学科分类
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417 个结果
  • 简介:在电的运输性质上评估Ni替换的影响,p类型skutteruditesRyFe3NiSb12(R=Ba,Nd和Yb)系统地从2.5K被调查到800K。由小心地修改三fillers,Ba,Nd和Yb的充满的部分,搬运人集中精确被调整,它按比例改变到数统治的原子价计算的名字的价值。活动性和Seebeck系数的搬运人集中依赖表示在原子价乐队的二乐队贡献,和为热电的性能的优化搬运人集中在之间(5–9)×1020厘米−3。样品的热电导率用稀土元素的元素(Nd和Yb)填满的格子作为与相比显著地更低充满Ba,由于更低的反响的频率并且部分充满。与公司替换相比,Ni替换趋于关上乐队差距,它为RyFe3NiSb12。然而由于状态的密度的改进,当搬运人集中是类似的时,RyFe3NiSb12比RyFe2公司2在更低的温度范围的Sb12。0.73的ZT价值为Yb0.77Fe3在600K的NiSb12。

  • 标签: 传输性能 热电 YB 载流子浓度 BA
  • 简介:Throughmeasuringthecoefficientoflinearexpansion,thestructureandpropertiesoftheLi2O-Al2O3-SiO2lowexpansionglassceramicscontainingB2O3arestudiedbyJRandXRD.ItisshoutnthattheIRmethodisefficientinthestudyoftheglass-ceramicsstructure.Thereisa"Boronabnormality"inthesystemwhichhasanimportantinfluenceonthepropertiesoftheglass-ceramics.

  • 标签: boron ABNORMALITY LI2O-AL2O3-SIO2 system glass ceramics
  • 简介:以煤气为还原剂、Fe为活性金属催化还原冶炼烟气SO2制取硫磺。研究了不同载体、不同金属含量、稀土Sm及其含量对SO2还原成S单质催化活性的影响。结果表明,载体Al2O3粉末越细,SO2还原反应出的硫温度越低;催化剂金属Fe的最佳含量(质量分数)为14%,当反应温度为400℃时,硫的产率为81.92%;稀土Sm的加入提高了催化剂的反应活性,当反应温度为360℃时,Sm-Fe/Al2O3的硫产率与Fe/Al2O3相比提高了40.5%。Sm-Fe/Al2O3催化剂的活性与Sm含量存在一定的关系,本试验条件下,稀土Sm的最佳含量(质量分数)为1.0%。

  • 标签: SO2 催化还原 硫磺 烟气 稀土Sm
  • 简介:TheelectronicstructuresofCuS2,CuSe2andCuTe2withpyritestructures,withintheframeworkthedensity-functionaltheoryhavebeeninvestigated.ThecalculatedresultsexplainedtherecentexperimentalresultswhichshowthatthereisnoclearindicationofstrongelectroncorrelationsintheelectronicpropertiesofCupyrites,duetothedominantchalcogenpcharacterratherthandcharacteristicofCuattheFermilevel.

  • 标签: 从头算 黄铜矿 电子结构 CuS2 CuSe2 CuTe2
  • 简介:TheantibacterialeffectofcarryingsilverB2O3-SiO2-Na2Oglassmaterialwasstudiedbymeansofantibacterialring,nephelometery,MICvalue,thinfilmattachmentandmicrocalorimetry,respectively.TheexperimentalresultsoffivekindsofantibacterialtestmethodsarealmostidenticalandcanverifythatcarryingsilverB2O3-SiO2-Na2Oglassmaterialexertsanexcellentantibacterialperformance.Antibacterialringandnephelometeryaresimple,quick,buttheprecisionisrestrictive.MICvalue,thinfilmattachmentmethodandmicrocalorimetrycanquantitativelycomparetheantibacterialeffectsoftheantibacterialglassmaterial.Comparedwiththetraditionalmicrobetestmethods,themicrocalorimetrycananalyzetheinhibitingeffectofthecell'sgrowthandmetabolismontheantibacterialglassmaterialbymonitoringthethermaleffectcontinuouslyandautomatically.

