简介:基于金刚石钻头干钻时出现较高摩擦热的现象,采用MoS2作为胎体润滑剂,用电镀法制备MoS2-Ni复合胎体材料,以减小胎体的摩擦因数、降低摩擦热;并研究电镀工艺对MoS2复合镀层的显微硬度和低温低压下复合镀层对胎体摩擦性能的影响。结果表明:随镀液中MoS2浓度增大,镀层的显微硬度和胎体的摩擦因数降低,当MoS2浓度大于0.5g/L时,镀层的显微硬度和胎体的摩擦因数变化不大;随镀液pH增大,镀层显微硬度降低,胎体的摩擦因数先减小后增大,当镀液pH增大到4.0后,镀层的显微硬度变化不大,胎体摩擦因数达最小值;随镀液电流密度增大,镀层显微硬度和胎体摩擦因数先减小后增大,当电流密度增大到2.5A/cm2时,镀层的显微硬度和胎体摩擦因数达到最小值。摩擦磨损后的胎体材料形貌分析表明,控制好电镀工艺条件,可实现低温低压下MoS2-Ni复合材料对胎体的润滑作用。
简介:采用粉末注射成形工艺制备含钕的钛合金TixNd(x为Nd的质量分数,%),采用金相显微镜、扫描电镜、电子探针以及硬度和力学性能测试等分析手段,研究钕对注射成形钛合金中氧的分布及力学性能的影响,并分析钕的最佳添加量。结果表明:随钕含量增加,合金的密度和伸长率先增加后降低,其中Ti15Nd的性能最优异,其相对密度为98.2%,强度和伸长率分别达到634MPa和6.5%,比纯钛分别提高248MPa和6.5%。纯钛的断裂面呈现解理断裂特征,而Ti15Nd为延性断裂。添加钕能提高钛合金的致密度,并且钕能吸收周围钛基体中的氧原子形成氧化钕,调节TixNd合金中氧的分布,从而有效提高合金的强度和韧性。计算证明氧化钛的分解和氧化钕的形成在热力学上是可行的。建立Ti-Nd扩散模型,考虑钕的蒸发和氧化等因素,计算得出钕的最佳添加量(质量分数)约为4.3%。
简介:在硅酸盐体系(Na2SiO3+KOH)电解液中,采用微弧氧化技术在5052铝合金表面原位生成微弧氧化膜层。并利用SEM、EDS和XRD等仪器设备,分析微弧氧化膜层形貌、元素分布和相组成,着重分析氧化时间对膜层厚度、表面孔隙率和最大孔洞直径及膜层耐腐蚀性的影响。结果表明:微弧氧化膜层表面有典型的“火山堆积”形貌生成,且膜层厚度、表面孔隙率和最大孔洞直径随氧化时间的增加而增大;膜层主要元素为O和Al,相组成为γ-Al2O3和α-Al2O3,且主要为γ-Al2O3;微弧氧化处理可显著提高试样的耐腐蚀性能,腐蚀电流密度至少下降2个数量级,电化学阻抗模值|Z|至少增加2个数量级,随氧化时间从10min延长到50min试样的耐腐蚀性能先提升后降低,氧化时间为20min的试样耐腐蚀性能最好。
简介:ZnOnanotubeswerehydrothermallysynthesizedandtheZNTs/CeO2fluorescentcompositewerepreparedbyintroducingnanoCeO2particlesintoZnOnano-tubesviaachemicalsolutionadsorptionandannealingprocess.ThesampleswerecharacterizedbyX-raydiffraction,scanningelectronmicroscopy,Fouriertransformationinfraredspectroscopyandroomtemperaturephotoluminescencemeasurement.DuetotheinteractionbetweenCe4+andthesurfaceatomsofZnO2nano-tubes,aphotoluminescenceenhancementwasobser...
简介:Withcoalgasasareducingagent,thecatalyticreductionofSO2tosulfurinthefluegasproducedinmetallurgicalprocesseswasstudiedovercatalystsofrareearth-Fe/Al2O3(REFe/Al2O3).ThecatalyticactivityoftheREFe/Al2O3catalystonthereductionofSO2tosul-furwasinvestigatedbasedonkindsandthecontentsofrareearthsanddifferentpreparationmethodofthecatalyst.Additionally,themecha-nismofthiscatalyticreductionreactionwasalsoexplored.ResultsshowedthatdifferentrareearthimposeddifferenteffectontheactivityoftheFe/Al2O3catalyst.Especially,theadditionofSmandDygreatlyimprovedthecatalyticactivityofFe/Al2O3.TheyieldofsulfuroverSmFe/Al2O3wasincreasedto86.62%at360℃,whichwas40.5%higherthanthatoverFe/Al2O3atthesametemperature;andthesulfuryieldoverDyFe/Al2O3wasincreasedto91.62%at400℃,26.4%higherthanthatoverFe/Al2O3.ThecatalyticactivityofREFe/Al2O3wassomehowdependentonthecontentofrareearth.ForSmFe/Al2O3,thecontentofSmwasoptimizedtobeabout1.0wt.%.Therareearthcatalystpreparedwithdifferentmethodsalsoshowedvariedactivity.Thesulfuryieldoverrare-earthtransitionmetalcatalystsfollowstheorder:SmandironsolutionmixingimpregnationSmfirst,thenironsolutionimpregnationironfirst,thenSmsolutionimpregnation.ThereactionmechanismofSO2reductiontosulfurwithcoalgaswasproposedtobeanintermediatemechanism.
简介:TheNd3+3.2%(atomfraction):KGd(WO4)2crystalwasgrownbyKyropoulosmethod.TheabsorptionspectrumandfluorescencespectrumofNd3+:KGWcrystalweremeasured.Theabsorptioncrosssectionsat808nm(0.6799×10-20cm2)werecalculated,andtheoutputwavelengthoffluorescenceis1064and1351nm.Thediode-pumpedlaserwasoperatedbothinthefree-runningandpassivelyQ-switchedoperatingmodes.Themaximumlaseroutput(1064nm)is326mWwith62.7%slopeefficiencywheninputenergyis900mW.ThebeamqualityfactorM2≈1.1.Thegreenlightof532nmisobtainedinfrequencydoublingoperation.ThelaserispassivelyQ-switchedbyusingCr4+:LuAGassaturableabsorber.Thepulsewidthis170nsatrepetitivefrequencyof15kHZ.