Direct synthesis of per(poly)fluoroalkylmethyl-substituted electrophilic cyclopropane derivatives-中国期刊网

摘要 Aconvenientanddirectper(poly)fluoroalkylmethyl-mtroducingcyclopropanationreactionwasdescribed.InthepresenceofCrCl3/Fe,per(poly)fluoroalkyliodidesreactedwithdiethylallylmalonateanditsanalogstogiveper(poly)fluoroalkylmethyl-substitutedelectrophiliccyclopropanederivativesinhighyields.Thisreactionwasconsideredtoproceedbytwosteps:radicaladditionfollowedbycyclopropanation.

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Direct synthesis of per(poly)fluoroalkylmethyl-substituted electrophilic cyclopropane derivatives

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Direct synthesis of per(poly)fluoroalkylmethyl-substituted electrophilic cyclopropane derivatives

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