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279 个结果
  • 简介:利用同步辐射X光衍射技术,对(La1-xBix)0.5Ca0.5MnO3(x=0.2,0.3,0.4)存在Jahn-Teller畸变,进行了原位高压研究。实验表明在外加压力作用,能有效地影响到晶格Mn-O键长Mn-O-Mn键角变化,样品晶格畸变有所减小。并且对晶格存在两种不同畸变模式Q2Q3,在外加压力作用变化规律进行了讨论。由于这两种不同畸变模式受到外力作用时,表现形为不一样,导致了位于a-b基面上Q2畸变模式消失,并且导致Q2畸变模式消失压力点随掺杂浓度增加而增加。

  • 标签: 压力 掺Bi LaCaMnO 晶格畸变
  • 简介:同步辐射软X光能区(50-2000eV)进行了硅光电二极管自标定实验,因为消除了二极管“死区”并采用很薄层SiO2作窗,使得可以用简单模型来分析实验结果,由实验测得光电流,计算出硅光电二极管量子效率,并求得入射同步辐射光通量。

  • 标签: 同步辐射 硅光电二极管 自标定 量子效率 工作原理 气通量
  • 简介:对于x从0.0到0.4之间变化Pt1-xSrxMnO3多晶体所进行价带光电子谱实验显示,Fermi边Fermi边以下-12eV范围内出现能带态密度随掺杂量x有一个显著变化。对这些现象以Pr1-xSrxMnO3体系基态下发生电荷转移为出发点进行了讨论。提出了随掺杂量x非线性电荷转移机制存在由电荷转移导致二级相变可能性。

  • 标签: Pr1-xSrxMnO3 价带 光电子能谱 稀土锰酸盐 能带态密度 非线性电荷转移机制
  • 简介:我们用XPS同步辐射技术研究了钙钛矿型氧化物SrTi1-xSbxO3(x=0,0.05,0.10,0.15,0.20)薄膜电子结构。该薄膜系列可见光波段透明,其透过率均超过90%。所有掺杂薄膜均导电。同步辐射电子谱研究结果表明该薄膜来自Sb杂质退局域化电子母化合物禁带引入了杂质能级。这是导电性根源,价带很小电子态密度限制了跃迁几率。禁带宽度跃迁几率光学透明性原因。

  • 标签: SiTi1-xSbxO3 透明导电薄膜 氧化物薄膜 钙钛矿结构 X-射线光电子能谱 钛酸锶
  • 简介:随着北京同步辐射光电子谱实验站持续稳定开放运行,用户基于该实验站提供光电子谱各种实验模式开展了从金属表面界面电子结构到纳米材料、掺杂金属富勒烯以及磁电阻氧化物体系电子结构研究工作。本文中选择部分具有代表性实验结果进行介绍。

  • 标签: 北京 同步辐射光电子能谱实验站 电子结构 研究工作 课题
  • 简介:采用在位高压Raman光谱高压同步辐射散X射线衍射技术,室温对晶粒尺寸为10nm锐钛矿TiO2进行了压致相变研究,压力范围分别为42.9GPa23.0GPa,实验结果表明,16.3GPaTiO2发生了一次结构相变,由原来锐钛矿结构变为α-PbO2结构(TiO2-Ⅱ),该相变不可逆。同体材料TiO2高压相变结果比较,由于晶粒尺寸效应,纳米尺寸锐钛矿TiO2相变压力明显高于体材料相变压力

  • 标签: 钛矿 相变压力 晶粒尺寸
  • 简介:本文介绍了同步辐射光源特点,以及应用于X射线形貌术带来各种好处。并通过介绍北京同步辐射装置上所做若干实验成果,扼要叙述了同步辐射X射线形貌术晶体缺陷研究晶体生长应用。

  • 标签: 同步辐射 X射线形貌术 晶体缺陷 晶体生长
  • 简介:Characteristicsofiontemperaturemeasuredwithcharge-exchangerecombinationspectroscopy(CXRS)werestudiedinOhmic,lower-hybrid-wave(LHW)drivenandion-cyclotron-resonance-frequency(ICRF)heatedplasmasinHT-7.TheresultsindicatethatthecentraliontemperatureTi0followstheone-thirdpowerlawintheproductofcentralline-averageddensityneandplasmacurrentIpinOhmicdischargesandisthereforeconsistentwiththeArtsimovichscalinglawTi0=K·(Ip·Bt·ne·R2)1/3.ItisshownthatthereisanappreciableincreaseofiontemperatureduringtheoperationwithbothLHWandICRFandthattheincrementofiontemperatureinthoseshotsismainlyduetotheenergytransferviacollisionsbetweenionsandelectronsratherthatbydirectheatingoftheions.

