学科分类
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11 个结果
  • 简介:Nuclearfusionhasenormouspotentialtogreatlyaffectglobalenergyproduction.Thenext-generationtokamakITER,whichisaimedatdemonstratingthefeasibilityofenergyproductionfromfusiononacommercialscale,isunderconstruction.Wallerosion,materialtransport,andfuelretentionareknownfactorsthatshortenthelifetimeofITERduringtokamakoperationandgiverisetosafetyissues.Thesefactors,whichmustbeunderstoodandsolvedearlyintheprocessoffusionreactordesignanddevelopment,areamongthemostimportantconcernsforthecommunityofplasma-wallinteractionresearchers.Todate,lasertechniquesareamongthemostpromisingmethodsthatcansolvetheseopenITERissues,andlaser-inducedbreakdownspectroscopy(LIBS)isanidealcandidateforonlinemonitoringofthewallsofcurrentandnext-generation(suchasITER)fusiondevices.LIBSisawidelyusedtechniqueforvariousapplications.Ithasbeenconsideredrecentlyasapromisingtoolforanalyzingplasma-facingcomponentsinfusiondevicesinsitu.ThisarticlereviewstheexperimentsthathavebeenperformedbymanyresearchgroupstoassessthefeasibilityofLIBSforthispurpose.

  • 标签: LIBS NUCLEAR fusion plasma-facing COMPONENTS
  • 简介:Laser-inducedbreakdownspectroscopy(LIBS)isapromisinganalyticalspectroscopytechnologybasedonspectroscopicanalysisoftheradiationemittedbylaser-producedplasma.However,forquantitativeanalysisbyLIBS,theso-calledself-absorptioneffectsonthespectrallines,whichaffectplasmacharacteristics,emissionlineshapes,calibrationcurves,etc,cannolongerbeneglected.Hence,understandinganddeterminingtheself-absorptioneffectsareofutmostimportancetoLIBSresearch.Thepurposeofthisreviewistoprovideaglobaloverviewofself-absorptioninLIBSontheissuesofexperimentalobservationsandadverseeffects,physicalmechanisms,correctionoreliminationapproaches,andutilizationsinthepastcentury.Webelievethatbetterunderstandingandeffectivesolvingtheself-absorptioneffectwillfurtherenhancethedevelopmentandmaturityofLIBS.

  • 标签: LASER-INDUCED BREAKDOWN spectroscopy(LIBS) SELF-ABSORPTION effect optically
  • 简介:在这份报纸,结果在导致激光的故障光谱学(解放)的第一应用上被介绍为在alpha石蜡的Mg集中的量的决心的技术。这种技术在与传统的方法的那些可比较的Mg集中给精确性,这被表明,作为ICP-OES,在短时间并且没有对样品准备的需要。为500ppb的顺序的Mg的察觉的限制被表明。而且,关于合适的刻度曲线和察觉(LOD)的限制的定义的实现的简短讨论被报导。CLC数字TP274

  • 标签: α-石蜡 镁含量 精确测量 激光诱导击穿光谱
  • 简介:Laser-inducedbreakdownspectroscopy(LIBS)hasbeenextensivelyappliedduetothecapabilitiesofreal-time,multi-phaseandmulti-elementanalysis.Withtheadvantages,portableLIBSisinrapiddevelopmentwithgreatpotentialoffieldmeasurements.Inthiswork,aportableLIBSwasdevelopedbya50μJlevellaserforexcitationandanobjectivelensforfocusingorimaging.Elementdetectionwassuccessfullyachievedbythissetup,andalsothemicroscopicobservationcouldbeobtainedwiththemagnificationof350×.ApreliminaryinvestigationwascarriedoutformineralrecognitionbythedevelopedportableLIBS.Theobtainedresultsindicatethattheelementdetectioncombinedwithmicroobservationwasaneffectivewayforrecognizingminerals,especiallyforsimilarmineralidentificationordiscrimination.Itissuggestedthatthemicro-joulelasercouldbealternativeforthecommercialportableLIBS,andtheon-sitemineralorrockrecognitionisapromisingfieldfortheapplication.

  • 标签: LIBS MINERAL RECOGNITION multi-element analysis
  • 简介:摘 要:本研究基于激光诱导击穿光谱(LIBS)法,探讨了铁矿石中硅(SiO2)、铝(Al2O3)、钙(CaO)和镁(MgO)含量的测定方法。采集了来自澳大利亚、南非、哈萨克斯坦和智利四个国家的244个铁矿石样品,代表了12个不同种类。通过LIBS测量,获取了这些样品的光谱数据,涵盖了180~970nm波长范围内的12814个数据点。在实验中,使用商用的LIBS仪器进行测量,通过调Q的Nd:YAG激光器,波长为1064nm,激光能量设置为30mJ,延迟时间为1μs,频率为5Hz。

  • 标签: LIBS 测定铁矿石 元素含量
  • 简介:Theaccuracyoflaser-inducedbreakdownspectroscopy(LIBS)quantitativemethodisgreatlydependentontheamountofcertifiedstandardsamplesusedfortraining.However,inpracticalapplications,onlylimitedstandardsampleswithlabeledcertifiedconcentrationsareavailable.Anovelsemi-supervisedLIBSquantitativeanalysismethodisproposed,basedonco-trainingregressionmodelwithselectionofeffectiveunlabeledsamples.Themainideaoftheproposedmethodistoobtainbetterregressionperformancebyaddingeffectiveunlabeledsamplesinsemi-supervisedlearning.First,effectiveunlabeledsamplesareselectedaccordingtothetestingsamplesbyEuclideanmetric.Twooriginalregressionmodelsbasedonleastsquaressupportvectormachinewithdifferentparametersaretrainedbythelabeledsamplesseparately,andthentheeffectiveunlabeledsamplespredictedbythetwomodelsareusedtoenlargethetrainingdatasetbasedonlabelingconfidenceestimation.Thefinalpredictionsoftheproposedmethodonthetestingsampleswillbedeterminedbyweightedcombinationsofthepredictionsoftwoupdatedregressionmodels.Chromiumconcentrationanalysisexperimentsof23certifiedstandardhigh-alloysteelsampleswerecarriedout,inwhich5sampleswithlabeledconcentrationsand11unlabeledsampleswereusedtotraintheregressionmodelsandtheremaining7sampleswereusedfortesting.Withthenumbersofeffectiveunlabeledsamplesincreasing,therootmeansquareerroroftheproposedmethodwentdownfrom1.80%to0.84%andtherelativepredictionerrorwasreducedfrom9.15%to4.04%.

  • 标签: LIBS EFFECTIVE unlabeled samples CO-TRAINING SEMI-SUPERVISED