简介:ThispapercarriesouttheFirstprinciplescalculationofthecrystalstructures(zincblende(B3)androcksalt(B1))andphasetransitionofboronarsenic(BAs)basedonthedensity-functionaltheory.Usingtherelationbetweenenthalpyandpressure,itfindsthatthetransitionphasefromtheB3structuraltotheB1structuraloccursatthepressureof113.42GPa.ThentheelasticconstantsC11,C12,C44,bulkmodulus,shearmodulus,Youngmodulus,anisotropyfactor,KleinmanparameterandPoissonratioarediscussedindetailfortwopolymorphsofBAs.TheresultsofthestructuralparametersandelasticpropertiesinB3structureareingoodagreementwiththeavailabletheoreticalandexperimentalvalues.
简介:Therearefourunitsofhigh-pressuretoultrahigh-pressuremetamorphismextendingfromsouthtonorthacrosstheTongbai-DabieMountains:theepidote-blueschist-faciesunit,thelow-temperatureeclogitefaciesunit,theultrahigh-pressureeclngitefaciesunitandthemedium-temperatureeclogitefaciesunit.ThelatertwounitswereformedduringtheCaledoniansubductionbetweentheTongbai-DabiemicroplateandtheNorthChinaplate,theformertwounitsaretheproductsofIndosiniancontinental-continentalsubductionandcollisionbetweentheYangtzeandtheNorthChinaplates.
简介:Inthiswork,themorphologiesandporestructuresofaseriesofcorncob-derivedactivatedcarbonsandzeolitetemplatedcarbonwithultrahighsurfaceareawerecarefullyinvestigatedbySEM,HRTEMandN2-sorptioncharacterizationtechnologies.Thehigh-pressurehydrogenuptakeperformancewasanalyzedusingstandardPressure-Composition-Temperatureapparatusinordertostudytheporesizeeffectsonhydrogenuptake.Theseas-obtainedporouscarbonsshoweddifferentcharacteristicsofporesizedistributionaswellasspecificsurfacearea.Theresultsindicatethatthemosteffectiveporesforadsorbinghydrogendependedonthestoragepressure.Theseultramicropores(0.65-0.85nm)couldbethemosteffectiveporesonexcessH2uptakeat1bar,however,micropores(0.85-2nm)wouldplayamoreimportantroleinexcessH2uptakeathigherpressureat77K.Atroomtemperature,poresizeeffectsonH2uptakecapacitywereveryweak.BothspecificsurfaceareaandtotalporevolumeplaymoreimportantrolesthanporesizeforH2uptakeatroomtemperature,whichwasclearlydifferentfromthatat77K.Forapplicationsinfuture,thecorncob-derivedactivatedcarbonscanbemoreavailablethanzeolitetemplatedcarbonsat77K.ElementdopingenhancedhydrogenuptakecouldbemainresearchdirectionforimprovingH2uptakecapacityatroomtemperature.更多还原
简介:InwallshotblastingisamethodofimprovingthesurfacehardnessandhightemperatureoxidationresistanceoftheS30432high-pressureboilertube.Thedifferencesonresidualstress,sub-grainsize,micro-hardnessandstructurebetweentheS30432inwallshot-blastingtubeproducedbyBaosteelwithsixtechnologicalprocessparametersandtheimportedsuper304Hwerestudiedsystematicallybycontrasttestresearch.IthasbeendemonstratedthattheS30432obtainsahigherresidualstress,adeeperdistributed...
简介:Byusingsuchflier-platematerial,quasi-isentropiccompressioncanberealized.Basedonit,hypervelocitylaunchingisfurtheraccomplished.Asaresult,anextremelyhighdynamicpressurecanbeobtainedinlaboratory,offeringapracticalmethodforthecomprehensivedeterminationofmaterialsbehavior,response,equation-of-stateandpropertiesindynamicloadingprocess.
简介:Decreasingtherisksandgeohazardsassociatedwithdrillingengineeringinhigh-temperaturehigh-pressure(HTHP)geologicsettingsbeginswiththeimplementationofpre-drillingpredictiontechniques(PPTs).ToimprovetheaccuracyofgeopressurepredictioninHTHPhydrocarbonreservoirsoffshoreHainanIsland,wemadeacomprehensivesummaryofcurrentPPTstoidentifyexistingproblemsandchallengesbyanalyzingtheglobaldistributionofHTHPhydrocarbonreservoirs,theresearchstatusofPPTs,andthegeologicsettinganditsHTHPformationmechanism.OurresearchresultsindicatethattheHTHPformationmechanisminthestudyareaiscausedbymultiplefactors,includingrapidloading,diapirintrusions,hydrocarbongeneration,andthethermalexpansionofporefluids.Duetothismulti-factorinteraction,acloudofHTHPhydrocarbonreservoirshasdevelopedintheYing-QiongBasin,butonlytraditionalPPTshavebeenimplemented,basedontheassumptionofconditionsthatdonotconformtotheactualgeologicenvironment,e.g.,Bellotti’slawandEaton’slaw.Inthispaper,wefocusontheseissues,identifysomechallengesandsolutions,andcallforfurtherPPTresearchtoaddressthedrawbacksofpreviousworksandmeetthechallengesassociatedwiththedeepwatertechnologygap.Inthisway,wehopetocontributetotheimprovedaccuracyofgeopressurepredictionpriortodrillingandprovidesupportforfutureHTHPdrillingoffshoreHainanIsland.
