简介:FieldlysimetermethodwasemployedtoinvestigatethedownwardmovementandleachingofNappliedtosummercorn(ZeamayL.)ondrylandsoilinBeijing,AN-fertilizer(120kgNhm^-2)andacontroltreatmentwerarrangedforthestudy.Soilsolutionwascollectedatdepthsof20,40,60,120and170cm,whileleachtewasollectedatthebottom(220cm)ofthelysimeter,TheresultsshowedthatthedownwardmovementofNO3^-Ninsoilprofilewasgreatlyaffectedbyrainfallpattern.ThepeakofleachedNO3^-Nfrombothtreatmentscoincidedwiththepeakoftherainfall.Inaddition,leachedNO3^-Nfrombothtreatmentsandrainfallweresignificantlycorrelated(P<0.05).TheamountofleachedNO3^-NwasnotgreatintheN-fertilizertreatment,TheresultsalsosuggestedthatNfertilizationcouldcauseNO3^--Ncontaminationofgroundeaterduringtherainyseason.
简介:对福建近海养殖水体的NO3^--N、NH4^+-NN及氧化还原电位、化学需氧量COD、叶绿素a、浊度等进行测定,分析NO3^--N、NH4^+-NN与环境因子的相关关系,并计算不同环境因子和水体中NH4^+-NN相对含量的灰色关联度值.结果表明:氧化还原电位及COD值均与NH4^+-NN的浓度呈负相关,与NO-3的浓度呈正相关;叶绿素a浓度及浊度均和NH4^+-NN的浓度呈正相关,与NO3^--N的浓度呈负相关.各环境因子与NH4^+-NN的相对含量的灰色关联度值无明显差异.COD和氧化还原电位在丰水期的灰色关联度值比枯水期高,叶绿素a和浊度在丰水期的灰色关联度值则比枯水期低.
简介:采用水热法合成了一个新的分子式为[Pb(phen)2(NO3)]·NO3的金属-有机配合物(phen=1,10-邻啡啰啉),并对其进行了元素分析、红外光谱表征和X射线单晶衍射的结构解析.该配合物(C24H16N6O6Pb)属于单斜晶系,空间群为P21/n,晶体学数据:a=16.7035(12),b=7.7341(5),c=18.1198(13),β=98.1860(10),V=2317.0(3)3,Mr=691.62,Dc=1.983g/cm3,μ(MoKα)=7.337mm-1,F(000)=1328,Z=4.直接法解析原子位置的结果显示:R=0.0269,wR=0.0533.该配合物具有零维网状结构.
简介:Anewμ3-Otriiron(Ⅲ)complex[Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2(HOBZ=benzoicacid)hasbeensynthesized,itsstructurehasbeendeterminedandvariabletemperaturemagneticsusceptilityhasalsobeenmeasured.Inthemolecule,threeironatomsformedanequilateraltrianglewithu3-Oincenter.ThefittingtothemagneticsusceptibilityshowedthatanintramolecularantiferromagneticexchangeinteractionoccurredbetweenironatomswithJ=-25.51cm-1,andaweakerintermolecularantiferromagneticexchangeinteractionoccurredwithzJ’=-2.30cm-1.
简介:TherelationshipofelectricalpropertiesofMn-dopedBa0.92Ca0.08TiO3PTCR(positivetemperaturecoefficientresistance)ceramicswithtwosinteringscheduleswasdiscussed.UsingTEM(transmissionelectronmicroscope)combinedwithEDS(energydispersiveX-rayspectrometer),theMnionsdistributedatgrainboundarieswereanalyzed.TheresultsshowthatthePTCReffectofMn-dopedPTCRceramicsismoredependentonthesinteringschedulethanthoseofMnfree.ThephenomenonmaybecausedbythevalencestatesvarianceofMnionssegregatedatthegrainboundaries.
简介:Kineticsofchloride/sulfate,chloride/nitrateandnitrate/sulfateforwardexchangesandreverseexchangesatsolutionconcentrationsof1N,0.2Nand0.02Non201×7strongbaseanionexchangeresin,respectively,havebeenexaminedat25℃.Itisfoundthattheforwardandthereverseexchangeratesofthetwogivenionsatlowsolutionconcentration,respectively,underidenticalconditionscanbecontrolledbydifferentmechanisms,whilethoseathighsolutionconcentrationareallcontrolledbyparticlediffusion.Theternaryexchangeratesofsulfate/(chloride+nitrate)andnitrate/(chloride+sulfate)havealsobeenexamined.
简介:Thesinglecrystalofthecomplex[Sc(NO3)3(H2O)2]·(15C5)hasbeenpreparedinacetonitrile.Thenewcomplexhasbeencharacterizedbyelementalanalysis,IRspectra,solubilityandmolarconductancemeasurements.ThestructureofthecomplexisdeterminedbysinglecrystalX-raydiffractionanalysis.
简介:设D是无平方因子正整数.本文证明了:当D不能被形如6k+1之形素数整除时,方程,-1=Dyn仅当D=17时有正整数解(x,y,n)=(18,7,3)适合n>2.