简介:LowcarbonsteelswithBandPadditionswereremeltedbyelectromagneticlevitationandsolidifiedinavacuumdroptube.Thedropletvolumesweresettobe2mm×2mm×2mm(TM)and5mm×5mm×5mm(FM),respectively.Themicrostructureofrapidlysolidifiedsteeldroplets(cooledinsiliconoil)withPandbothBandPadditionwasobserved.ThemicrostructuresofB-bearingdropletsamplesweremoreuniformthanthoseofB-freeones,forbothTMandFMsamples.Thedistributionof℃andPalongthediameterofeachsamplewasdetected.Thewell-distributionof℃andPwasdetectedinB-bearingdropletsamples.SoitcouldbededucedthatBwasalsowelldistributedinthesteels.ItwasBatomsthatpromotedthewell-distributionof℃andP,whichfurtherimprovedtheuniformityofmicrostructureundertheconditionofrapidsolidification.Themicro-hardnessofBbearingsampleswashigherthanthatofB-freesamples,andthehardeningmechanismwasdiscussedindetail.
简介:One-dimensional(1D)nanomaterialsandnanostructureshavereceivedmuchattentionduetotheirpotentialinterestforunderstandingfundamentalphysicalconceptsandforapplicationsinconstructingnanoscaleelectricandoptoelectronicdevices.Zincsulfide(ZnS)isanimportantsemiconductorcompoundofII-VIgroup,andthesynthesisof1DZnSnanomaterialsandnanostructureshasbeenofgrowinginterestowingtotheirpromisingapplicationinnanoscaleoptoelectronicdevices.Thispaperreviewstherecentprogresson1DZnSnanomaterialsandnanostructures,includingnanowires,nanowirearrays,nanorods,nanobeltsornanoribbons,nanocables,andhierarchicalnanostructuresetc.Thisarticlebeginswithasurveyofvariousmethodsthathavebeendevelopedforgenerating1Dnanomaterialsandnanostructures,andthenmainlyfocusesonstructures,synthesis,characterization,formationmechanismsandopticalpropertytuning,andluminescencemechanismsof1DZnSnanomaterialsandnanostructures.Finally,thisreviewconcludeswithpersonalviewstowardsfutureresearchon1DZnSnanomaterialsandnanostructures.
简介:Thebovinehydroxyapatite(BHA)wasappliedtopreparebiologicaltissueengineeringscaffoldsbythemethodofextrusionfreeforming.Toachievethisgoal,BHAwereaddedtosodiumalginate(SA)solutiontoformaslurrysysteminappropriateproportion.Theresultingmixtureswerefabricatedtobeakindofcontrollableandporousscaffoldsfollowedwithcross-linkingin5%calciumchloride(CaCl2)solutionfor24h.Afterthat,thescaffoldsweresinteredinairat1000,1100,1200and1300℃for5h.Scanningelectronmicroscopy(SEM)andX-raydiffraction(XRD)studieswereperformedonthescaffoldstoanalyzeitsmicrostructureandconstituent.Toexploretheeffectofsinteringtemperatureonscaffolds,thecompressivestrength,volumeshrinkageandwaterabsorptivityofBHA-SAcompositescaffoldsaftersinteringwereinvestigated.TheresearchtestsindicatedthefeasibilityofapplyingBHApowderto3Dprinting.Besides,thescaffoldssinteredinarespectivelylowertemperaturepossessmuchmoreporesandperformedhigherwaterabsorptivity,whichmeansbettercellularaffinity.Andscaffoldssinteredbetween1100and1200℃presentshighercompressivestrength.
简介:Amathematicalmodelforthethree-dimensionalsimulationoffreedendriticgrowthandmicrostructureevolutionwasdevelopedbasedonthegrowthmechanismofcrystalgrainsandbasictransferequationssuchasheat,massandmomentumtransferequations.Manyfactorsincludingconstitutionalundercooling,curvatureundercoolingandanisotropy,whichhadvitalinfluencesonthemicrostructureevolution,wereconsideredinthemodel.SimulatedresultsshowedthatfinalmicrostructuralpatternsandfreedendriticgrowthcouldbepredictedreasonablyandcalculatedresultswerecoincidentwithexperimentalThesimulatedresultsoffreedendriticgrowthindicatedthatthestrengthofanisotropyhassignificanteffectsonfreedendriticgrowth,dendriteprofile,microsoluteandtemperaturedistribution.Thedendriticgrainprofileswithfully-grownparallelsecondaryarmtendtobeformedattheintensiveanisotropy,whilenearoctahedralgrainprofileswithsmallprotuberancesofsurfaceatlowstrengthofanisotropy.Thesimulatedresultsoffreedendriticgrowthalsoindicatedthattherearesmallmoltenpoolsleftininterdendriticareas.Thisishelpfultounderstandthefundamentaloftheformationofmicrostructurerelateddefectssuchasmicrosegregationandmicroporosity.
简介:二维(2D)有multilayered质地的碳/碳(C/C)composites,特别与不同厚度高度粗糙(HT)pyrocarbon层,被等温的、等压的化学蒸汽渗入(CVI)准备技术。C/Ccomposites的机械性质上的矩阵微观结构的影响被极化的轻显微镜学调查,扫描电子显微镜学和三点的弯曲测试。结果证明有多层粗糙的pyrocarbon矩阵的样品与纯媒介粗糙的结构比那件拥有更高曲折的力量,它被归因于多重裂缝偏转并且在HT层以内的在不同粗糙的pyrocarbon层之间并且在亚层之间的界面的滑动。HTpyrocarbon层的厚度的增加改进样品的粘性并且在伪塑料行为显示破裂。
简介:PositronannihilationbehaviorshavebeenstudiedinthesinglephaseNd2Fe14BmagnetandthenanocompositeNd2Fe14B/α-Femagnet,preparedbymeltspinning.Theresultsshowedthatthenumberofvacancy-clusteratgrainboundariesincreaseswithincreasingannealingtemperatureforthebothtypesofmagnets.Theincreaseofthiskindofdefectcanimprovethecoercivityof
简介:MoleculardynamicssimulationusingauniversalforcefieldhasbeenemployedtodeterminethediffusioncoefficientsofO2andNa2SO4vaporintoB2O3andSiCfrom700Kto1273K,respectively.Einsteindiffusionwasobservedina250~300pssimulation.ThediffusioncoefficientfortheO2rangefromabout9.279×10-9cm2/sforB2O3to2.275×10-10cm2/sforSiCataloadingof32moleculespersimulationbox,thatfortheNa2SO4vaporrangefromabout9.888×10-7cm2/sforB2O3to1.837×10-10cm2/sforSiCataloadingof8moleculespersimulationbox.EnvironmentpropertiesofC/SiCcompositewillbeincreasedviatheB2O3preventingthediffusionofO2andNa2SO4vaporintothepyrolyticinterphaseandcarbonfibers.