Homogeneous Plastic Flow of Fully Amorphous and Partially Crystallized Zr41.2Ti13.8Cu12.5Nil0Be22.5 Bulk Metallic Glass

(整期优先)网络出版时间:2003-06-16
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ThehomogeneousplasticflowoffullyamorphousandpartiallycrystallizedZr41.2Ti13.8Cu12.5Ni10Be22.5bulkmetallicglass(Vitl)hasbeeninvestigatedbycompressiontestsathightemperaturesinsupercooledliquidregion.Experimentalresultsshowthatatsufficientlylowstrainrates,thesupercooledliquidofthefullyamorphousalloyrevealsNewtonianflowwithalinearrelationshipbetweentheflowstressandstrainrate.Asthestrainrateisincreased,atransitionfromlinearNewtoniantononlinearflowisdetected,whichcanbeexplainedbythetransitionstatetheory.Overtheentirestrainrateintervalinvestigated,however,onlynonlinearflowispresentinthepartiallycrystallizedalloy,andtheflowstressforeachstrainrateismuchhigher.Itisfoundthatthestrainrate-stressrelationshipforthepartiallycrystallizedalloyatthegiventemperatureof646Kalsoobeysthesinhlawderivedfromthetransitionstatetheory,similartothatoftheinitialhomogeneousamorphousalloy.Thus,itisproposedthattheflowbehaviorofthenanocrystalline/amorphouscompositeat646Kismainlycontrolledbytheviscousflowoftheremainingsupercooledliquid.