Gneiss-Water Interaction and Water Evolution During the Early Stages of Dissolution Experiments at Room Temperature

(整期优先)网络出版时间:2003-04-14
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Gneiss-distilledwaterinteractionatroomtemperaturewasinvestigatedwithbatch-reactorstostudywater-rockreactionandgeochemicalevolutionoftheaqueousphasewithtime.Theionconcentrationsinwaterwerecontrollednotonlybythedissolutionofprimaryminerals,butalsobytheprecipitationofsecondaryminerals.Thedecreasingfractionsizesofgneisscouldfavordissolutionandprecipitationsimultaneously.Ca2+andK+werethemajorcations,andHCO3-wasthemajoranioninwater.AlltheionsexceptCa2+increasedinconcentrationwithtime.TheCa2+releasefromtherocktotheaqueousphasewasinitiallymuchfasterthanthereleaseofK+,Na+andMg2+.Butafterabout5-24hours,theCa2+concentrationsinwaterdecreasedveryslowlywithtimeandbecamerelativelystable.Duringtheexperiment,thewatervariedfromtheCa-(K)-HCO3-typewatertotheK-Ca-HCO3-typewater,andthentotheK(Ca,Na)-HCO3-typewater.Thewater-gneissinteractionwasdominatedbythedissolutionofKfeldsparinthesolution.Theremainingsecondarymineralsweremainlykaolinite,illiteandK(Mg)-mica.