简介:Rareearthandtraceelementsaredeterminedforcassiteritefromavein—typeorebody,alensandasheeted-typeorebodyintheDachangSn-polymetallicorefield,GuangxiProvince.Cassiteritefromthevein-typeorebodyhasrareearthandtraceelementcharacteristicssimilartothatofDachangbiotitegraniteofLateYanshanage,showinganinheritableandageneticrelationship.Cassiteritesfromthelensandsheeted-veinorebodyhaverareearthandtraceelementcharacteristicsgreatlydifferentfromthoseofthevein-typecassiteriteandthegranite,showingdistinctlyhighercontentsoftheore-formingelementsAs,Sb.Zn.Agetc.andapositiveEuanomalyandanegativeCeanomaly.Thedifferenceofrareearthandtraceelementcharacteristicsforcassiteritefromtwokindsoforebodiesreflectsthecompositionaldifferenceofore-formingsolutions.Authorssuggestthatthelensandsheeted—veinorebodywasofnonmagmatic,mixedwithundergroundhotbrineorigin,andthatthiskindofhotbrinereactedwithDevonian
简介:Cytarabine(1-β-D-arabinofuranosylcytosine,Ara-C),isolatedfromaCaribbeanspongespeciesTethyacrypta,isthefirstantitumordrugfromamarineresource.In1980,theUSFoodandDrugAdministrationapprovedthisdrugforthetreatmentofdifferenttypesofleukemia.Thisdrughasashortplasmahalf-life,lowstability,limitedbioavailability,andseveresideeffects.Toimprovestabilityandbioavailability,wesynthesizedninenovelderivativesbyblockingthecytarabinemetabolicsitesandimprovinglipophilicity.ThecLogPvaluesofthenewlysynthesizedcompoundswerecalculated.Allthesynthesizedcompoundsweremorelipophilicthancytarabine,resultinginmembranepermeabilityandbioavailabilityimprovement.TheantitumoractivitiesagainstleukemiacelllineHL-60wereevaluatedbyusingtheMTTassay.ThebioassayresultsrevealedthattheIC50valuesofcompounds5,8and9were0.080,0.090and0.057μmolL-1,respectively,whichwassimilarwiththatofcytarabine(0.056μmolL-1).Incomparison,compound4withaphosphategroupatO5’wasinactive.Becausephosphoesterbondsareeasilyhydrolyzedbyalkalinephosphataseandarecommonlyusedinproducingprodrugstrategies,compound4mightalsobemetabolizedinvivoandgeneratecompound3orevencytarabinethroughamulti-stepreaction.Thus,compound4mightbeapromisingcompoundtobedevelopedasaprodrug.
简介:Euphausiapacificisanimportantsourceofnaturalastaxanthin.StudieswerecarriedouttoassesstheextractabilityofastaxanthinfromE.pacificusingsubcritical1,1,1,2-tetrafluoroethane(R134a).Toexaminetheeffectsofmultipleprocessvariablesontheextractionyield,astaxanthinwasextractedundervariousconditionsofpressure(30-150bar),temperature(303-343K),time(10-50min),flowrate(2-10gmin-1),moisturecontent(5.5%-63.61%),andparticlesize(0.25-0.109mm).Theresultsshowedthattheextractionyieldincreasedwithtemperature,pressure,timeandflowrate,butdecreasedwithmoisturecontentandparticlesize.Amaximumyieldof87.74%wasobtainedunderconditionsof100bar,333K,and30minwithaflowrateof6gmin-1andamoisturecontentof5.5%.Thesubstantialastaxanthinyieldobtainedunderlow-pressureconditionsdemonstratesthatsubcriticalR134aisagoodalternativetoCO2forextractionofastaxanthinfromE.pacific.
简介:以闽江河口感潮段塔礁洲野慈姑(SagittariatrifoliaL.)淡水湿地为研究对象,2015年12月—2016年10月每月小潮日定期向试验样地施加0、60和120kgS·hm-2·a-1的K2SO4溶液,探讨闽江河口感潮段淡水湿地CO_2排放通量特征对SO_4~(2-)沉降的响应,并同步观测主要环境因子。结果表明,1)对照(CK)和2个SO_4~(2-)沉降处理CO_2排放通量具有相似的月变化动态,夏秋季节排放通量较高,冬春较低。2)除夏季60kgS·hm-2·a-1的SO_4~(2-)输入显著降低CO_2排放通量外(P〈0.05),2种SO_4~(2-)处理均未显著影响河口感潮段淡水湿地CO_2排放通量(P〉0.05)。3)相关分析显示,不同处理下的CO_2排放通量与土壤温度显著正相关(P〈0.01)。
简介:Sn-polymetallicoresatDachang,GuangxiAutonomousRegion,China,arehostedinMiddle-UpperDevonianreeflimestones,siliceousrocks,bandedandlenticularlimestones,etc.Twotypesoforebodiescanbedistinguishedaccordingtotheirtelationstothebedding:oneisdistributedalongthebeddingandthe.othercutsacrossthebedding.SnandsulfideorebodiesassociatedwithK-feldsparearemostlycharacterizedbylaminatedorestructure.MicroscopicexaminationsofK-feldspar-bearingrocks,inconjunctionwithX-raydiffraction,chemicalcomposiionandcathodoluminescencedataforK-feldspars,aswellastheirtelationstomineralization,theauthorsconsiderthattheK-feldspareareofauthigenicorigin,subordinatetotheepigeneticstageofdiagenesis,Theyresultedfromthereactionofmixed,deep-seated,circulatingundergroundhotwatersrichinK,AlandSiwithargillaceouscarbonatesduringtheIndonesianorogenicmovement.ItissuggestedmoreattentionshouldbepaidtotheeffectofauthigenicK-feldsparsonSnmineralization.Inthemeantimetheeventrelatedtocirculatingundergroundhotwatersshouldalsobetakenintoaccountsoastoprovidenewcluestoblindoreprospecting.
