Catalytic Cracking of Cycloparaffins Admixed with Olefins：1. Single-Event Microkinetic （SEMK） Modeling-中国期刊网

摘要 Single-eventmicrokinetic(SEMK)modelofthecatalyticcrackingofmethylcyclohexaneadmixedwith1-octeneoverREUSYzeolitesat693K—753Kintheabsenceofcokeformationisenhanced.Tokeepconsistencywiththewellknowncarbeniumionchemistry,hydridetransferformingandconsumingallyliccarbeniumionsinthearomatizationofcycloparaffinsarefurtherinvestigatedanddifferentiated.Thereversibilityofendocyclicβ-scissionandcyclizationreactionsisrefinedbyaccountingexplicitlyforthereactingolefinsandresultingcycloparaffinsinthecorrespondingthermodynamics.24activationenergiesforthereactionsinvolvedinthecrackingofcycloparaffinsareobtainedbytheregressionof15setsofexperimentaldataupontakingtheresulting37maincrackingproducts,i.e.,responsesintoaccount.TheenhancedSEMKmodelcanadequatelydescribethecatalyticbehaviorof37mainproductswithconversionandtemperature.

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Catalytic Cracking of Cycloparaffins Admixed with Olefins：1. Single-Event Microkinetic （SEMK） Modeling

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Catalytic Cracking of Cycloparaffins Admixed with Olefins：1. Single-Event Microkinetic （SEMK） Modeling

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