简介:Athreedimensionalsteady-statemagnetohydrodynamicmodelisdevelopedforthearcplasmainaDCsubmergedelectricarcfurnacefortheproductionoffusedMgO.Thearcisgeneratedinasmallsemi-enclosedspaceformedbythegraphiteelectrode,themoltenbathandunmeltedrawmaterials.Themodelisfirstusedtosolveasimilarprobleminasteelmakingfurnace,andthecalculatedresultsarefoundtobeingoodagreementwiththepublishedmeasurements.ThebehaviorofarcswithdifferentarclengthsisalsostudiedinthefurnaceforMgOproduction.Fromthedistributionofthearcpressureonthebathsurfaceitisshownthatthearcplasmaimpingementislargeenoughtocauseacrater-likedepressiononthesurfaceoftheMgObath.Thecirculationofthehightemperatureairundertheelectrodemayenhancethearcefficiency,especiallyforashorterarc.
简介:ThemagneticfusionreactorusingtheadvancedD-3Hefuelshastheadvantageofmuchless-neutronproductionssothattheconsequentdamagestothefirstwallarelessserious.Iftheestablishmentofthiskindofreactorbecomesrealistic,theexplorationof3Heonthemoonwillbelargelymotivated.Basedonrecentprogressesinthesphericaltorus(ST)research,wehavephysicallydesignedaD-3HefusionreactorusingtheextrapolatedresultsfromtheSTexperimentsandalsothepresent-daytokamakscaling.Itisfoundthatthereactorsizesignificantlydependsonthewallreflectioncoefficientofthesynchrotronradiationandoftheimpuritycontaminations.ThesecondaryreactionbetweenD-DthatpromptlyleadstotheD-Treactionproducing14MeVneutronsisalsoestimated.ComparisonofthisD-3HeSTreactorwiththeD-Treactorismade.
简介:TheHTScurrentleadsofsuperconductingmagnetsforlargescalefusiondevicesandhighenergyparticlecolliderscanreducethepowerconsumptionforcoolingby2/3comparedwithconventionalleads.Theresistivesectionsofhigh-ratedcurrentleadsareusuallymadeofaheatexchangercooledbygasflow.Thesupplyofthecoolingmassflowincursmorethan90%ofthecoolingcostfortheHTSleads.Themassflowraterequirementdependsnotonlyonthelengthandmaterialoftheresistiveheatexchanger,butalsoontheheattransfercoefficientandHEXsurface,thejointresistanceatthecoldendanditscoolingapproach.Thedesignandoperationofasheet-stackHEXwithalargerspecificsurfaceandamuchsmallerhydraulicdiameterarepresentedinthepaper.ThetestresultsofanHTSleadoptimizedfor8kAshowthata98.4%efficiencycanbeachieved.
简介:本文通过高分辨X射线衍射及掠入射(GID)的实验方法对生长在SrTiO3衬底上的LLa2/3Ca1/3MnO3和YBaCu3O7单层膜及YBa2Cu3O7-x/La2/3Ca1/3MnO3异质结构双层薄膜的微结构进行了研究。结果发现,所有薄膜都呈c向生长。由于热膨胀系数的不同而引起的热应力使得LCMO膜的晶格参数与靶材的相差较大。La2/3Ca1/3MnO3在单层腹及双层膜中都由靶材的立方结构变成了薄膜状态的四方结构。YBa2Cu3O7在单层膜及双层膜中都由靶材的正交结构变成了薄膜状态的四方结构。La2/3Ca1/3MnO3膜与YBa2Cu3O7膜在不同的样品中处于不同的应力状态。
简介:Theγ-Fe2O3nanoparticlescoatedwithDBSandCTABwerepreparedbythemicroemulsionmethod.Thecoatedsamplesshowenhancednonlinearopticalpropertiescomparedwiththeirbulkcouterpart.The.Moessbauerspectraatroomtemperatureweremeasuredforthecoatedferricoxides.Themonolayersoftheorganicmoleculearefoundtohaveastrongchemicalbondwiththesurfaceatomsandthushaveasignificantinfluenceontheelectronstructureofparticlesurface.@1999ActaMetallurgicaInc.
简介:TheNi-AlalloycontainingCr,FeadditiveswerepreparedasRaneyNiCatalystbyhighenergymilling.ThesizeandsurfacestateofNi-Alalloypowderwerestudiedbyparticlesizeanalyzerandsanningelectronmicroscopy.theStructurewasanalyzedbyXRDandMoessbauermethods.Theresultsshowedthatafterahigh-energymilling(HEM).theNi-Alalloytransformstoanano-scaleNiAlstructurewithrichAl.Byannealingthealloy,ametastableNi2Al3phasecanbeobtained.
简介:Thenanoparticlesγ-Fe2O3coatedwithsurfactants.DBS,STandCTAB.repsectively.weresynthesizedbymicroemulsionmethod.Thecoatedferricoxides.whichshowenhancednonlinearopticalpropertiescomparedwiththeirbulkcounterpart.wereprobedbyEXAFSinsolutionforms.Thex=-rayabsorptionspectraforFeKedgeweremeasuredatroomtemperaturebyhelpofsynchrotronradiationlightsource.Extendedx-rayabsorptionfinestructureanalysisshowsthatthecoatinglayersoforganicmoleculesinteractwithsurfaceatomsofnanopartices,theFe-Obondlengthwasextended.
简介:AseriesofoxideizedCO-K-Mo/γ-Al2O3catalystsamples,preparedbyimpregnatingoxidizedK-Mo/γ-Al2O3sampleswithanaqueoussolutionofcalculatedCo(NO3)2andthencalcininginairattemperaturesof350℃,500℃65℃and800℃respectively,weresulfidedandtheninvestigatedfortheactivityinthesynthesisofmixedalcoholsfromCOhydrogenationunderconditionsofp=5.0MPa,T=350℃andGHSV=4800h^-1.TheresultsdemonstratethattheadditionofcobaltpromoterisfavorabletotheformationofhigheralcoholsandtheopimumcalcinationtemperaturesafterimpregnatingwithCo^2+areabout500-650℃.ThestructureofCoandMospeciesontheoxidizedandsulfidedsampleswasdeterminedbyX-raydiffraction(XRD),laserRamanspectrum(LRS)andextendedX-rayabsorptionfinestructure(EXAFS).Foroxidizedsamplecalcinedat350℃,cobaltexistsasCo3O4spectiesandcoversthesurfaceofK-Mo-Ospecies,thestructureofK-Mo-OspeciesisthesameasthatinK-Mo/Al2O3sample.TheinteractionbetweencobaltandK-Mo-Ospeciesisrelativelyweak.Aftersulfidation.Cobaltexistsassulfidecrystalliteswithanoctahedralcoordinatedstructure,andmolybdenumasMoS2crystallites.Foroxidizedsamplescalcinedat500-650℃,CocomponentinteractswiththeK-Mo-Ospeciesanddestroysthelong-rangeorderoftheK-Mo-Ospectesgradually,Aftersulfidation.CotendstoexistasasulfidewithtetrahedralcoordinatedstructureandMostillasMoS2crystallites.Foroxidizedsamplecalcinedat800℃,CocomponentexistsmainlyasCoAl2O4species,mostofwhichcannotbesultidedduringsulfidation.