A novel insight into enhanced propane combustion performance onPtUSY catalyst

(整期优先)网络出版时间:2017-01-11
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Platinumwassupportedonγ-A1203andultra-stableYzeolite(USY)byanincipientwetnessimpregna-tionmethod.Thecatalystswerecharacterizedbynitrogenphysisorption,transmissionelectronmicroscopy(TEM),CO/C3H8isothermaloxidations,NH3temperature-pro-grammeddesorption(NH3-TPD)andinfrared(IR)spec-troscopyofadsorbedprobemolecules(CO,C3H8andC3H8+02).ComparedwithPt/Al2O3,PtUSYcatalystshowsobviouslyhigheractivityforthecombustionofpropane.AfterestimatingthesizeeffectofPtparticlesandpropaneadsorptioncapacityofUSY,theexcellentactivityofPtUSYisalsoattributedtothestronginteractionsbetweenthepreciousmetalandtheacidiczeolite.Itinhi-bitstheoxidationofPtinanoxygen-richatmosphereathightemperatures,whichfacilitatetheinitialoxidationstepinvolvingtheC-HbondactivationonmetallicPtasreflectedbyinsitudiffusereflectanceinfraredFourier-transformed(DRIFT)spectra.