简介:Alkalimetalhydroxideandhydridecompositesystemscontainbothprotic(HbondedwithO)andhydridichydrogen.Theinteractionofthesetwotypesofhydridesproduceshydrogen.Theenthalpyofdehydrogenationincreasedwiththeincreaseofatomicnumberofalkalimetals,i.e.,-23kJ/molH2forLiOH-LiH,55.34kJ/molH2forNaOH-NaHand222kJ/molH2forKOH-KH.Thesethermodynamiccalculationresultswereconsistentwithourexperimentalresults.H2wasreleasedfromLiOH-LiHsystemduringballmilling.ThedehydrogenationtemperatureofNaOH-NaHsystemwasabout150℃;whereasKOHandKHdidnotinteractwitheachotherduringtheheatingprocess.Instead,KHdecomposedbyitself.Inthesethreesystems,NaOH-NaHwastheonlyreversiblehydrogenstoragesystem,theenthalpyofdehydrogenationwasabout55.65kJ/molH2,andthecorrespondingentropywasca.101.23J/(molH2K),sothetemperatureforreleasing1.0barH2wasashighas518℃,showingunfavorablethermodynamicproperties.TheactivationenergyforhydrogendesorptionofNaOH-NaHwasfoundtobe57.87kJ/mol,showinggoodkineticproperties.
简介:Ultramafichypoxenolithsfoundinthealkali-richporphyryintheLiuheVillage,Heqing,Yunnan,China,areofgreatsignificanceinunderstandingtheoriginandevolutionoftheporphyry.Thispaperdiscussesthemineralogicalfeaturesofthehypoxenoliths.Itshowsthatthexenolithsarecharacterizedbytheuppermantlerocksmodifiedtocertainextentbytheenrichedmantlefluidmetasomatisminthemantleenvironment,withtheenrichedmantlepropertyofIow-degreepartialmelting.Thisconstitutestheimportantmineralogicalevidenceforthepetrogenesisandmineralizationofalkali-richporphyry.
简介:Theabsorptionoffreealkaliatlowconcentrationbysubacidresinwastracedwithelectricconductancemethod,theeffectoftemperatureontheadsorption,theactivationenergy,ofadsorption(Ea)andinteractionenergy(U)wasstudied.Theresultshowedthat,theprocessoflowconcentrationalkaliadsorptionbysubacidresinwasinaccordancewithmechanismofmonomolecularlayerabsorption,inaddition)withtheincreasingoftemperature,theinteractionenergybetweenadsorbateandsorbentincrease,sodidthesurfaceadsorptionrate(k),andlinearcorrelationexistedbetweeninteractionenergy(U)andtemperature(T).
简介:InNorthXinjiangthereisanalkaligranitebeltextendingintheNW-SEdirectionalongthesouthernbandoftheUlungurRiverandrunningparalleltothesuturezone,i.e.,Aermantai-ZhahebaOphioliticMelangeZone,betweentheJunggarPlateandtheAltayOrogenicBelt.Whole-rockRb-SrisochronagesoftheUlunguralkaligranitesarewithintherangeof292-309Ma,showingthattheyweregeneticallyconnectedwiththelatestepisodeofHercynianmagmatismsubsequenttothesyncollisionS-typeandpost-collisionupliftingI-typegranitoidsintheAltayregion.Thealkaligranitesareminer-alogicallycharacterizedbytheoccurrenceofaegirineandarfvedsoniteandchemicallybyhighsiliconandalkali,lowcalciumandmagnesiumandabundanthigh-fieldelements,beingtypicalA-typegranites.ThealkaligraniteswereformedinthefinalstageoftheHercyniancalc-alkalinemagmaticcycleinaveryshortperiodoftime.Theyareinlinewiththepost-orogenicA-type(PA-type)granites,implyingthatthetectonicregimewaschangedfromcompressiontoextension.
