简介:Metalion-imprintedlycrosslinkedchitosanresin1andresin2werepreparedbytheuseofCu^2+andNi^2+astemplateionsandglutaraldehydeascrosslinkingagent,respectively,ThroughinvestigationontheadsorptioncapactiesandbindingconstantsforCu^2+,Ni^2+andCo^2+ionsonchitosanresins,resin1andresin2exhibittheadsorptionselectivityforthemixturesolutionof1L1Cu^2+andNi^2+ions.Theadsorptionselectivityofmetalion-imprintedresinsfortheirtemplateionsinmuchhigherthanthatofuncrosslinkedchitosanresin.
简介:用微波高温固相法合成了Er^3+单掺Lu2O3,Li^+与Er^3+共掺Lu2O3及Li^+,Zn^2+,Mg^2+掺杂Lu2O3∶Er^3+的荧光粉。实验表明金属离子Li^+、Zn^2+、Mg^2+、Er^3+掺杂Lu2O3,不影响Lu2O3的立方晶相。扫描电子显微镜测量表明,Li^+掺杂可以有效改善粉体的分散性和形貌,Li^+,Zn^2+,Mg^2+共掺杂获得的粉体颗粒分布更加均匀,粒径范围为80~100nm。379nm激发下,Li^+与Er^3+共掺样品发光较单掺Er^3+样品在565nm处的发光增强了4.5倍,而Li^+、Zn^2+、Mg^2+与Er^3+共掺样品较其发光增强5.3倍。980nm激发下,Li^+与Er^3+共掺样品,Li^+、Zn^2+、Mg^2+与Er^3+共掺样品的发光分别比单掺Er^3+样品在565nm处发光增强23倍与39倍,在662nm处发光强度分别增强20倍与43倍。379nm激发下,较单掺Er3+的样品,掺杂Li^+的样品和Li^+,Zn^2+,Mg^2+和Er^3+共掺的样品荧光寿命均有所增加,而Zn^2+、Er^3+共掺及Mg^2+、Er^3+共掺样品的荧光寿命则有所缩短。
简介:Emissionquenchingof[Ru(bpy)2(4,4’-dcbpy)](PF6)2(1)bybenzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl(2)or1,5-diphenyl-3-(2-phenothiazine)-2-pyrazoline(3)wasobserved.Measurementsoftheemissiondecayof1beforeandafteradditionof2or3bysinglephotoncountingtechniquecon-finnedtheobservations.Theemissionquenchingof1by2or3wassubmittedtoStern-Volmerequation.Itwascalculatedthatthequenchingrateconstants(kq)are5.5×109(mol/L)-1s-1for2and4.0×109(mol/L)-1s-1for3,respectively.Theseresultsindicatedacharacterofdynamicquenchingprocess.Thesinglet-stateof2or3wasalsoquenchedby1.ThequenchingbehaviorsdidnotconformtotheStern-Volmerequationandinvolvedbothstaticanddynamicquenchingprocesses.Theapparentquenchingrateconstant(kapp)wascalculatedtobe3×109(mol/L)-1fortheinteractionofexcited2with1,and1.2×109(mol/L)-1forthatofexcited3wit
简介:TheroleoftemperatureontheoxidationdynamicsofCu2OonZnO(0001)wasinvestigatedduringtheoxidationofCu(111)/ZnO(0001)byusingoxygenplasmaastheoxidant.AtransitionfromsinglecrystallineCu2O(111)orientationtomicro-zonephaseseparationwithmultipleorientationswasrevealedwhentheoxidationtemperatureincreasedabove300°C.TheexperimentalresultsclearlyshowtheeffectoftheoxidationtemperaturewiththeassistanceofoxygenplasmaonchangingthemorphologyofCu(111)filmandenhancingthelateralnucleationandmigrationabilitiesofcuprousoxides.Averticaltop-downoxidationmodeandalateralmigrationmodelwereproposedtoexplainthedifferentnucleationandgrowthdynamicsofthetemperature-dependentoxidationprocessintheoxidationofCu(111)/ZnO(0001).
简介:theAlternatingSegmentCrank-Nicolsonschemeforone-dimensionaldiffusionequationhasbeendevelopedin[1],andtheAlternatingBlockCrank-Nicolsonmethodfortwo-dimensionalproblemin[2].Themethodshavetheadvantagesofparallelcomputing,stabilityandgoodaccuracy.Inthispaperforthetwo-dimensionaldiffusionequation,thenetregionisdividedintobands,aspecialkindofblock.ThismethodiscalledthealternatingBandCrank-Nicolsonmethod.
简介:描述表面在nanocrystals熄灭孤立的离子中心的一个模型基于在做的离子和熄灭中心的nanocrystalline表面之间的精力转移被建议。熄灭的率在nanocrystal取决于离子的位置,在非选择的刺激下面的因此腐烂曲线通常是非指数的。与这个模型一起计算的腐烂曲线在对T-4(1)的好同意>(6)在ZnS的A(1)排放:Mn2+nanocrystals。
简介:Twonewdicyanamidecoordinationpolymers,{Mn(dmpz)[N(CN)2]2}2(1)and{Cu(dmpz)[N(CN)2]2}2(2)(dmpz=3,5-dimethylpyrazole),weresynthesizedandcharacterizedbysinglecrystalX-raydiffractionanalysisandIRspectroscopy.In1and2themetalionshavetwodifferentcoordinationmodes,whereoneiscoordinatedtofourdicyanamideanionsandtwomonodentatedmpzmoleculestoformaslightlydistortedoctahedralgeometry,whiletheotheradoptsoctahedralgeometry,surroundedbyfournitrileNatomsandtwoamideNatomsofthedicyanamideanions.Bothcomplexescontaintwoalternatingchainsthatareparalleltoeachother.
