摘要
LowfieldNMRtechniquewasappliedtoinvestigatethehydrationofcementpasteswithdifferentwatertocementratiosoradditionofsuperplasticizer.Asanondestructivemethod,thistechniquecanbeusedtomonitorthehydrationkineticsprocessbyfollowingthechangesoflongitudinalrelaxationtime(T1)ofwaterconstrainedinthepastes.TheexperimentalresultsindicatethattheT1distributionsofwaterinthefreshpastenormallyexhibitebimodaldistribution,wherethelargepeakiscorrespondingtothefreewaterwhilethesmalloneiscontributedbythewaterstoredintheflocculations.TimedependenceoftheweightedaverageT1hasagoodagreementwiththehydrationprocessandcouldbedividedintofourstages,ie,initialperiod,dormantperiod,acceleratedperiodandsteadyperiod.Thehydrationmechanismofeachstagewasdescribedbasedonthetheoryofcementchemistry.Inaddition,thetotalsignalintensity,whichisproportionaltothecontentofthephysicallyboundwaterinthesamples,decreasesuccessivelyduringthehydrationreflectingtheconsumptionofphysicallyboundwaterbyhydrationreactions.
出版日期
2010年04月14日(中国期刊网平台首次上网日期,不代表论文的发表时间)