  • 标签: 抗菌玻璃 镀银 B2O3-SiO2-Na2O MIC价值 比浊计
  • 简介:Newvisibletransparent,UVabsorption,andhighinfraredreflectionpropertieshavebeenrealizedbydepositingmultilayerSiO2/ZnO:Al/CeO2-TiO2/SiO2filmsontoglasssubstratesatlowtemperaturebyradiofrequencymagnetronsputtering.OptimumthicknessofSiO2,ZnO:Al(ZAO)andCeO2-TiO2(CTO)filmsweredesignedwiththeaidofthinfilmdesignsoftware.Thedegreeofantireflectioncanbecontrolledbyadjustingthethicknessandrefractiveindex.TheouterSiO2filmcandiminishtheinterferencecoloringandincreasethetransparency;theinnerSiO2filmimprovestheadhesionofthecoatingontheglasssubstrateandpreventsCa2+,Na+intheglasssubstratefromenteringtheZAOfilm.Theaveragetransmittanceinthevisiblelightrangeincreasesbynearly18%-20%,ascomparedtodoublelayerZAO/CTOfilms.Andthefilmsdisplayhighinfraredreflectionrateofabove75%inthewavelengthrangeof10-25μmandgoodUVabsorption(〉98%)properties.Thesesystemsareeasytoproduceonalargescaleatlowcostandexhibithighmechanicalandchemicaldurability.ThetriplefunctionalfilmswithhighUVabsorption,antireflectiveandhighinfraredreflectionratewilladapttoapplicationinflatpaneldisplayandarchitecturalcoatingglass,automotiveglass,withdiminishinglightpollutionaswellasdecreasingeyefatigueandincreasingcomfort.

  • 标签: SI O2/Zn O:Al /Ce O2-Ti O2/Si
  • 简介:Inpursuingexcellentsupercapacitorelectrodes,wedesignedaseriesofM0S2/C0S2compositesconsistingofflower-likedMoS2andoctahedron-shapedCoS2throughafacileone-stephydrothermalmethodandinvestigatedtheelectrochemicalperformanceofthesampleswithvarioushydrothermaltime.Duetothecouplingoftwometalspeciesandabigamountofwell-developedCoS2andMoS2,theresultsindicatedthattheMoS2/CoS2compositeselectrodesexhibitedthebestelectrochemicalperfor-mancewithalargespecificcapacitanceof490F/gat2mV/sor400F/gat10A/gamongallsamplesasthehydrothermaltimereached48h(MCS48).Furthermore,theretentionofMCS48is93.1%after10000cyclesat10A/g,whichmanifeststheexcellentcyclingstability.TheoutstandingelectrochemicalperformanceofMCS48indicatesthatitcouldbeaverypromisingandnovelenergystoragematerialforsupercapacitorsinthefuture.

  • 标签: MoS2/CoS2 COMPOSITES HYDROTHERMAL time ELECTROCHEMICAL properties
  • 简介:三新奇Ba_5RNiNb_9O_(30)(R=La,Nd和Sm)陶艺在BaO-R_2O_3-NiO-Nb_2O_5系统被准备并且描绘。所有三混合物areparaelectjicphasesadopting。在房间温度的充满的四角形的钨铜(TB)结构。在1MHz,Ba_5RNiNb_9O_(30)陶艺有高电介质在范围193-245.3,在范围0.0059-0.0087的低绝缘的损失,和在范围的绝缘的常数(tau_e)的温度系数的常数-1140-1310X10~(-6)中心点degC。他们绝缘的常数的温度系数显著地Ba_5RNiNb_9O_(30)与那些相比被减少(R=La,Nd,Sm)陶艺。

  • 标签: Ba5RNiNb9O30陶瓷 钨青铜 X射线衍射 结构 介电性能
  • 简介:以便得到TiB2-Al2O3的同质的混合物和协议,一个表面修正方法被用来准备nano规模的杂交Al2O3涂的TiB2粒子。PE蜡粒子是第一到由杂交,然后nano规模Al2O3粒子的TiB2粒子上涂又是涂的到由PE蜡粒子涂的TiB2的表面上。SEM,TEM和版本被用来描绘同样收到的核心/壳粒子和它的协议的微观结构。试验性的结果显示出那粒子规模TiB2和Al2O3的同质的分散能不仅在混合粉末而且在使脱蜡的协议被形成。协议当时是由煤气压的sintering(GPS)的sintered。物件顶端的装饰物产品显示出与参考样品由正常方法制作了作比较的改进技工性质。

  • 标签: 复合材料 AL2O3颗粒 TIB2 氧化铝涂层 制作 表面改性方法
  • 简介:铁磁性微晶玻璃由于具有磁性和生物活性,可以用作磁感应热疗的热种子材料。采用SiO2-Na2O-CaO-P2O5-Fe2O3五元系统,通过共沉淀-熔融法和熔融法两种不同的方法制备铁磁性微晶玻璃,利用XRD确定其晶相并计算晶体的晶格常数和晶粒尺寸,并通过VSM表征样品的磁性能。结果表明,玻璃液在自然冷却的过程中就形成了大量的磁铁矿,不经过热处理过程即可制得具有磁铁矿唯一晶相的铁磁性微晶玻璃并具有生物活性。共沉淀-熔融法制备的样品磁性更强。