  • 标签: 热等离子体 温度特性 托卡马克 回旋共振频率 离子温度 等离子体电流
  • 简介:SawtoothcontrolexperimentswereperformedonHT-7withalimiterconfigurationandontheExperimentalAdvancedSuperconductingTokamak(EAST)withadoublenullcon-figuration.Thesawtoothperiodcanbemodifiedbylowerhybridwave(LHW)andioncyclotronresonancefrequency(ICRF).Differentsawtoothbehaviorwasobservedwiththesameplasmadensity,LHWpowerbutdifferentplasmacurrentsonHT-7.TherewasadwelltimebetweenLHWaddedandthesawtoothstabilizationonHT-7whilethesawtoothstabilizationimmediatelyhappenedwhenLHWpowerwasinjectedonEAST.Thepossiblemechanismofthesawtoothcontrolisdiscussedinthispaper.Alltheexperimentalresultshaveprovedthatpowerdepositionoftheradiofrequency(RF)shouldbethekeyfactorforsawtoothcontrol.

  • 标签: 超导托卡马克 控制实验 HT-7 锯齿 EAST 等离子体密度
  • 简介:实验观测到X射线反向曲线具有双晶特征。研究表明缺陷聚集孪晶晶界。应力晶界边缘处得到释放。应力释放导致享晶其它缺陷形成。由于缺陷形成缺陷附近产生无位错无应力或低位错小应力区。因此我们提出一种孪晶模型来解释实验结果。应力(主要是热应力),化学配比偏离杂质非均匀分布液封直接(LEC)InP单晶生长过程中产生孪晶主要因素。研究了液封直拉(LEC)InP(111)面上孪晶。本文中讨论了上面提到孪晶模型实验证据如何得到无孪晶液封直接(LEC)InP单晶。

  • 标签: INP 孪晶 晶界 同步辐射 磷化铟 面缺陷
  • 简介:Experimentsonlowerhybridwave(LHW)couplingwereinvestigatedintheHT-7tokamak.GoodcouplingofLHWplasmahasbeendemonstratedatdifferentconditionsintheHT-7tokamak.RelevantresultshaveprovedthatLHW-plasmacouplingisaffectedbythephasedifferencebetweenadjacentwaveguides.Furthermore,theedgedensityaroundthegrillandrelevantcouplingcanbeadjustedbychangingtheplasmalineaveragedensityorthegapvaluebetweentheLHgrillandthelastclosedfluxsurfaces(LCFS).ItisfoundthatthecouplingofLHWsbecomespoorwhentheedgedensityaroundtheLHgrillislargeenoughintheHT-7tokamak,andthatcouplingremainsgoodwithaproperedgedensity.WithincreasingLHWpower,itisalsofoundthatthereflectioncoefficients(RCs)increaseduetonon-lineareffectsunderconditionsoflowedgerecycling,butcandecreaseunderhighedgerecycling.Theedgedensitydependsmainlyonthecompetitionbetweentheponderomotiveforce(PMF)andtheedgerecyclingintensityintheHT-7tokamak.

  • 标签: HT-7托卡马克 低混杂波 波耦合 实验 等离子体 边缘密度
  • 简介:SawtoothactivityonHT-7tokamakhasbeeninvestigatedexperimentallymainlybyusingsoftx-raydiodearrayandmagneticprobes.Theirbehaviorsandoccurrencesarecorrelatedcloselytothedischargeconditions:theelectrondensityNe,theelectrontemperatureTe,thesafetyfactorqaonplasmaboundaryandwallconditionetc.Whencentralline-averagedelectrondensityNe(0)isover2.0×1013cm-3,majorsawtoothactivityemergeswithaperiodofupto6.5msandafluctuationamplitudeofupto2~30%ofSXRradiationsignal.Insomecasessuchasthesafetyfactorbetween4.2~4.7andZeff=3.0~6.0,amonstersawtoothactivityoftenemergeswithoutapparentdeteriorationofplasmaconfinementandwithoutmajordisruption.Duringtheseevents,abundantMHDphenomenaareobservedincludingpartialsawtoothoscillations.Inthispaper,theobservedsawtoothbehaviorsandtheirdependenceontheandtheirdependencedensityNeandwallconditioninohmicallyheatedplasmaareintroduced,theresultsarediscussedandpresented.

