简介:Precipitationstrengtheningaswellassolutionstrengtheningiskeymechanismforheatresistantsteels.Itisveryimportanttocharacterizetheprecipitatesin9%Crferriteheatresistantsteels,especiallytoshowthenanometer-sizedparticles.Bytransmissionelectronicmicroscopeattachedwithanenergydispersivespectrometeraswellasopticalmicroscope,scanningelectronicmicroscope,themicrostructureandchemicalcompositionofprecipitatesina9%Crheatresistantsteelafterdifferentheattreatmentswereinvestigated.ItwasfoundthatthemicrostructureofnormalizedsamplewasmartensitewithfineNbCandFe3C.Themicrostructureoftemperedsampleistemperedmartensite,andtheremainlyweretwotypesofprecipitates,M23C6withthesizerangeof50-300nmandMXwiththesizeof10-100nm.SuperfineM23C6precipitatedpreferablyonpriorausteniticgrainboundariesandmartensiticlathboundaries,whilenanometer-sizedMXprecipitatesweredistributedrandomly.Aftershort-termcreep,Lavesphaseformedalonggrainboundariesofthe9%Crsteel,andM23C6andMXprecipitateswerefoundtobecomecoarser.Moreinformationaboutprecipitatesinthe9%Crsteelhadbeenexhibitedbyatomicforcemicroscopy.Thereby,distribution,sizeandshapeoftheprecipitatesaswellastheircompositionsandstructureswererevealed.
简介:Inthisstudy,metallographicanalysisandnanoindentationcharacterizationwereusedtoanalyzethepropertiesandmicrostructuresofas-castnitrogenalloyed27Cr-7Ni-4Mosuperduplexstainlesssteel(super-DSS).Theas-castmicrostructureofthesuper-DSSwascharacterizedbyitsferriteandisland-likeaustenitephases.Duringthesolutionannealingprocess,theaustenitevolumepercentageofthesteeldecreasedgraduallywithincreasedannealingtemperature.Asamainelement,thechromiumcontentintheferriticandausteniticphaseselevatedslightlyatfirstthendecreasedwithincreasedannealingtemperature.Thechromiumpartitioncoefficientinthesteelvariedbyaround1.0.Thecontentsofnickel,anothermainalloyelement,alsoincreasedintheferriticandausteniticphaseswithincreasedannealingtemperature,asdidthenickelpartitioncoefficientinthesteel,whichtendedtobecloseto1.0.Thenanoindentationcharacterizationresultsindicatethatthehardnessoftheaustenitephaseisslightlygreaterthanthatoftheferritephase.Theyweresimilartoeachotherwithinacertaintemperaturerangefrom1050℃to1100℃.Thistemperaturerangewasconsistentwiththetemperaturerangeinwhichthecontentratioofthetwophaseswascloseto1∶1.WefoundtheYoung'smodulusoftheferritephasetobegreaterthanthatoftheaustenitephase.Withincreasedannealingtemperature,theYoung'smodulusoftheferritephasedecreasedwhilethatoftheaustenitephaseremainedalmostunchanged.
简介:Themechanicalandcorrosivepropertiesof00Cr13Ni4Mo(S13-4N)weretestedandcomparedwiththoseof00Cr13Ni6Mo(S13-6).Theeffectsofnitrogenonthepropertiesofthesteelswereanalyzed.Theresultsofthetensileandcorrosiontestsshowthestrength,theductility,andthepittingcorrosionresistanceofS13-4Narehigher,lowerandpoorerthanthoseofS13-6respectively,whentemperedatatemperaturebelow550℃andviceversawhenthetemperingtemperatureishigherthan550℃.TheresultsoftheX-raydiffraction(XRD)andtheelectronbackscattereddiffraction(EBSD)analysesrevealthatinversedausteniteappearsat550℃andtheamountofitpeaksat600℃withthebestductility.AndthetotalamountoftheinversedausteniteinS13-6ismorethanthatinS13-4Nindifferentforms.Nitrogenperformsbetterintermsofstabilizinginversedaustenitewhilenickelismorefavorableforforminginversedaustenite,theamountandstabilityofwhichaffecttheductilityremarkably.ThereasonfortheembrittlementofS13-4Nat450℃canbetheresultofcarbideandnitrideprecipitatingatgrainboundaries.
简介:利用扫描电镜观察和能谱分析,研究了A709-50T-2结构用钢探伤不合格的原因。结果表明:中心偏析和大块Nb和Ti的碳或氮化物的形成共同作用,使钢板中心产生裂纹,最终导致了探伤的不合格。