简介:Three-dimensional(3D)flowerlikehierarchicalZn2GeO4andMn2+-dopedZn2GeO4microstructureshavebeenpreparedbyafacilehydrothermalapproach.X-Raydiffraction(XRD),fieldemissionscanningelectronmicro-scopy(FESEM),transmissionelectronmicroscopy(TEM)andphotoluminescence(PL)spectrometrywereemployedtocharacterizethesamples.SuchflowerlikehierarchicalZn2GeO4microstructureswithanaveragediameterof3―4μmwerefoundtobeconstructedbyabundantsinglecrystallinenanorodsofabout90nmindiameter.TheluminescentpropertiesofZn2GeO4:xMnphosphorswithdifferentcontentsofMn2+asanactivatorwereinvestigated.TheMn2+-dopedsamplesshowedgreenluminescencecorrespondingtothed-dtransitionofMn2+undertheirradiationofUVlight.Theredshift(from531nmto538nm)inλemwithincreasingMn2+contentwasobservedintheluminescentspectra,whichshouldbeattributedtoaweakcrystalfieldbecauseofthesubstitutionofZn2+byMn2+atadistortedtetrahedrallatticesite.
简介:研究了YBaCu3O6~7超导催化剂上CO2的加氢制醇反应。考察了温度、压力和空速等条件对催化剂反应性能的影响。反应的主要产物是甲醇、CO和少量甲醚。利用XPS、XRD和AFM等技术对催化剂的结构、铜的存在状态和反应活性位进行表征发现,在反应过程中,YBa2Cu3O6~7由orthombic相转变为tetragonal相。反应活性位可能是Cu(I)物种。反应后催化剂颗粒的分散程度明显提高
简介:TheternaryCu(Ⅱ)complexwith2,2′-bipyridyl(bipy)andL-methioninte(L-Met)hasbeensynthesizedandcharacterizedbyelementalanalysis,molarconductivity,UV-Visspectra,IRspectraandpH-potentiometrictitrationmethods.Thestructureofthecomplex[Cu(L-Met)(bipy)(H2O)]ClO4·3/8H2OwascharacterizedbytheX-raydiffractionanalysis.Itcrystallizesinthetriclinicsystem,spacegroupP1withfourmoleculesinaunitcellofdimensions,a=0.7656(2)nm,b=1.3142(3)nm,c=2.0596(4)nm,α=97.70(3)°,β=97.96(3)°,γ=94.33(3)°,V=2.0244(8)nm^3,R1=0.0441andwR2=0.0678,Thecrystalcontainsfourcrystallographicallyindependent[Cu(L-Met)(bipy)(H2O)]^+complexes(Cu1-Cu4),havingadistortedsquare-pyramidalgeometrywiththesamecoordinatedatomsaroundeachcoppercenter.Thebaseplaneisoccupiedbytwonitrogenatomsofonebipy,theaminonitrogenatomandonecarboxylateoxygenatomfromeachindependentL-Metmoiety,andonewateroxygenatanaxialposition.CulandCu3areessentiallyenantiomersofCu2andCu4.Thefourmoleculesarepackedwitheachotherbyintermolecularhydrogen-bondingandaromatic-ringstackinginteractions.
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简介:AnewlayeredCu-basedoxychalcogenideBa3Fe2O5Cu2S2hasbeensynthesizedanditsmagneticandelectronicpropertieswererevealed.Ba3Fe2O5Cu2S2isbuiltupbyalternativelystacking[Cu2S2]2-layersandironperovskiteoxide[(FeO2)(BaO)(FeO2)]2-layersalongthecaxisthatareseparatedbybariumionswithFe3+fivefoldcoordinatedbyasquare-pyramidalarrangementofoxygen.Fromthebondvalencearguments,weinferredthatinlayeredCuCh-based(Ch=S,Se,Te)compoundsthe+3cationinperovskiteoxidesheetprefersasquarepyramidalsite,whilethelowervalencecationprefersthesquareplanarsites.Thestudiesonsusceptibility,transport,andopticalreflectivityindicatethatBa3Fe2O5Cu2S2isanantiferromagneticsemiconductorwithaNe′eltemperatureof121Kandanopticalbandgapof1.03eV.Themeasurementofheatcapacityfrom10Ktoroomtemperatureshowsnoanomalyat121K.TheDebyetemperatureisdeterminedtobe113K.TheoreticalcalculationsindicatethattheconductionbandminimumispredominantlycontributedbyO2pand3dstatesofFeionsthatantiferromagneticallyarrangedinFeO2layers.TheFe3dstatesarelocatedatlowerenergyandresultinanarrowbandgapincomparisonwiththatoftheisostructuralSr3Sc2O5Cu2S2.
简介:AnefficientprocessfortheconversionofdimethyloxalateintoethyleneglycolwithhighselectivityandhighyieldoverCu2Owasinvestigated.InsituformedCuasatruecatalyticallyactivespeciesshowedagoodcatalyticperformanceforDMOconversiontoproduceEGin95%yield.