffluorinatedpolyurethaneswithnormalpolyurethanewascarriedouttoachievebalancedmechanicalandsurfaceproperties.Itwasfoundthatpolyurethanewithgoodmechanicalpropertiesandlowsurfaceenergycanbeobtainedbyaddingasmallamountoffluorinatedpolyurethane.Thefluorinatedsidechainscaneasilymigratetouppermostsurfacesoftheblendsuntillthefluorinelevelatthesurfacebecomesalmostsaturated.Ithasbeenshownfromcontactangle,XPSandAFMmeasurementsthatonlyaslittleas0.34wt%offluorinelevelisenoughtoproduceasurfacesaturatedwithfluorine,andthefluorinelevelattheuppermostsurfaceisonehundredtimeshigherthanthatintheblendbulk.Thefinaloutersurfacestructuresofthepolyurethaneblendwereindependentofthecontentofthefluorinatedpolyurethaneintheblendsduetothesurfacessaturatedbyfluorine.

简介：

简介：Anovelsmallband-gapconjugatedpolymer-poly[(3-acetylpyrrole-2,5-diyl)(4-dimethylaminobenzyliene)(3-aeetylpyrrolequinodimethane-2,5-diyl)](PAPDMABE)-anditsprecursorweresynthesizedbyasimplemethodandcharacterizedby1H-NMR,FT-IR,TGAandUV-VIS.ThepolymercanbedissolvedinstrongpolarsolventssuchasDMSO,DMForNMP.Theband-gapenergyofPAPDMABEwasfoundtobe0.95eV.Theconductivityofdopedproductswithiodinefallsintherangeofasemiconductor.``

简介：3-Ethynyl-4-（trimethylsilyl）thiophene（1a）and3-ethynyl-4-bromothiophene（1b）selectivelyundergoacetylenepolymerizationsinthepresenceoftheMoCl5-andWCl6-Ph3SiHcatalyststogivesoluble,high-molecular-weightpoly（thienylacetylenes）（2）（Mwupto602000）inhighyields（upto100%）.LighttransmissionspectraofTHFsolutionsof2continuouslyred-shiftwithincreasingconcentration.Theconcentratochromismshowsalogarithmicconcentrationdependence;thatis,theopticaltransitionsof2arepredictablytunablebysimplychangingtheirconcentrations.

简介：Anewkindofmonomerswassuccessfullysynthesizedbythereactionbetween2-chloromethylcycloketalandtrimethylsilylcyanide,followedbyringclosureanddehaiogenation.Polymerizationsofthemonomerswerecarriedoutinbenzenesolutionat80℃withbenzoylperoxideasinitiator.BoththestructuresofmonomersandpolymerswerecharacterizedbyIR,1HNMR,13CNMRandelementalanalysis.

简介：

简介：Poly(4-vinylpyridine)(P4-VP)nanofiberandfluoresentpoly(4-vinylpyridine)/porphyrin(P4-VP/TPPA)nanofiberwererespectivelypreparedbyelectrospinning.TheeffectoftheconcentrationofP4-VP/dimethylformamide(DMF)electrospinningsolutionsonthemorphologyofP4-VPnanofiberwasinvestigatedanditwasfoundthattheaveragediameterofthenanofiberofP4-VP/DMFincreasedwiththeincreaseoftheconcentrationofthespinningsolution.AftertheadditionofTPPAtotheP4-VP/DMFspinningsolution,thediameterofP4-VP/TPPAnanofiberbecameevenduetotheincreaseoftheconductivityoftheP4-VP/DMF-TPPAsolution.Thephotoluminescent(PL)spectralanalysisindicatesthattheemissionpeakpositionofP4-VP/TPPAnanofiberisalmostthesameasthatofpureTPPAatabout650nmwithoutpeakshift,andwhenitwasstoredfor20days,theemissionpeakofP4-VP/TPPAnanofiberisalsoat650nm,indicatingthatthefluorescentpropertyofP4-VP/TPPAnanofiberisstable.Fourier-transforminfrared(FTIR)spectrumconfirmsthechemicalcompositionoftheresultingP4-VP/TPPAcompositenanofiber.

简介：二氧化碳共聚物聚氨酯胺PUA与聚丙烯碳酸盐PPC被混合以便没有牺牲另外的机械性质，改进PPC的坚韧和灵活性。与纯PPC相比，有装载的5wt%PUA的PPC/PUA混合证明400%在裂缝在延伸增加，虽然相应让步力量象稍微显示出的33.5MPa和幼仔模量一样仍然保持高减少。在PPC/PUA的结合的相互作用混合的分子间的氢被FTIR，2D红外和XPS系列分析，和PUA的细微地驱散的微粒结构在PPC证实在SEM图象被观察，它为PPC的韧化的机制提供了好证据。