简介:TheYushugouterrainofhigh-pressuregranulitefaciesinsouthernTianshanMountainiscomposedmainlyofanophiolitesuite.Mostselectedziroconsareroundorellipticalinshape,andsomeareoftetragonalprismwithroundedges.Thegranulometricanalysesshowthattheyarewellsortedinsedimentation.ZrO2/HfO2ratiosinzirconsrangefrom45to57.thesecharacters,togetherwiththepetrologicandgeochemicalcharactersofplagioclase-garnet-orthopyroxenitebearingzircons,indicatethattheprotolithofplagioclase-garnet-orthopyroxenitemaybederivedmainlyfromvolcanicbasesurgesedimentarydebrisinoceanicislandsandfromclaysformedbyseafloorweathering.Zirconsaresimplyofpyroclasticdebris.Theophioliteformationageof(440±18)Maandthefirst-stagemetamorphicage(amphiboliteorgranulitefacies)of(364±5)Mawereobtainedwithamethodofmultiplegrainsindifferentgroupsandamethodofconcordiaplot.TheseagesprovideimportantinformationonthetemporalandspatialoccurrenceofsouthernPaleoxoicTianshanOcean,Thesubductionrateoftheoceaniccrustandtheformationmechanismofophioliteofgranulitefacies.
简介:Thehighpressureequationofstateforcarbonisconstructedbysomesimplephysicalmodels.Forsolidstate,amultiphaseequationofstateisconsidered,whichincludesfoursolidstates.Forliquidstate,theliquidperturbationtheoryofCRISmodelisused.Inthehightemperature,theelectroniccontributionisobtainedbytheionizationequilibriumtheory.Theresultofourcalculationbasedontheabovemodelsiscomparedwiththefirstprincipledensityfunctionalcalculationandtheothermodels.TheHugoniotandthephasediagramofcarbonarealsocomparedwiththeexperiments.Theresultsaresatisfactory.
简介:Thereisawidespreadinterestinleadtelluride(PbTe)asagoodthermoelectricmaterial.WereportthetemperaturedependenceofthermopowerS(T)andresistanceR(T)forPbTeatthedifferentpressuresoffrom1.8GPato5GPaobtainedbyusingthecubicanvilhighpressureapparatus.Withincreasingpressure,R(T)andS(T)decrease.TheeffectofpressureonR(T)islargerthanthatonS(T).Thepowerfactorthatisdeterminedbythermopowerandresistivityincreaseswithincreasingpressure.Thismethodisanefficienttoolforsynthesizinggoodthermoelectricmaterialsathighpressureandhightemperature.
简介:Theprincipleofnewopticalfibrepressuretransducerisanalysed,andinge-niousdesignschemeofthistransducerisvigen.Thisnewtransducerspecimenisprovidedwithfollowingcharacteristics;experimentaltransmittingdistanceis20m(actuallyupto1000m);systemsensitivityis0.1mV/Pa;powerconsumptionoftheprobeislessthan125μW.Finally,somepointsoftheappraisementaregiveninthispaper.
简介:<正>DearSir,Oculartraumaisatopicofunresolvedcontroversiesandtherearecontinuouscontroversialanddebatablediagnosticandmanagementstrategiesforopen-globeinjuries[1].Amongstmanytypesofoculartrauma,theopenglobeinjuryisthemostseriousduetoitsverypoorvisualprognosisandyoungpopulationofpatientsaremostlyaffected[2].Thetreatmentoutcomemaybeimprovedbypromptdiagnosis,andimmediatesurgicalrepairperformedtohighstandard[3].Amongsttheotherclinicalsignstheintraocularpressure(IOP)isfoundtobeparticularlyreducedandconventionallythisisconsideredasaveryreliableindicatorofoccultglobe
简介:Thestructuralpropertiesofjadeiteathighpressures(0.0001-30GPa)areinvestigatedusingplane-wavepseudopotentialdensityfunctionaltheorymethod.Asafunctionofpressure,themonocliniccellparameterswerecalculatedandthecompressibilitycoefficientsare0.0026,0.0023and0.0026GPa-1,respectively.Thebondlength,bondangleanddistortionvariationwerestudiedinordertoobtaintheinformationofpolyhedralcompression.Thepressure-volumeequationofstatewasconsideredinordertoobtainthebulkmodulusK0.ComparisonbetweenthecalculatedK0valuesandtheexperimentaldatasuggestedthatthemodelprovidesreasonableinsightsintocrystallographicandphysicalpropertiesofjadeite.