简介:在之中无铅焊接材料,Sn-Ag-Cu合金有许多优点优异界面的性质和高度例如好弄湿的性质,爬抵抗。在这篇文章,组织和Sn-Ag-Cu材料的焊接性能被调查。二合金的表面形态学被实体镜的显微镜观察并且扫描电子显微镜(SEM)。化学宪法被X光检查精力散的光谱学(版本)检验。Sn-Ag-Cu的机械性质焊接Sn-Cu与那些相比系统地被评估焊接。结果证明Sn-Ag-Cu焊接基于不同焊接垫不同焊接性质。在接口的金属间化合的化合物(IMC)的厚度与老化时间增加。为镀金的垫,有很多IMC图,并且在焊接连接它能减少电的连接的可靠性。Sn-Ag-Cu焊接关节表演在传统的Sn-Cu上的一个优异机械性质焊接。酒窝减少和洞的数字增加因为Sn-Cu0.7合金和Sn-Ag3.0-Cu0.5合金的破裂表面有同类地分布式的许多小尺寸酒窝。
简介:摘要贵州芙蓉江沙阡水电站两台水轮发电机组投产发电后多次发生剪断销剪断事故,偶尔伴有导叶连杆断裂情况。本文主要针对沙阡水电站导水机构剪断销剪断及连杆断裂的事故原因、检查结果、进行分析阐述。
简介:这个工作由进行批实验在沉积调查Cu离子的吸附,包括等温的实验和吸附动力学实验。从等温的实验的数据用Freundlich和Temkin模特儿兰米尔被分析,试验性的运动数据用伪first-order,pseudo-second-order,Elovich,液体电影散开和intra粒子散开模型是合适的。兰米尔模型导致了为平衡数据合适的最好,它显示沉积上的Cu离子的吸附能力是1.0403?mg?有K1>L4.2877的KL价值?L?mg1。也提供的Freundlich和Temkin模型好适合,并且nFnF和A价值是3.8565和66.9964?Lmg1,分别地,显示在Cu离子和沉积之间的更强壮的吸附紧张和吸附精力。与伪first-order和Elovich模型相比,pseudo-second-order模型为描述吸附动力学是更适当的,显示吸附的化学吸着性质。吸附运动过程能被划分成电影散开,毛孔散开和吸附反应。为吸附动力学的控制的步随着吸附过程的发展变化了。全部吸附过程拿了180?min。电影散开是控制步骤为开始的20?min。在期间20~60?min时期,逐渐地增加的毛孔散开和电影散开减少了以便两现象共存了。毛孔散开在60-180期间是控制步骤?min时期。
简介:TherecentdevelopmentofCu-basedelectrocatalystsforelectrochemicalreductionofcarbondioxide(CO2)hasattractedmuchattentionduetotheiruniqueactivityandselectivitycomparedtoothermetalcatalysts.Particularly,CuistheuniqueelectrocatalystforCO2electrochemicalreductionwithhighselectivitytogenerateavarietyofhydrocarbons.Inthisreview,wemainlysummarizetherecentadvancesontherationaldesignofCunanostructures,thecompositionregulationofCu-basedalloys,andtheexploitationofadvancedsupportsforimprovingthecatalyticactivityandselectivitytowardelectrochemicalreductionofCO2.ThespecialfocusistodemonstratehowtoenhancetheactivityandselectivityofCubasedelectrocatalystforCO2reduction.TheperspectivesandchallengesforthedevelopmentofCu-basedelectrocatalystsarealsoaddressed.WehopethisreviewcanprovidetimelyandvaluableinsightsintothedesignofadvancedelectrocatalyticmaterialsforCO2electrochemicalreduction.
简介:ThedosimetricphosphorsLi_3PO_4:M(M=Tb,Cu)wereproducedbymodifiedsolid-statemethod.ThestructuralandmorphologicalcharacterizationwascarriedoutthroughX-raydiffraction(XRD)andscanningelectronmicroscope(SEM).Additionally,thephotoluminescence(PL),thermoluminescence(TL)andopticallystimulatedluminescence(OSL)propertiesofpowderLi_3PO_4dopedwithTbandCuwerestudied.ItisadvocatedthatLi_3PO_4:CuphosphornotonlyshowshigherOSLsensitivity(25timesormore)butalsogivesfasterdecayinOSLsignalsthanthatofLi_3PO_4:Tb~(3+)phosphor.Theminimumdetectabledose(MDD)ofLi_3PO_4:M(M=Tb,Cu)phosphorsisfoundtobe21.69×10~(-3)and3.33×10~(-6)J·kg~(-1),respectively.InOSLmode,phosphorshowslineardoseresponseintherangeof0.02-20.00J·kg~(-1).InTLmode,sensitivityofLi_3PO_4:CuphosphorismorethanthatofLi_3PO_4:Tbphosphor.Thekineticsparameterssuchasactivationenergyandfrequencyfactorsweredeterminedbypeakshapemethod,andphotoionizationcrosssectionsofpreparedphosphorwerecalculated.
简介:Polyacrylonitrilebeads(PAN)cysteine(CS)wassynthesizedfrompolyacrylonitrilebeads(PAN)andcysteine(CS).ThecontentofthefunctionalgroupandthepercentageconversionofthefunctionalgroupofPAN-CSpreparedundertheoptimumconditionusingresponsesurfacemethodology(RSM)forthefirstattemptwere3.22mmol/gand35.78%.ThestructurewascharacterizedbyET-IRandelementalanalysis.TheadsorptionpropertiesoftheresinforCu(Ⅱ)wereinvestigatedbybatchandcolumnexperiments.BatchadsorptionresultssuggestedthatPAN-CShadhigheradsorptioncapabilityforCu(Ⅱ)thanothermetalionsandmaximumsaturatedadsorptioncapacitywas184.7mg/g.TheresinanditsmetalcomplexeswerestudiedbyFT-IR.Furthermore,theresincanbeelutedeasilyusing1mol/LHC1.PAN-CScanprovideapotentialapplicationforselectiveremovalofcopperfromwastesolution.
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