简介:Novelsulfur-containingcompounds(3a–3c,4a–4c)wereobtainedinethanolwith1,3-diphenyl-2-propanoneasthestartingmaterial.Theadvantagesofthisprocedureweremildreactionconditions,simpleprotocol,andhighyields.ThestructuresoftheproductswerecharacterizedbyIR,1HNMR,MSandelementaryanalysis.Thecrystalofthenewcompound4abelongstomonoclinic,spacegroupC2witha=18.727(3),b=6.5179(9),c=13.7576(18),b=131.0610(10)°,V=1266.2(3)A3,Z=2,Dc=2.136g/cm3,μ=1.078mm-1,F(000)=843,R=0.0490andwR=0.1247for3211observedreflectionwithI>2δ(I).X-rayanalysisrevealsthatthemoleculeisnotsymmetrical,themolecularstructureisstabilizedbyweakp–pstackinginteractions,andnoclassicalhydrogenbondscanbeobserved.
简介:Basedonconsolidationequationsproposedforunsaturatedsoil,ananalyticalsolutionfor1Dconsolidationofanunsaturatedsingle-layersoilwithnonhomogeneousmixedboundaryconditionisdeveloped.Themixedboundaryconditioncanbeusedforspecialapplications,suchastestsoccurinlaboratory.Theanalyticalsolutionisobtainedbyassumingallmaterialparametersremainconstantduringconsolidation.Inthederivationoftheanalyticalsolution,thenonhomogeneousboundaryconditionisfirsttransformedintoahomogeneousboundarycondition.Then,theeigenfunctionandeigenvaluearederivedaccordingtotheconsolidationequationsandthenewboundarycondition.Finally,usingthemethodofundeterminedcoefficientsandtheorthogonalrelationoftheeigenfunction,theanalyticalsolutionforthenewboundaryconditionisobtained.Thepresentmethodisapplicabletovarioustypesofboundaryconditions.Severalnumericalexamplesareprovidedtoinvestigatetheconsolidationbehaviorofanunsaturatedsingle-layersoilwithmixedboundarycondition.
简介:EQrot1nonconformingfiniteelementapproximationtoaclassofnonlineardualphaselaggingheatconductionequationsisdiscussedforsemi-discreteandfully-discreteschemes.Byuseofaspecialproperty,thatis,theconsistencyerrorofthiselementisoforderO(h2)oneorderhigherthanitsinterpolationerrorO(h),thesupercloseresultsoforderO(h2)inbrokenH1-normareobtained.Atthesametime,theglobalsuperconvergenceinbrokenH1-normisdeducedbyinterpolationpostprocessingtechnique.Moreover,theextrapolationresultwithorderO(h4)isderivedbyconstructinganewinterpolationpostprocessingoperatorandextrapolationschemebasedontheknownasymptoticexpansionformulasofEQrot1element.Finally,optimalerrorestimateisgainedforaproposedfully-discreteschemebydifferentapproachesfromthepreviousliterature.
简介:Effectsofspacevelocity,reactiontemperatureandsupportacidityonproductdistributionandinductionperiodin1-buteneisomerizationandmetathesisoverMo/mordenite-aluminawereinvestigated.Asrevealedbythecatalyticperformanceresults,inductionperiodandobjectiveproductwerecloselyrelatedtothereactionconditions.Lowerspacevelocityledtolongerinductionperiodandhigherpropeneyield.Theoptimalreactiontemperatureforpropeneproductionisaround150Canditshiftedto100Cforetheneproduction.1-Buteneauto-metathesispredominatedinthereactionnetworkifthesupportwithlowerdegreeofsodiumexchanged.Andpropenegraduallybecamethedominantproductuponincreasingthesupportsodiumexchangedegree.6Mo/H100Na0M-30Alcatalystwithasupportoffullsodiumexchangedegreeexhibitedthehighestpropeneyield.
简介:对将运行于日-地L1点的太阳观测器进行了热设计,重点论述了日-地L1点的轨道外热流计算和Lymanα日冕仪(LACI)反射镜M2光阱、Lymanα日冕成像仪(LADI)滤光片组件、CCD组件、电箱、观测器主体等部分的热设计方案。通过在探测器对日面设置集热板,将观测器的主动加热功耗降低了73%;选用预埋热管的设计方案解决了对日定向观测导致的框架温差问题。仿真分析结果表明,在对日高温工作、对日低温工作、低温存储、轨道转移等4个极端工况下,观测器各组件温度均满足指标要求。该热设计方案以较低的加热功耗,解决了太阳观测器在轨工作阶段的散热、轨道转移阶段的保温等问题,满足CCD焦面工作温度<-50℃的要求。
简介:证明对一切θ∈(0,1),所有θ(2√λη-λ-η)都是单重休假的M/M/1排队模型的主算子的几何重数为1的特征值.