MODIFICATION OF POLYETHYLENE BY in situ FORMED SODIUM ACRYLATE

(整期优先)网络出版时间:2006-06-16
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ToimprovethewatertreeresistanceofPE,linearlow-densitypolyethylene(LLDPE)wascompoundedwithsodiumacrylate(NaAA)forinsitupolymerization,inwhichNaAAwasformedthroughtheneutralizationofacrylicacid(AA)withsodiumhydroxide(NaOH)beforeaddingdicumylperoxide(DCP)toinitiatetheinsitugraftpolymerizationandhomopolymerization.AseriesofLLDPE/NaAAcompoundswereinvestigatedfortheirwaterabsorptionratio(WAR)measurement,watertreeing,mechanicalanddielectricproperties.TheresultsstronglysuggestthatNaAAcanimprovethewatertreeresistanceofLLDPE.Inaddition,theLLDPE/NaAAcompoundspossesssatisfactorymechanicalpropertiesanddielectricproperties.CharacterizationofLLDPE/NaAAcompoundsbyusingFouriertransforminfraredspectrometry(FTIR)suggeststhattheneutralizationandpolymerizationreactioncouldbeachievedeffectively.UsingadequateDCPcontentisthekeyfactorforcontrollingthepolymerizationofNaAAwithpreciseconversionratio.