简介:DiamondfromLiaoning,Chinawasstudiedbysynchrotronradiationandinfraredspectrum.Thedistributionofdislocationsinthespecimenthasbeenrevealed.Anewmethodtodeterminetheorientationofcrystaldefectshasbeenproposedandtheorientationindexesofthedislocationsinthespecimenwerecalculatedbythismethod.Ithasbeenfoundthatthedislocationsinthespecimentarenearbutnotpreciselyparallelto{111}planes,Themaximumanglebetweendislocationand{111}planeisabout16°.AlmostallthedislocationsinthespecimenthavethesameBurgersvector1/2[101]andimplythesamenessoftheirorigination.
简介:Thepaperdescribestheproposedmodelsofdiamondformationbothinmeteoritesandinkimberliteandlamproitebodies.metamorphiccomplexesandexplosive-ringstructures('astroblemes'),Thediamonddistributioninmeteorites(chondrites,ironmeteoritesandureilites)isrestrictedtotaente-kamasitephase.Thediamondgenerationhereistiedupwiththefirststageofevolutionoftheplanets,Thisstageischaracterizedbyhighpressureofhydrogen.leadingtotheformationoftheplanetenvelope,Thesecondstageofplanetevolutionbeganwiththeprogressiveimopoverishmentoftheiratmospheresinhydrogenduetoitspredominantemissionintothespaceandtoprogressivedevelopmentofoxidativeconditions.Themodelappearstohaveprovedtherelictnatureofdiamondmineraolizationinmeteorites.Diamondandotherhigh-pressureminerals(its'satellites')werecrystallizedwithoutanyexceptionintheearlyintratelluricstagesofperidotiteandeclogite-pyroxenitemagmaevolutionjustbeforethemagmaintrusionintothehigherlevelsofthemantleandcrustwherediamondisnotthermodynamicallystable,Theultramaficintrusivebodies(bearingrichrelictdiamonds)inthedaseofaplatformpaaeartobethesubstratafortheformationofkimberlite-lamproitemagmachambersasaresultofmagmaticreplacement.Themodelexplainsthepolyfacialnatureofdiamondiferouseclotgites,pyroxenitesandperidotitesanddiscussestheprocessofinheritanceoftheirdiamondmineralizationbykimberlitesandlamproites.Dimondoproductivityofmetamorthiccomplexesisoriginatedbytheinheritanceoftheirdiamondsfromtheabove-mentionedprimarydiamondiferousrocks.Largediamondiferousexplosive-ringstructureswereformedbyhigh-energyendogenicexplosionoffluidwhichcamefromtheEarth'score.Thishighenergydiffersendogenicimpactogenesisfromexplosivevolcanism.Itproceedsatveryhightemperaturetocreatediaplecticgalsses(monomineralpseudomorphs)-theproductofisochoricmelting,atthepressurehighenoughforth
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简介:Thehalogenatedboron-dopeddiamond(BDD)surfaceswerereactedwithsodiumazidethroughanucleophilicsubstitutionreaction.Theresultingazide-terminatedBDDsurfaceswereusedtotriggerthe'click'reaction.Becauseoftheattractiveelectrochemicalpropertiesofferrocene-containingmolecules,suchasfastelectrontransferrates,reversibleredoxactivities,andfavorableredoxpotentials,weshowthatferrocenederivativescanbegraftedontonon-oxidizeddiamondsurfacesbyclick'chemistry'.Theseredox-activeferrocene-containinglayersonaBDDsurface,becauseoftheirabilitytostoreandreleasechargesreversibly,havethepotentialtobeusedashybridmolecular/semiconductormemorydevices.
简介:AnewtechniqueofthesynthesisofNanocrystallineDiamond(NCD)Filmsbyheliconwaveplasma(HWP)chemicalvapordepositionatroomtemperaturewasreported.ThegrowthmorphologyandtheroughnessofNCDsampleswascharacterizedusingfiledemissionscanningelectronmicroscopy(SEM-SU8010)andatomforcemicroscopy(AFM),respectively.Theresultsshowthegrowthrateofthefilmwasveryfast,about833nm/min.TypicalG,Dbands
简介:ThediamondfilmshavebeendepositedbythehotfilamentCVDmethodonmolybdenumsubstratesfromthemixturereactantgasofacetoneandhy-drogen.Thesurfacemorphologiesoftheobtaineddiamondfilmsundervariousde-positionconditionshavebeenobservedbyscanningelectronmicroscope(SEM).Theexperimentalresultsstronglyindicatethatthesurfacemorphologiesofthere-sultingfilmshavecloselyrelatedtothedepositionconditions,i.e.,reactionpres-sure.Formolybdenumsubstrates,underthelowerreactionpressurethesurfacemorphologiesofthegrainscomprisingtheresultingfilmsmainlydisplaythesmallsinglecrystalcubo-octahedronanddoublesmallcrystalcubo-octahedron;underthehigherreactionpressure,thesurfacemorphologiesmainlydisplaythelargecauliflower-like.TheseresultsshowthattherearevariouscrystalhabitsforCVDdiamondundervariousdepositionconditions.
