简介:结晶化修正(vinylidene氟化物)(PVDF)poly为PVDF并且poly的混合电影(甲基methacrylate)(PMMA)被调查。集体crystallinity(c)并且进一步,阶段内容(PVDF的F()),与不同集体比率为asprepared混合电影被学习。另外,c和F的变化()一旦PMMA部件从相关混合系统被移开,系统地被探查。DSC,FTIR和XRD大小都显示了那1)c,F()并且甚至阶段的内容(F())与PMMA的增加减少了;2)与PMMA的抽取,c和F()当时,增加了F()减少。它是值得注意的c和F的增加()取决于提取PMMA(EPMMA)的相对数量,即,越多PMMA被移开,越多c和F()增加。这些结果从PMMA成分揭示阻碍者效果到PVDF的结晶化,并且因而,当PMMA被提取时,这限制将被释放。
简介:Themainrequirementsforbatteryseparatorsarehighporositywhichcanservepathwaysoflithiumionandspaceforgelelectrolytestoimpregnateinamembraneandmechanicalstrengthtoalloweasyhandlingforbatteryassembly.Generally,itappearsthetrade-offrelationshipbetweentheporosityandmechanicalstrengthofthemembrane.PVdFcompositemembranescontainingnano-sizeclayswereusedtoimprovethemechanicalstrengthofthemembranewithoutaffectingthemembraneporosity.Thecompositemembraneswerepreparedbyphaseinversionmethodcontrollingthemembranepreparationconditionssuchasretentiontime.Theresultantmembranesshowincreasedmechanicalpropertieswithsimilarmembraneporosityaround80%comparedtothepristinePVdFmembrane.Incorporationofnonoclaycanbeconsideredasaneffectivemethodtoimprovethemechanicalstrengthinporousmembranesupports,especiallyinaseparator.
简介:薄膜物理与制备技术研究对于惯性约束聚变(ICF)实验具有重要意义,2003年开展的研究工作主要包括几个方面的内容:低压等离子体化学气相沉积(LPPCVD)法微球CH涂层及掺杂(溴等)技术研究;脉冲激光沉积(PLD)法Fe/Al合金薄膜研制;磁控溅射法Au/Gd,Ti/A1,Ti/Cr支撑薄膜研制;碳氢氮(CxNyH1-x-y)薄膜制备技术研究。相应主要结果如下:(1)利用低压等离子体化学气相沉积(LPPCVD)装置深入考察了以反式-2-丁烯如下: