Influence of Mixing Conditions on Morphologies and Properties of MMT/Epoxy Resin Composite Materials

(整期优先)网络出版时间:2010-03-13
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Montmorillonite(MMT)wasdirectlymodifiedwithhexadecyltrimethylammoniumbromide.Theinterlayerspacingoftheorganophilicmontmorillonite(organo-MMT)correspondingtothed(001)planepeakwas2.21nm.Theinfluencesofthecontentoforgano-MMTandmixingconditionsincludingmixingtemperatureandmixingtimeontheintercalationandexfoliationstructuresofMMT/epoxyresincompositeswereinvestigatedbywideX-raydiffraction(WXRD).TheX-raypatternsrevealthatorgano-MMTwasintercalatedbytheepoxyresinduringmixingprocess.Onlyundercertainmixingconditions,couldtheexfoliationnanocompositesbeformed.Themechanicalandthermalpropertiesofthecompositesweremeasured.TheresultsindicatethatthecompositeshavebettermechanicalpropertiesandhigherTgthanthoseofthepristineepoxyresin.