简介:Thenon-edibleoilsarebelievedtobeoneofthemajorfeedstockfortheproductionofbiodieselinfuture.Inthepresentstudy,weinvestigatedtheproductionofJatrophaoilmethylesters(JOMEs)viaalkali-catalyzedtransesterificationroute.ThebiophysicalcharacteristicsofJatrophaoilwerefoundwithintheoptimalrangeinaccordancewithASTMstandardsasasubstitutedieselfuel.Thechemicalcompositionandproductionyieldofas-synthesizedbiodieselwereconfirmedbyvariousanalyticaltechniquessuchasFT-IR,1HNMR,13CNMRandgaschromatographycoupledwithmassspectrometry.Ahighpercentageconversion,~96.09%,offattyacidsintoesterswasachievedunderoptimizedtransesterificationconditionswith6:1oiltomethanolratioand0.9wt%NaOHfor50minat~60°C.Moreover,twelvefattyacidsmethylesters(FAME)werequantifiedintheGC/MSanalysisanditwasinterestingtonotethatthemassfragmentationpatternofsaturated,monounsaturatedanddiunsaturatedFAMEwascomparablewiththeliteraturereportedvalues.
简介:FrequencyupconversionofEr3+inalkalilanthanumgallateglasses(Na2O-La2O3-Ga2O3orNLG)wasinvestigated.Visibleemissionsat532,546,and660nmcorrespondingtothe2H11/2→4I15/2,4S3/2→4I15/2,and4F9/2→4I15/2transitionswereobservedundercontinuouswaveexcitationat980nm.Thequadraticpumppowerdependenceoftheseemissionsindicatedatwophotonupconversionprocess.Atapumpintensityof52W·cm-2at980nm,frequencyupconversionefficienciesof1.1×10-2and2.7×10-3wereobtainedforgreenandredemissions,respectively.
简介:Anintactalkalimarshsoil(MS)coreandanagriculturesoil(AS)corewerestudiedbythesimulatedtestinordertogetthecomparisonofthenutrientsretentioninalkaliMSandAS.ThesoilcoresextractedfromtheXianghaiWetland,westernJilinProvince,China,wereleachedwithsolutioncontainedcarbon,nitrogenandphosphorus.Thentheeffluentwaterfromtheoutletsofsoilcorewithdifferentdepthswasmeasured,includingchemicaloxygendemand(COD),totalphosphorus(TP),phosphate(PO3-4-P)andnitrogenexistedasnitrate(NO-3-N),nitrite(NO-2-N)andammonianitrogen(NH+4-N)andthetotalnitrogen(TN)intheeffluentwater.CODandTParedecreasedwiththedepth,thechangingtrendsofTN,NO-3-NandNH+4-NcontentsaresimilartoCODandTP,whereasNO-2-NinbothMSandASeffluenthavealittletransitionat40cmdepth.ItissimilarefficiencyofMStoASinsignificantlycuttingdownCOD,TP,PO3-4-P,TN,NO-3-N,NH+4-NandNO-2-Ninnutrientwater.ThefunctionofMSwouldbesameefficiencyofthenutrientsretentionastheAS.AlthoughtheSOMandpHhavesomeimpactsonnutrientsretentioninthesoil,theMSwithhighersoilorganicmatter(SOM)andpHhavethesameeffluentwaterastheASwiththelowerSOMandpHatthedepthof60cm,thebottomofthesoilcores.
简介:FivenearlyE-W-trendingalkali-richigneousrockbeltsaredistributedfromnorthtosouthinnorthernXinjiang,andtheyarecomposedmainlyofriebeckite,K-feldspargraniteandhigh-Kandmedium-Kcalc-alkalinevolcanicrocksandshoshonite.TheyweremainlyemplacedoreruptedbetweentheCarboniferousandPermian.ThecompositionsofSr,Nd,Pb,andOisotopesimplythattheirprincipalresourcematerialsarederivedfromtheuppermantleorjuvenilecrust,indicatingobviouscontinentalgrowthinthePhanerozoic.Thetraceelementassociationimpliesthattheirtectonicsettingsarewithinplateandvolcanicarcforalkali-richgranites,andpost-collisionalarc,lateoceanicarcandcontinentalarcforalkali-richvolcanicrocks.AnarchipelagomodelwassuggestedforthetectonicevolutioninnorthernXinjiang.Itcanbenamedthecentral-Asia-typeorogeny,whichisdifferentfromthesocalledcircum-Pacificocean-continent-typetectonicsortheAlpine-Himalayancontinent-continent-collisional
简介:Objective:Toobservetheexpressionoflamininandfibronectininalkali-burnedcorneasinrats.Methods:Atotalof18normalWistarratswererandomlydividedinto6groups(n=3ineachgroup).Foreachrat,oneeyewasinjuredbyalkaliburn,theotheronewastakenasthenormalcontrol.Thenallthecorneasweresurgicallyremovedandtheexpressionoflamininandfibronectinwasobservedwithimmunohistochemistryrespectivelyat7hours,1day,3days,7days,14daysand28daysafteralkaliburn.Results:Comparedwiththatofthenormalcontrols,theexpressionoflamininandfibronectinoftheburnedeyeswasdramaticallyhigherat7hours,reachedpeakat14daysanddecreasedtothenormallevelat28daysafteralkaliburn.Conclusions:Intheprocessofwoundhealingafteralkaliburn,theexpressionoflamininandfibronectinincreasesdramatically,whichsuggeststhatlamininandfibronectinmayparticipateintheprocessofcornealwoundhealing.