简介:Fromthepetrologicalstudyofore-hostingfockswhichcontainlargeanorthitscrystalsandtheoccurrenceandchemicalcompositionofanorthitesandrelatedminerals,theauthorsconsiderthatthelargeanorthitecrystalsareofauthigenicorigin.Thedistributioncharacteristicsofanorthites,i.e.,theyaredistributedalongthebeddingandstructurallyweakzonesbutnotrestrictedtosynsedimentaryslumpstructures,andtherelationshipforsomeelementsbetweenanorthitesandothermineralsindicatethatanorthiteshaveresultedfromreactionofcirculatingalkalinesolutionsrichinAlandSiwithcarbonatedduringtheIndosinianorogeny.TheresultsofthisworksuggestthattheassociationofauthigenicanorthiteswithbeddedorebodiesintheDachangorefieldmaybetheevidencethatthemineralizationisrelatedtocirculatingundergroundhotwaters.
简介:摘要:随着人们生活水平的提升,对食品安全性要求进一步提升,这也是人们生活状态发生改变的标志,从以往的吃饱穿暖,到现在的高质量生活。但是现在我们食用的一些视频在生长种植过程中往往会使用一些药物,提高其抗病虫害的能力。这些药物使用之后往往会产生一定的药物残留,为了保证人们饮食的健康,我国对相关的药物残留有明确的规定,必须在某个数值标准之下才能够进入食品加工行业,如果超过改标准可能会给我们的生活产生严重的影响。大豆、花生、豆油以及花生油这些产品也是我们生活中常用的,而大豆生长过程中往往也会喷洒诸如氟乐灵等药物,我国规定该药物的残留量要低于 0.05mg/kg。为了保证产品中药物残留的合格性,会用多重方法对其进行检测本文采用气相色谱法,对大豆、花生、豆油以及花生油中的氟乐灵残留进行测定
简介:1IntroductionDengfuxianorefieldliesattheintersectionoftheQin-HangCombinedZone(QCZ)andtheNanlingMetallogenic,andcomprisesXiangdongW-Sndeposit(AlsoknownasDengfuxianW-Sndeposit),Jiguanshi
简介:ThePengshanSn-Pb-ZnpolymetallicorefieldislocatedintheJiujiang-Ruichangregion,whichisasegmentofthemiddle-lowerYangtzeRivermetallogenicbelt.ThePengshanlateYanshanianburiedplutonwithgraniticcompositionisacalc-alkalinepluton,intrusionofwhichisresponsiblefortheformationoftheSn-Pb-Znpolymetallicdepositthroughprovidingthermodynamicconditionandore-formingmaterial.Thelong-activebasementriftsinitiallyformedintheJinningperiodandthedomalstructurewithinducedsecondaryorderfaultsformedbyemplacementofthepluton,suchasring-detachmentfault,top-detachmentfaultandjointfissure,actasthepassage-wayformagmaandore-formingfluidandimpoundingstructurefororedeposit.ThemagmatoformtheplutonwithDI>90isintensivelydifferentiated.Thevariationoftheore-formingfluidincompositionwithfallingintemperaturecausedbyactionofmagmatichydrothermalconvectionsystemcombinedwithgroundwaterconvectionsystemattributestomineralizationofvarioustypesintheorefield.Themineralizationprocesscanbedividedintosixstages,i.e.,greisenization,skarnizationofearlystage,fluorite-stanniferoussilicationstage,skarnizationofadvancedstage,quartzandcassiterite-sulfurationstageandcarbonationstage.Themineralassemblagesformedindifferentmineralizationstagesaredifferentowingtotemperaturechangingandmaybeoverlappedinspace.Malayaiteisrecognizedfromthemineralassemblageformedinthefluorite-stanniferoussilicationstage.TheoresinthePengshanSn-Pb-ZnpolymetallicdepositarespatiallyzonedwithvariationfromAs-SnmineralassemblageofhightemperatureintheinnerzonethroughSn-PbandPb-Zn-Agmineralassemblageofmiddletemperatureinthemiddlezonetofluoritemineralassemblageoflowtemperatureintheouterzone.TheexchangingofSn,MgandFebetweenbiotiteandhydrothermalfluidresultedfromvariationofphysicochemicalconditionduringevolutionprocessesofthehydrothermalflu