  • 标签:
  • 简介:TheICRF(IonCyclotronRangeFrequency)cleaningtechniquehasbeenusedasaroutinewallcleaningmethodintheHT-7superconductingtokamak.Inawiderangeoftoroidalfield,thcremovalrateofresidualgasbyICRFcleaningwasabouttwentytimeshigherthanthatofglowdischargecleaning(GDC).AtdifferentgaspressureandRFpowerlevels,theICRFcleaningisstudiedcarcfully.Agoodimpurityclcaningeffectandaveryhighhydrogenremovalratewereobtained.Theremovalrateofhydrogenby5kWICRFcleaningachievedwas1.6×10-5Torr.1/s.AndtherelationshipsamongpressureP,outgassingrateQ,atomiclayersLabsorbedonsurfaceandthecleaningmodewerediscussedbriefly.

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  • 简介:Thispaperreportsforthefirsttimeanexperimentalstudyonthepowerdepositionprofileoftheioncyclotronrangefrequencies(ICRF)powerdepositingonelectronsinHT-7.ThefastFouriertransform(FFT)analysisandthebreakinslope(BIS)methodareutilizedtoobtaintheinformationofthepowerdeposition.Theresultsindicatethattheelectronswereheateddirectly,andtheelectronsabsorbedaround20%oftheinputpowerofthedischargeofinterest.

  • 标签: 功率沉积 实验测定 HT-7 ICRF 电子 快速傅立叶变换
  • 简介:Togetanoptimizedpulsedelectricalplasmadischargereactorandtoincreasetheenergyutilizationefficiencyintheremovalofpollutants,twohybridplasmadischargereactorsweredesignedandoptimized.Thereactorswerecomparedviathedischargecharacteristics,energytransferefficiency,theyieldsoftheactivespeciesandtheenergyutilizationindyewastewaterdegradation.TheresultsshowedthatunderthesameACinputpower,thecharacteristicsofthedischargewaveformofthepoint-to-platereactorwerebetter.UnderthesameACinputpower,thetworeactorsbothhadalmostthesamepeakvoltageof22kV.Thepeakcurrentofthepoint-to-platereactorwas146A,whilethatofthewire-to-cylinderreactorwasonly48.8A.Thepeakpowersofthepoint-to-platereactorandthewire-to-cylinderreactorwere1.38MWand1.01MW,respectively.Theenergyperpulseofthepoint-to-platereactorwas0.2221J,whichwasabout29.4%higherthanthatofthewire-to-cylinderreactor(0.1716J).Toremove50%AcidOrange7(A07),theenergyutilizationsofthepoint-to-platereactorandthewireto-cylinderreactorwere1.02×10-9mol/Land0.61×10-9mol/L,respectively.Inthepoint-toplatereactor,theconcentrationofhydrogenperoxideinpurewaterwas3.6mmol/Lafter40minofdischarge,whichwashigherthanthatofthewire-to-cylinderreactor(2.5mmol/L).Theconcentrationofliquidphaseozoneinthepoint-to-platereactor(5.7×10-2mmol/L)wasabout26.7%higherthanthatinthewire-to-cylinderreactor(4.5×10-2mmol/L).Theanalysisresultsofthevarianceshowedthatthetypeofreactorandreactiontimehadsignificantimpactsontheyieldsofthehydrogenperoxideandozone.ThemaindegradationintermediatesofA07identifiedbygaschromatographyandmassspectrometry(GCMS)wereaceticacid,maleicanhydride,pbenzoquinone,phenol,benzoicacid,phthalicanhydride,coumarinand2-naphthol.Proposeddegradationpathwayswereelucidatedinlightoftheanalyzeddegradationproducts.

  • 标签: 放电反应器 等离子体放电 废水降解 酸性橙7 染料 双杂交