简介:<正>AfterstudyingsystematicallyPetrology,Mineralogy,Petrochemistry,REEgeochemistryandstrontium,sulphur,leadisotopeofthealkali-richgraniteprophyrydistribuledextensivelytheYangtzeplatfromwesternmargin’salkali-richgraniteporphyrywepointoutthatthealkali-richgraniteporphyryhavethepropertiesofnewintrusiveages,Rangeoftheisotopeageisform36Mato51Ma,theybelongtotheHimalayadate,Mainmineralcomponetsofthealkali-richgraniteporphyryconsistofk-fcldspar(35~45x),quartz(36x±)plagioclase(15x±)andbiotitc(10x±).Accessorymineralsoftherockbelongtotypeof
简介:Theadsorptionpropertytheoperatinglife,theoperatingexchangecapacityandregenerationofD412macroporousphosphonomethylaminachelatingresinforremovingCa2+,Mg2+andFe2+fromhighpHbrineofalkaliproductionbyionicmembranewereinvestigatedTheresinshowedgoodphysical-chemicalandkineticproperty,highexchangecapacity,excellentdurability.
简介:ZSM-48zeoliteswithvariousSi/AlratioswerehydrothermallysynthesizedintheH2N(CH2)6NH2(HDA)-containingmedia.TheobtainedsampleswerehighlycrystallizedwithminormixedphasesasevidencedbyX-raypowderdiffraction(XRD).ThealkalinetreatedZSM-48zeolitesmaintaineditsstructureunderdifferentconcentrationsofNaOHaqueoussolution.Microporesremainedunchangedwhilemesoporeswithwideporesizedistributionformedafterthealkalinetreatment.Thesurfaceareaincreasedfrom228to288m2/g.TheBr?nstedacidsiteshadlittlealterationwhileanobviousincreaseofLewisacidsiteswasobserved.Thehydroisomerizationofhexadecanewasperformedasthemodelreactiontotesttheeffectsofthealkalitreatment.Theconversionofhexadecanehadalmostnochange,whichwasattributedtothepreservationoftheBr?nstedacidsites.Whilehighselectivitytoiso-hexadecanewithanimprovedisotonormalratioofalkaneswasduetothemesoporeformationandimproveddiffusivity.
简介:Metal-organicframeworks(MOFs)haveattractedmuchattentionasadsorbentsfortheseparationofCO2fromfluegasornaturalgas.Here,atypicalmetal-organicframeworkHKUST-1(alsonamedCu-BTCorMOF-199)waschemicallyreducedbydopingitwithalkalimetals(Li,NaandK)andtheywerefurtherusedtoinvestigatetheirCO2adsorptioncapacities.Thestructuralinformation,surfacechemistryandthermalbehaviorofthepreparedadsorbentsampleswerecharacterizedbyX-raypowderdiffraction(XRD),thermo-gravimetricanalysis(TGA)andnitrogenadsorption-desorptionisothermanalysis.TheresultsshowedthattheCO2storagecapacityofHKUST-1dopedwithmoderatequantitiesofLi+,Na+andK+,individually,wasgreaterthanthatofunmodifiedHKUST-1.ThehighestCO2adsorptionuptakeof8.64mmol/gwasobtainedwith1K-HKUST-1,anditwasca.11%increaseinadsorptioncapacityat298Kand18barascomparedwithHKUST-1.Moreover,adsorptiontestsshowedthatHKUST-1and1K-HKUST-1displayedmuchhigheradsorptioncapacitiesofCO2thanthoseofN2.Finally,theadsorption/desorptioncycleexperimentrevealedthattheadsorptionperformanceof1K-HKUST-1wasfairlystable,withoutobviousdeteriorationintheadsorptioncapacityofCO2after10cycles.