学科分类
/ 3
55 个结果
  • 简介:CyclicvoltammetryandchronoamperometrywereusedtoinvestigatetheclectrochemicalbehaviorofFe(Ⅱ)andEr(Ⅲ)inaLiClO4-DMSO(dimethylsufoxide)systematPtandCuelectrodes.ExperimentalresultsindicatethatthereductionsofFe(Ⅱ)toFe(0)andEr(Ⅲ)toEr(0)wereirreversibleatPtandCuelectrodes.ThediffusioncoefficientandtheclectrontransfercoeffieientofFe(Ⅱ)ina0.01mol/LFeCl2-0.1mol/LLiClO4-DMSOsystemat303Kwere1.70×10^-10m^2/sand0.08respectively,thediffusioncoeffieientandtheelectrontransfercoefficientofEr(Ⅲ)ina0.01mol/LErCl3-0.1mol/LLiClO4-DMSOsystemat303Kwere1.47×10^-10m^2/sand0.108respectivealy.Thehomogeneous,strongadhesiveEr-FealloyfilmscontainingErof31.39%-42.12%inmassfractionwithmetalliclustrewerepreparedbypotentiostaticelectrolysisonaCuelectrodeinaErCl3-FeCl2-LiClO4-DMSOsystemat-1.75—-2.05V(vs.SCE).

  • 标签: 铒钫合金 薄膜 二甲亚砜 循环伏安法 计时安培分析法 电化学
  • 简介:(EC+β+)Decayof153Erand157Yb¥XuShuwei;XieYuanxiang;PanQiangyan;ZhangJuping;ZhangXueqian;WangYihao;GeYuanxiu;YinXijin?..

  • 标签:
  • 简介:γ Decay of New Neutron-rich Nuclei 175ErγDecayofNewNeutron-richNuclei175Er¥ZhangXueqian;YuanShuanggui;YangWeifan;YuXian;...

  • 标签:
  • 简介:Inthisworkpulsegenerationinboththe1.5and2μmspectralrangesusingagrapheneoxide(GO)-paper-basedsaturableabsorberinEr-andTm-dopedfiberlasersispresented.ThearticledescribesthefabricationmethodofGOpaperanditscharacterization.Theperformanceofbothlasersisdiscussedindetail.Stable,mode-lockedoperationprovides613fsand1.36pssolitonpulsescenteredat1565.9and1961.6nminEr-andTm-dopedfiberlasers,respectively.Furthermore,scalingofspectralwidth,andhencethepulseduration,byincreasingthenumberofGOpaperlayersintheEr-dopedlaserisdescribed.TheversatilityandsimplicityofGOpaperfabricationcombinedwiththepossibilityofscalingtheopticalspectrumfullwidthathalf-maximumareessentialfeaturesthatmakeitagoodcandidateforultrafastlow-powermode-lockedlasersoperatingindifferentspectralregions.

  • 标签:
  • 简介:Atemperature-inducedspinreorientationtransitionbetweenГ4(Gx,Ay,Fz)andГ2(Fx,Cy,Gz)hasbeenstudiedinthefamilyofEr1–xYxFeO3(x=0,0.25,0.5,0.75,1)singlecrystals.BydopingnonmagneticY3+,wetunedthespinreorientationtemperaturetolowtemperaturewithincreasingx.Moreover,thetypicalcompensationpointandspinfliptransitionofErFeO3alsodecreaseswithdoping,anddisappearsabovex=0.75.WealsoreporttheRietveldrefinementsandRamanspectroscopyofEr1–xYxFeO3,wheresomeRamanpeaksareshiftedtolowfrequencywithincreasingdoping.Ourresultsshedlightontheunderstandingoftheinteractionbetweentwomagneticsub-latticesofrareearth(R3+)andiron(Fe3+)ions,andwillalsocontributetothematerialsdesignandpotentialapplications.

