学科分类
/ 2
26 个结果
  • 简介:市场过去对大规模WDN系统的偏爱现在转向了100G,2013年上半年40G网络的部署已经开始降温,100G获得了越来越多的认可,成为最主要的技术趋势。2013年第二季度,100G的销售额就已经超过了40G,Ovum预计2012~2018年间,100G都会稳居领先地位。

  • 标签: WDN系统 40G网络 海底光缆 光网络
  • 简介:ExplicitexpressionsofMori-Tanaka’stensorforatransverselyisotropicfiberreinforcedUDcompositearepresented.Closed-formformulaefortheeffectiveelasticpropertiesofthecompositeareobtained.Ina3Dsense,theresultingcompliancetensorofthecompositeissymmetric.Nevertheless,the2DcompliancetensorbasedonadeterioratedMori-Tanaka’stensorisnotsymmetric.Noristhecompliancetensordefineduponadeteriorated2DEshelby’stensor.Thein-planeeffectiveelasticpropertiesgivenbythosethreeapproachesaredifferent.AdetailedcomparisonbetweenthepredictedresultsobtainedfromthoseapproacheswithexperimentaldataavailableforanumberofUDcompositesismade.更多还原

  • 标签: 柔度张量 注记 复合材料 横观各向同性 弹性性质 显式表达
  • 简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.

  • 标签: 反应概率 动力学计算 上海 量子 表面 截面曲线
  • 简介:Co(II)-salenwasencapsulatedinMIL-100(Cr)metalorganicframeworkby"shipinabottle"tosynthesizeanewelectrocatalyst,Cosalen@MIL-100(Cr).ThematerialwascharacterizedbyXRD,FT-IR,UV-VisandN2-adsorption.TheCosalen@MIL-100(Cr)modifiedglassycarbonelectrodeexhibitsawell-definedreductionpeakatthepotentialof–0.21Vtowardtheoxygenreductionreaction(ORR)bycyclicvoltammetry(CV)inpH=6.84phosphatebuffer.Almost400mVpositiveshiftofpotentialatCosalen@MIL-100(Cr)modifiedelectrodeforORRcomparedwiththatatbareglassycarbon,indicatesthatCosalen@MIL-100(Cr)possessesexcellentelectrocatalyticactivity.ThetransferrednumberofelectronsforORRwasdeterminedbychronocoulometry.TheresultsuggeststhattheintroductionofCo(II)-salencomplexintoMOFincreasestheelectrocatalyticactivityviaafour-electronreductionpathway.Furthermore,thiselectrocatalystexhibitsgoodstabilityandreproducibility.

  • 标签: 电催化还原 封装 电催化活性 玻碳电极 氧气 金属有机骨架
  • 简介:ThispaperpresentsaclosedformsolutionandnumericalanalysisforEshelby’sellipticinclusioninaninfiniteplate.Thecomplexvariablemethodandtheconformalmappingtechniqueareused.Thecontinuityconditionsforthetractionanddisplacementalongtheinterfaceinthephysicalplanearereducedtothesimilarconditionsalongtheunitcircleofthemappingplane.Thepropertiesofthecomplexpotentialsdefinedinthefiniteellipticregionareanalyzed.Fromthecontinuityconditions,onecanseparateandobtaintherelevantcomplexpotentialsdefinedintheinclusionandthematrix.Fromtheobtainedcomplexpotentials,thedependenceoftherealstrainsandstressesintheinclusionfromtheassumedeigenstrainsisevaluated.Inaddition,thestressdistributionontheinterfacealongthematrixsideisevaluated.Theresultsareobtainedinthepaperforthefirsttime.

  • 标签:
  • 简介:采用密度泛函理论的B3LYP方法、从头算的MP2方法和自洽反应场极化连续模型(PCM),在6-311++G(2d,2p)基组水平上研究了N,N’-二甲基-S-异苯并呋喃在气相和溶液中发生S→N烷基重排反应的机理、溶剂效应和取代基效应.结果表明:该反应通过四元环机理和双位迁移机理生成产物,在气相和溶剂水中,双位迁移途径的能垒均比四元环途径低,反应主要通过双位迁移途径生成产物.在气相,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在MP2/6-311++G(2d,2p)水平上比没有取代时分别低4.18,7.61,4.96kJ/mol,反应的取代基效应不明显.而在溶剂水中,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在PCM-MP2/6-311++G(2d,2p)水平上比气相时分别低37.73,39.96和37.17kJ/mol,反应的溶剂化效应非常明显.理论研究结果与实验观察结果一致.

  • 标签: N N’-二甲基-S-异苯并呋喃 S→N烷基重排 溶剂化效应 反应机理 密度泛函理论
  • 简介:在吝啬地的三地点的BoseHubbard模型以内,偶极的bosonic气体与的通道动力学一周期性地,散布的s波浪的调整被调查。系统经历通道(CDT)的协调破坏转移在下邻居偶极子偶极子相互作用,所在地的相互作用和散布的调制s波浪之中源于相关效果的复杂、富有的协调通道(CT)。特别地,为产生CT(CDT)散布的调制s波浪的区域是最宽(最狭窄)什么时候所在地的相互作用和下邻居偶极子偶极子相互作用一些相关与通道精力和系统的相互作用精力有关仔细珍视,它是。为出现CDT的相关的值能理论上从通道精力和系统的相互作用精力被获得。

  • 标签: 偶极相互作用 周期性调制 玻色系统 隧道掘进 波散射 HUBBARD模型
  • 简介:Veryrecently,BelleannouncedtheirobservationofΥ(5S)!bJ!(J=0;1;2),indicatingthattheΥ(5S)!bJ!decaysalsohavelargedecaywidths,i.e.,themeasuredbranchratiosofΥ(5S)!bJ!are<3:410??3,(1:640:23+0:30??0:22)10??3,and(0:570:220:07)10??3withJ=0;1;2,respectively[1].ItshouldbenoticedthateventhoughthetreelevelcontributionstoΥ(5S)!bJ!(J=0;1;2)shouldbestronglysuppressedduetotheOkubo-Zweig-Iizuka(OZI)rule,suchlargedecaywidthsareobserved,whichagaininspiresourinterestinunderstandingsuchquantities.Inthiswork,weproposethatthecontributionfromthehadronicloopshouldbeconsideredinstudyingΥ(5S)!bJ!.

  • 标签: LOOP LOOP BE OUR IT
  • 简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.

  • 标签: 半导体光催化剂 可见光照射 Mott-Schottky图 P型 制氢 密度泛函理论
  • 简介:Thedevelopment,theunderlyingtechnologyandthecurrentstatusofthefullydiode-pumpedsolid-statelasersystemPOLARISisreviewed.Currently,thePOLARISsystemdelivers4Jenergy,144fslonglaserpulseswithanultra-hightemporalcontrastof5×1012fortheASE,whichisachievedusingaso-calleddoublechirped-pulseamplificationschemeandcross-polarizedwavegenerationpulsecleaning.Bytightlyfocusing,thepeakintensityexceeds3.5×1020Wcm-2.TheseparameterspredestinePOLARISasascientifictoolwellsuitedforsophisticatedexperiments,asexemplifiedbypresentingmeasurementsofacceleratedprotonenergies.Recently,anadditionalamplifierhasbeenaddedtothelaserchain.Intheramp-upphase,pulsesfromthisamplifierarenotyetcompressedandhavenotyetreachedtheanticipatedenergy.Nevertheless,anoutputenergyof16.6Jhasbeenachievedsofar.

  • 标签: design high power LASER LASER amplifiers