PhotocatalystwaspreparedbyimmobilizingTiO_2onglassbeadsusingthetradi-tionalsol-gelmethod.Ultravioletlight(UV)producedbypulsedstreamerdischargewasthenusedtoinducephotocatalyticactivityofTiO_2photocatalyst.Decolourationefficiencyoftherep-resentativeazodye(acidorange7,AO7)wasinvestigatedusingthesynergisticsystemofpulsedstreamerdischargeplasmaandTiO_2photocatalysis.Theobtainedresultsshowedthatthede-colourationrateofAO7couldbeincreasedby16.7%undertheconditionofaddingsupportedTiO_2inthepulsedstreamerdischargesystem,comparedtothatinthesolepulsedstreamerdischargeplasmasystem,duetothesynergisticeffectofpulsedstreamerdischargeandTiO_2photocatalysisinducedbypulsedstreamerdischarge.ThesynergisticsystemofpulsedstreamerdischargeandTiO~photocatalystwasfoundtohavemorereactiveradicalsfordegradationoforganiccompoundsinwater.