简介:Adsorptionanddesorptionofexogenousrareearthelements(REE)insoilswerestudied.ResultsshowedthatsoilshadstrongadsorbabilityforREEandtherateofadsorptionofREEwasover95%oftheaddedREEinthesetests.ThecharacteristicsofadsorptionisothermscorrespondedwellwiththebothFreundlichandTemkinequations,butdeviatedfromtheLangmuirequation.TheadsorptionofREEtendedtoincreasewiththerisingofsoilpH.AsequentialextractionmethodusedforstudingthedesorptionanddistributionofREEsorbedinsoilsarealsodiscussed.
简介:Thedistributionofrareearthelement(REE)formsinsoilsisgiveninthepresentpaperonthebasisofsequentialfractionationanddeterminationof34representativesurfacesoilscollectedfromallpartsofChina.ResultsobtainedshowthattheextractionrateofwatersolubleandexchangeableREEhadtheodd-evenphenomenonandthatoforganicallyboundREEfromLatoLutendedtoreducegraduallywiththeincreaseofatomicnumber.ThestabilityofScandtheactivityandenrichmentofTminsoilsareproposed.Furthermore,thepapermakesapreliminarydiscussiononthedifferencesintheconcentrationdistributionofvariousformsofindividualREEinsomesoils.
简介:Afieldtestwiththetraditionalrotationofpaddyrice/uplandcrop(wheat)wascarriedoutonapaddysoilderivedfromredearthtoelucidatetheeffectoforganicmanureonthephoshporusadsorption-desorptionbysoilanditsPavailability.Soilsamplesweretakenfromdifferenttreatmentsatricehavestingstageandanalysed.TheisothermaladsorptionofPbythesamplesfittedverywellwithLangmuirequation,andhence,theparametersintheequation,i.e.,maximumadsorption(qm),constantrelatedtobondingenergy(k)andtheirproduct(k×qm)couldbeusedasacomprehensiveindextocharacterizethepotentialPadsorptivityofthesoil.Organo-inorganicfertilizationandorganicmanuringcoulddecreaseqmandk,whilemineralPapplicationhadlittleeffectonthem.TheisothermaldesorptionofPwassignificantlycorrelatedwithinitiallyaddedandisothermallyadsorbedP.PartofPaddedwasfixed,whichrepresentedthePfixationcapactyofsoil,andorganicmanuringcouldobviouslylowerthePfixation,ThecontentofsoilavailablePhadasignificantnegativecorrelationwithqm,kandfixedP.ItisconcluedthatorganicmanurecouldincreasethePavailabilityofpaddysoilderviedfromredearthbydecreasingqm.k,maximumbufferingcapacity(MBC=k×qm)andfixationcapacity.