  • 标签: 共沉淀-熔融法 熔融法 铁磁性微晶玻璃 磁性能
  • 简介:SiO2-B2O3-Al2O3-CaO在低sintering温度使契约成玻璃,高力量被讨论。FTIR和XRD分析被用来与铝的不同内容描绘基本使成玻璃的契约的结构。弯曲力量和热扩大系数也被测试。同时,在660光线衍射(XRD)的sintering温度的合成标本的微观结构,扫描电子显微镜(SEM)分析和其它工具。结果证明分别地,钾和磷的溶解率在95.64wt%lessthan的一种谷物尺寸的条件下面是70wt%和93.7wt%0.074公里,9.78gg-1硫磺的酸,0.5gg-1铵氟化物,160桴???瑳畲瑣牵獥椠?慭湩慴湩摥映吗??

  • 标签: 陶瓷结合剂 显微组织 性能 热膨胀系数 烧结温度 XRD分析
  • 简介:TiB2ceramicspowderwassynthesizedfromB2O3-TiO2-Mgsystem.TheeffectsofTiB2additionasdiluentonthecombustionsynthesisprocesswereinvestigated.TheresultsofthermodynamiccalculationandexperimentsshowthattheincreaseofTiB2contentrangingfrom0to20wt%canreducetheadiabatictemperatureTadfrom3100Kto2896KandcombustiontemperatureTcfrom2139Kto1621Krespectively.TheparticlesizeandhalfwidthoftheparticledistributionarealsoincreasedwiththeadditionofTiB2increasingfrom0to20wt%.ThecombustionproductisamixtureofTiB2,MgO,andotherintermediatephases.TheleachedproductcontainsmainlyTiB2,TiO2andTiN,anditsoxygencontentis7.77wt%.

  • 标签: 氧化合成 TIB2 陶瓷粉末 大气压
  • 简介:TiO_2isapromisingphotocatalyst.However,thelowphotocatalyticefficiencycallsforthemodificationofTiO_2.Metal-andnonmetal-dopingofTiO_2havebeenprovedtobeeffectivewaystoenhancephotocatalyticproperties.Thisreviewprovidesadeepinsightintotheunderstandingofthemetal-andnonmetal-dopedTiO_2photocatalysts.ThisarticlebeginswiththeintroductionofthecrystalstructuresofTiO_2andapplicationsofTiO_2materials.Wethenreviewedthedoped-TiO_2systemintwocategories:(1)metal-dopedTiO_2photocatalystssystem,and(2)nonmetal-dopedTiO_2photocatalystssystem.Bothexperimentalresultsandtheoreticalanalysesareelaboratedinthissection.Inthefollowingpart,fortheadvantagesofTiO_2thinfilmsoverparticles,variouspreparationmethodstoobtainTiO_2thinfilmsarebrieflydiscussed.Finally,thisreviewendswithaconciseconclusionandoutlookofnewtrendsinthedevelopmentofTiO_2-basedphotocatalysts.

  • 标签: TIO2薄膜 光催化作用 金属添加剂 合成方法
  • 简介:用organo听Sn(OC4H9)4作为先锋,钠dodecylsulfonate(SDS)和SDS明胶(SDS-G)象模板复杂,二听二氧化物胶体的粒子被准备由一自己组装方法。两个SnO2产品分别地与SDS-G与SDS和SnO2-C粒子被标记SnO2-B粒子,它在制作相应于SnO2-B和SnO2-C传感器的SnO2煤气的传感器被使用。X光检查衍射(XRD),扫描电子显微镜学(SEM),传播电子显微镜学(TEM)和thermogravimetry和不同热分析(TG/DTA)被用于描述。试验性的结果证明SnO2-B胶体的粒子由mesoporous组成像片的粒子,当SnO2-C粒子主要由球形的粒子组成时。煤气的察觉到大小证明那个SnO2-B传感器执行察觉到反应到所有目标气体的最好,包括H2,C2H5OH和液体石油气体(LPG)。特别地,SnO2-B传感器的察觉到的反应在1000潩獮的集中在H2空气在32点被完成

  • 标签: 气敏性能 液化石油气 胶体粒子 气敏传感器 SnO2 颗粒组成