  • 标签: Er1–xYxFeO3 single CRYSTAL GROWTH MAGNETIC MEASUREMENTS
  • 简介:ZnOfilmscontainingErandGenanocrystals(nc-Ge)weresynthesizedandtheirphotoluminescence(PL)propertieswerestudied.Visibleandnear-infraredPLintensitiesarefoundtobegreatlyincreasedinnc-Ge-containingfilm.Er-related1.54μmemissionhasbeeninvestigatedunderseveralexcitationconditionsupondifferentkindsofGe,ErcodopedZnOthinfilms.1.54μmPLenhancementaccompaniedbytheappearanceofnc-Geimpliesasignificantcorrelationbetweennc-GeandPLemissionofEr3+.Theincreasedintensityof1.54μminGe:Er:ZnOfilmisconsideredtocomefromthejointeffectofthelocalpotentialdistortionaroundEr3+andthepossibleenergytransferfromnc-GetoEr3+.

  • 标签:
  • 简介:报道了波长可调谐增益开关中红外2.8μm脉冲光纤激光器。采用脉冲975nm半导体激光器泵浦高掺Er:ZBLAN双包层光纤,以闪耀光栅为谐振腔反馈元件,获得了波长可调谐增益开关中红外脉冲光纤激光输出。激光器工作频率为1~10kHz,波长调谐范围为2.703-2.819μm。在泵浦源重频10kHz条件下,激光器最大平均功率为110mw,最小脉宽为661.2ns,峰值功率为16.5W,斜率效率达28.6%。

  • 标签: 中红外 增益开关 可调谐 光纤激光器 掺铒氟化物光纤
  • 简介:Wereportonacompactpassivemode-lockedEr:fiberringlaseroperatedatthefundamentalrepetitionrateof517MHz,whichwebelieveisthehighestfundamentalrepetitionrateeverreportedinaringcavityfiberlaser.Thekeytechniqueistheemploymentoftwoinnovativehigh-powerwavelengthdomainmultiplexercollimatorswithallgainfibercavitysuitedforthehighpower(upto2W)pumping.Thelaserisfeaturedwithadirectchirpfreeoutputpulse,whichis97fswithoutextracavitycompressionatanaverageoutputpowerof90mW.

  • 标签:
  • 简介:Multilayerblackphosphorus(BP)nanoplateletsofdifferentthicknesseswerepreparedbytheliquidphaseexfoliationmethodanddepositedontoyttriumaluminumgarnetsubstratestoformsaturableabsorbers(SAs).Thesewerecharacterizedwithrespecttotheirthickness-dependentsaturableabsorptionpropertiesat3μm.TheBP-SAswereemployedinapassivelyQ-switchedEr:Lu2O3laserat2.84μm.ByusingBPexfoliatedindifferentsolvents,stablepulsesasshortas359nsweregeneratedatanaverageoutputpowerofupto755mW.Therepetitionrateintheexperimentwas107kHz,correspondingtoapulseenergyof7.1μJ.TheseresultsprovethatBP-SAshaveagreatpotentialforopticalmodulationinthemid-infraredrange.

  • 标签:
  • 简介:Inthispaper,weproposedawaytorealizeanEr-dopedrandomfiberlaser(RFL)withadisorderedfiberBragggrating(FBG)array,aswellastocontrolthelasingmodeoftheRFLbyheatingspecificlocationsofthedisorderedFBGarray.ThedisorderedFBGarrayperformsasboththegainmediumandrandomdistributedreflectors,whichtogetherwithatunablepointreflectorformtheRFL.Coherentmulti-moderandomlasingisobtainedwithathresholdofbetween7.5and10mWandapowerefficiencybetween23%and27%whenthereflectivityofthepointreflectorchangesfrom4%to50%.Tocontrolthelasingmodeofrandomemission,aspecificpointofthedisorderedFBGarrayisheatedsoastoshiftthewavelengthoftheFBG(s)atthispointawayfromtheotherFBGs.Thus,differentresonancecavitiesareformed,andthelasingmodecanbecontrolledbychangingthelocationoftheheatingpoint.

  • 标签:
  • 简介:Inthispaper,Er/Ybco-dopedfiberamplifiers(EYDFAs)withanYb-bandfiberBragggrating(FBG)atthepumpendtoimprovetheperformanceoftheamplifierissystematicallystudied.TheinfluenceofthereflectivityandcenterwavelengthoftheFBGalongwiththegain-fiberlengthontheperformanceofanEYDFAarenumericallyanalyzed.TheresultsshowthatthewavelengthoftheFBGhascriticalinfluenceontheefficiencyoftheEYDFA,whereastherequirementtoitsreflectivityisrelaxed.Itisaneffectiveandpromisingwaytoimprovetheefficiencyofahigh-powerpumpedEYDFAbyintroducingasuitableYb-bandFBGatthepumpend.Basedontheanalysisoftheunderlyingprinciples,suggestionsforthepracticaldesignandpossiblefurtherimprovementstrategiesarealsoproposed.