简介:Diamond-likecarboncoatingshavebeenusedassolidlubricatingcoatingsinvacuumtechnologyfortheirgoodphysicalandchemicalproperties.Inthispaper,thehybridtechniqueofunbalancedmagnetronsputteringandplasmaimmersionionimplantation(PIll)wasadoptedtofabricatediamond-likecarbon-basedfunctionallygradientfilm,N/TiN/Ti(N,C)/DLC,onthe304stainlesssteelsubstrate.ThefilmwascharacterizedbyusingRamanspectroscopyandglancingX-raydiffraction(GXRD),andthetopographyandsurfaceroughnessofthefilmwasobservedusingAFM.Themechanicalpropertiesofthefilmwereevaluatedbynano-indentation.Theresultsshowedthatthesurfaceroughnessofthefilmwasapproximately0.732nm.Thehardnessandelasticmodulus,fracturetoughnessandinterfacialfracturetoughnessofN/TiN/Ti(N,C)/DLCfunctionallygradientfilmwereabout19.84GPa,190.03GPa,3.75MPa.m1/2and5.68MPa@m1/2,respectively.ComparedwiththatofDLCmonolayerandC/TiC/DLCmultilayer,thisDLCgradientfilmhasbetterqualitiesasasolidlubricatingcoating.
简介:Wehaveinvestigatedthephysicalproperties,includingthemorphology,texture,adhesionandchemicalquality,ofhigh-frequencychemicalvapourdepositeddiamondcoatingsonWC-6%Cosubstrates,whichwerepre-treatedbyatwo-stepetchingmethod.TheresultsindicatethattheincreasingCocontentfrom0.12to3.05%withintheetchingdepthof5μmcausedamorphologytransformationfromprismdiamondtospheruliticdiamond,andatexturetransformationfroma{111}orientationtoa{110}orientation.TheRamanspectrumshowsthatthespheruliticdiamondfilmcontainsmorenon-diamondphases(graphite,amorphouscarbonanddiamond-likecarbon,etc)andhaslowerchemicalqualitythandiamondfilmsonaWC-6%Cosubstrate.Thediamondcoatinggrainsizesbecameaboutfourtimessmallerwhenthedepositiontemperaturesonthesubstratesurfacewerereducedfrom1000to900℃.Comparedwithspheruliticdiamondfilms,theprismdiamondfilmsexhibitbetteradhesionontheWC-6%Cosubstrate.
简介:Thedesignmethodsofanodeandcathodeareproposedforprecisionprofilegrinding.Basedontheelectrolyticmachiningtheory,electrolyticequilibriumconditionandFaraday′slawofelectrolysisareappliedtoestablishingthemathematicalmodelofprofilediamonddressingprocess-es.Afiniteelementmethod(FEM)programisdevelopedtosolvetheinverseboundaryproblemofLaplace′sequation.Desiredanodecontourorcathodeshapeisdeterminedbycomputingthedistributionofelectricpotentiallayerbylayer.Electrolyticmachiningexperimentiscarriedouttoverifythesimulatedanodeshape.Theresearchresultshowsthatshapedeviationbetweendesignedcathodeandprofilewheelincreaseswiththevalueofanglebetweenfeedrateandthenormaltoanodesurface.Theshapeofsimulatedanodeisconsistentwiththecontourofmetal-bondeddiamondprofilewheelforagivencathode.Basedontheanodecontour,cathodeshapecanalsobedesignedaccurately.
简介:Tensilica公司和MediaPhy公司共同宣布,位于加州SanJOSe的MediaPhY公司获得Tensilica公司业界最低功耗的32位处理器内核一Diamond108Mjnf的授权。MediaPhy利用DiamondStandard108Mini进行手机电视产品的开发。
简介:Highlyc-axis-orientedZnOfilmsweredepositedsuccessfullyonthenucleationsidesoffree-standingdiamond(FD)filmsbythedirectcurrent(DC)magnetronsputteringmethod.Theeffectofthesputteringparameters,suchaspower,gaspressureandsputteringplasmacompositionofAr-to-O_2,onthepropertiesofZnOthinfilmswasinvestigatedindetail.X-raydiffraction(XRD)measurementsshowedthat,atasputteringpowerof200W,gaspressureof0.5PaandanAr-to-O_2compositionof1:1,ahigherintensityofthe(002)diffractionpeakandanarrowerfullwidthathalfmaximum(FWHM)weredetectedwhichmeanthighc-axisorientationandhighqualityoftheZnOfilms.ToimprovethequalityoftheZnOfilm,athinZnOlayerwaspre-grownasahomo-bufferlayer.XRDmeasurementsshowedthatthisbufferlayerhadabeneficialeffectonthestructuralandmorphologicalpropertiesofthepost-grownZnOfilm.