  • 标签:
  • 简介:Erbium,Ytterbium-codopedZrO2nanoparticles(ZrO2∶Er3+,Yb3+)werepreparedbythesol-emulsion-geltechnique.Thepurposeofthepresentstudyistheapplicationofupconversionphosphorinthebiologicallabel.Inordertomakeoutthemechanismofupconversionunder980nmexcitationthe488nmpumpwasused.Theinfluenceoftemperatureonthecrystallitephasewasstudied.TheresultsconfirmtheupconvertedmechanisminZrO2∶Er3+,Yb3+nanocrystalsisduetoanenergytransferupconversion(ETU).

  • 标签: 二氧化锆 能量上转换作用 作用机理 铒离子 镱离子 掺杂
  • 简介:Wereportgenerationofsub-100fspulsestunablefrom1700to2100nmviaRamansolitonself-frequencyshift.Thenonlinearshiftoccursinahighlynonlinearfiber,whichispumpedbyanEr-dopedfiberlaser.Thewholesystemisfullyfiberized,withouttheuseofanyfree-spaceoptics.Thankstoitsexceptionalsimplicity,thesetupcanbeconsideredasanalternativetomode-lockedTm-andHo-dopedfiberlasers.

  • 标签:
  • 简介:采用溶胶凝胶法合成了稀土离子Er^3+-Yb^3+共掺杂的纳米TiO2晶体粉末,利用XRD,UV-VIS吸收光谱及上转换发射光谱对其结构和光学特性进行了表征.以致病性嗜水气单胞菌为实验菌株,以980nm激光为激发光源,考察了室温下Er^3+-Yb^3+共掺杂纳米TiO2的光催化杀菌性能.结果表明,稀土离子掺杂的纳米TiO2可以通过上转换发光的途径增加TiO2对可见光的利用率,从而实现TiO2在可见光和近红外光范围的光催化氧化杀菌作用.

  • 标签: 纳米TIO2 稀土掺杂 上转换 杀菌作用
  • 简介:Tuningthecoloroutputofrare-earthiondopedluminescentnanomaterialshasimportantscientificsignificanceforfurtherextendingapplicationsincolordisplays,lasersources,optoelectronicdevices,andbiolabeling.Inpreviousstudies,pre-designedphasemodulationofthefemtosecondlaserfieldhasbeenproventobeeffectiveintuningtheluminescenceofdopedrare-earthions.Owingtothecomplexlight–matterinteractionintheactualexperiment,thedynamicrangeandoptimalefficiencyforcolortuningcannotbedeterminedwiththepre-designedphasemodulation.Thisarticlesharesthedevelopmentofanadaptivefemtosecondpulseshapingmethodbasedonageneticalgorithm,anditsusetomanipulatethegreenandredluminescencetuninginanEr3+-dopedglassceramicunder800-nmfemtosecondlaserfieldexcitationforthefirsttime.ExperimentalresultsshowthattheintensityratioofthegreenandredUCluminescenceofthedopedEr3+ionscanbeeitherincreasedordecreasedconvenientlybythephase-shapedfemtosecondlaserfieldwithanoptimalfeedbackcontrol.Thephysicalcontrolmechanismsforthecolortuningarealsoexplainedindetail.Thisarticledemonstratesthepotentialapplicationsoftheadaptivefemtosecondpulseshapingtechniqueincontrollingthecoloroutputofdopedrare-earthions.

  • 标签: nonlinear optics UPCONVERSION LUMINESCENCE rare earth
  • 简介:运用非线性动力学方法对癫痫患者与正常人的脑电数据进行分析。研究结果表明,癫痫患者发作期的样本熵值总体上低于正常人,并且癫痫患者在发作时的脑电样本熵值较发作前有明显降低,发作后又回到发前水平。这预示着样本熵可能为癫痫病的临床诊断提供一定的参考。同时通过实验验证,样本熵具有较好的一致性,且只需要较短的数据就能达到分析目的,是分析脑电信号的有利手段。

  • 标签: 癫痫 非线性分析 样本熵